Below is the exact episode guide of Road to Avonlea when it first aired in 1990 and ended in 1996.
1. 1- 1 7 Jan 90 The Journey Begins
2. 1- 2 14 Jan 90 The Story Girl Earns Her Name
3. 1- 3 21 Jan 90 The Quarantine at Alexander Abraham's
4. 1- 4 28 Jan 90 The Materializing of Duncan McTavish
5. 1- 5 4 Feb 90 Old Lady Lloyd (aka Song in the Night)
6. 1- 6 11 Feb 90 Proof of the Pudding
7. 1- 7 18 Feb 90 Conversions
8. 1- 8 25 Feb 90 Aunt Abigail's Beau
9. 1- 9 4 Mar 90 Malcolm and the Baby
10. 1-10 21 Apr 90 The Witch of Avonlea
11. 1-11 7 May 90 Felicity's Challenge
12. 1-12 4 Nov 90 The Hope Chest of Arabella King
13. 1-13 11 Nov 90 Nothing Endures But Change
Season 2
14. 2- 1 2 Dec 90 Sara's Homecoming
15. 2- 2 9 Dec 90 How Kissing Was Discovered
16. 2- 3 16 Dec 90 Aunt Hetty's Ordeal
17. 2- 4 23 Dec 90 Of Corsets and Secrets and True True Love
18. 2- 5 30 Dec 90 Old Quarrels, Old Love
19. 2- 6 6 Jan 91 May the Best Man Win
20. 2- 7 13 Jan 01 Family Rivalry
21. 2- 8 20 Jan 91 Sea Ghost
22. 2- 9 27 Jan 91 All That Glitters
23. 2-10 3 Feb 91 Dreamer of Dreams
24. 2-11 10 Feb 91 It's Just a Stage
25. 2-12 17 Feb 91 A Mother's Love
26. 2-13 24 Feb 91 Misfits and Miracles
Season 3
27. 3- 1 12 Jan 92 The Ties That Bind (aka Sister of the Bride)
28. 3- 2 19 Jan 92 Felix and Blackie
29. 3- 3 26 Jan 92 Another Point of View (aka Facts and Fictions)
30. 3- 4 2 Feb 92 But When She Was Bad... She Was Horrid (1)
31. 3- 5 9 Feb 92 But When She Was Bad... She Was Horrid (2)
32. 3- 6 16 Feb 92 Aunt Janet Rebels (aka Aunt Janet's Rebellion)
33. 3- 7 23 Feb 92 A Dark and Stormy Night
34. 3- 8 1 Mar 92 Friends and Relations
35. 3- 9 8 Mar 92 Vows of Silence (aka True Confessions)
36. 3-10 15 Mar 92 After the Honeymoon
37. 3-11 22 Mar 92 High Society
38. 3-12 29 Mar 92 The Calamitious Courting of Hetty King
39. 3-13 5 Apr 92 Old Friends, Old Wounds
Season 4
40. 4- 1 17 Jan 93 Tug of War
41. 4- 2 17 Jan 93 The Lady and the Blade
42. 4- 3 24 Jan 93 Incident at Vernon River
43. 4- 4 31 Jan 93 Boys Will Be Boys
44. 4- 5 7 Feb 93 Moving On (aka Sara and the Marshal)
45. 4- 6 14 Feb 93 Evelyn
46. 4- 7 21 Feb 93 The Dinner (aka Felicity's Grand Design)
47. 4- 8 28 Feb 93 Heirs and Graces
48. 4- 9 7 Mar 93 Hearts and Flowers
49. 4-10 21 Mar 93 Felicity's Perfect Beau
50. 4-11 28 Mar 93 The Disappearance
51. 4-12 4 Apr 93 Jasper's Home Movie
52. 4-13 29 Nov 93 Hearth and Home
Season 5
53. 5- 1 9 Jan 94 Fathers and Sons
54. 5- 2 9 Jan 94 Memento Mori
55. 5- 3 16 Jan 94 Modern Times
56. 5- 4 23 Jan 94 A Friend in Need
57. 5- 5 8 Feb 94 Strictly Melodrama
58. 5- 6 13 Feb 94 The Great Race
59. 5- 7 20 Feb 94 Stranger in the Night
60. 5- 8 1 Mar 94 Someone to Believe In
61. 5- 9 8 Mar 94 Thursday's Child
62. 5-10 15 Mar 94 Best Laid Plans
63. 5-11 22 mar 94 Otherwise Engaged
64. 5-12 29 Mar 94 Enter Prince Charming (1)
65. 5-13 5 Apr 94 The Minister's Wife (2)
Season 6
66. 6- 1 15 Jan 95 The Return of Gus Pike
67. 6- 2 15 Jan 95 Lonely Hearts
68. 6- 3 22 Jan 95 Christmas In June
69. 6- 4 29 Jan 95 Fools and Kings
70. 6- 5 5 Feb 95 Comings and Goings
71. 6- 6 12 Feb 95 The Trouble with Davey
72. 6- 7 19 Feb 95 Great Expectations
73. 6- 8 19 Feb 95 A Fox Tale
74. 6- 9 5 Mar 95 The More Things Change
75. 6-10 6 Mar 95 Home Is Where the Heart Is
76. 6-11 19 Mar 95 What a Tangled Web We Weave
77. 6-12 26 Mar 95 A Time to Every Purpose (aka The Calling)
78. 6-13 2 Apr 95 Homecoming
Season 7
79. 7- 1 14 Jan 96 Out of the Ashes
80. 7- 2 14 Jan 96 Love May Be Blind... But the Neighbours Ain't
81. 7- 3 21 jan 96 Davey and the Mermaid
82. 7- 4 28 Jan 96 Woman of Importance
83. 7- 5 4 Feb 96 Secrets and Sacrifices
84. 7- 6 11 Feb 96 Ah... Sweet Mystery of Life
85. 7- 7 18 Feb 96 King of the Great White Way
86. 7- 8 25 Feb 96 Total Eclipse
87. 7- 9 3 Mar 96 From Away
88. 7-10 10 Mar 96 After the Ball Is Over
89. 7-11 17 Mar 96 Return to Me
90. 7-12 24 mar 96 The Last Hurrah
91. 7-13 31 Mar 96 So Dear to My Heart
TV Movie
13 Dec 98 Happy Christmas Miss King