The Janet Periodic Table of Elements (1929) may be re-arranged
as a series of square matrices. The matrices are of different sizes and each
matrix organizes the atomic orbitals into square concentric rings. Each cell
may be assigned an atomic number which also identifies a “most significant electron”.
The matrices may be stacked vertically to form “The
Periodic Stack of Elements” as shown below.
The sub-atomic particles may also be arranged as square
matrices. These matrices may be stacked to form “The Periodic Stack of
Particles”.
Please send your comments to; doulting@shaw.ca Last Revision 07 October 2009.
Contents
1 Introduction
2 Most
Significant Electron
3 The
Periodic Stack of Elements
4 The
Quantum Numbers
5 Orbital
Angular Momentum
6 Spin
Angular Momentum
7 Trajectory
Angular Momentum
8 The
Quantum Matrix
9 Couples
10 Quantization
11 Quantum Vectors
12 Single Electron Systems
13 Calculations for Multiple Electron Systems
14 Dynamic Matrices
15 Fundamental Principles of Chemistry
16 The Periodic Stack of Particles
17 Particle Quantum Numbers
18 The Particle Number
19 Nomenclature
20 References
1.
Introduction
Various forms of the Periodic Table of Elements are
popular. One interesting arrangement is “The Periodic Table in Flatland”3.
Another interesting table is derived from atomic ionization potentials1.
Eric Scerri (UCLA) has written
extensively on variations of the Periodic Table. His table may be found at;
http://www.meta-synthesis.com/webbook/35_pt/pt_database.php?PT_id=20
Another form of the PT is based upon tetrahedral
sphere packing.
http://www.perfectperiodictable.com/
The Janet Periodic Table2 is a 2D arrangement of the natural
elements. Charles
Janet first proposed this form of the Periodic Table in 1929. The Janet form of
the Periodic Table has been proposed from time to time by various persons4.
Acceptance of this table requires minor modification of the periods7. According to Winter8, the Janet
table is preferred by some persons to the standard form. Further information on the Janet table may
be found at;
http://www.ipgp.jussieu.fr/~tarantola/
and at; http://www.meta-synthesis.com/webbook/35_pt/pt.html#j
The Janet table can be arranged as a series of four
square matrices. Each matrix is a different size. Each matrix arranges the
atomic orbitals (s,p,d,f) into a series of concentric rings. The “s” ring is
the core and the other orbitals form concentric rings around the core. The
atomic number is used to identify the most significant electron (MSE) of an
element in the ground state. Elements (actually MSEs) which are located on a
major diagonal have the quantum number for orbital magnetic moment (mℓ)
equal to zero.
The matrices may be stacked vertically with the orbital rings aligned
vertically. This is a 3D visualization of the natural elements called “The
Periodic Stack of Elements”. Vertical sections through the stack give
interesting groupings of elements.
If a quantum number ‘mn’ is admitted, then it may represent a
magnetic moment associated with the principal quantum number (n). From
observation it is possible to deduce a 2x3 matrix of quantum numbers.
The top row is; n , ℓ
, s
The bottom row is; mn , mℓ , ms
A new set of quantum numbers (a, ma) may be
derived from quantum numbers in the matrix. This new set is called the “aufbau
pair” and it quantifies the aufbau principle.
The sub-atomic particles may also be arranged as a
series of square matrices.
2. Most Significant Electron
All
electrons of an atom in the ground state may be identified by a number from 1
to Z, with 1 being the least energetic and Z the most energetic. The atomic
number (Z) of any element may have a dual purpose. In addition to identifying
the number of protons in the nucleus, the atomic number may also be used to
identify the “most significant electron” (MSE) of an atom in the ground state.
This is usually the most energetic electron, which is normally the first
electron to ionize the atom. The characteristics of this electron are
represented by its quantum numbers. It is possible to represent the MSE (Z) of
any element as a function of its quantum numbers.
3. The Periodic Stack of Chemical Elements
The
Janet periodic table may be re-arranged into a series of square matrices. Each
matrix is a different size. The matrices arrange the atomic orbitals as square
concentric rings. The core is the ‘s’ orbital and the remaining orbits (p, d,
f) are arranged concentrically around the core. The quantum numbers associated
with the “most significant electron” of any element (in the ground state)
determine the position of the element within the matrix. The matrices may be
stacked vertically with the core and orbital rings in alignment. This is the
“Periodic Stack of Elements” which resembles a stepped pyramid. Various
pyramidal and tetrahedral forms of the PT have been postulated5.
Matrix Identification (a)
;
Each
matrix is identified by a matrix number (a) where; a = 1,2,3,4
Half-Matrix Identification (mn , ms) ;
The
upper or lower half of each matrix is identified by a number (mn).
The
upper half of each matrix is defined by ; mn = +½.
The
lower half of each matrix is defined by ; mn = -½.
The
right or left half of each matrix is identified by the quantum number for spin
magnetic moment (ms).
The
right half of each matrix is defined by ; ms = +½.
The
left half of each matrix is defined by ; ms = -½.
Together
mn and mS define a quadrant of any matrix.
Concentric Rings (ℓ);
Each
matrix may be viewed as a set of concentric square rings arranged around a
core. The core is the inner four cells. Each ring is identified by the quantum
number for orbital angular momentum (ℓ).
The core of each matrix
is defined by ; ℓ = 0
The outermost ring of
each matrix is defined by ; ℓ
= a - 1
Electrons
with quantum number "ℓ" greater than three are not known to be
of any significance in chemical processes. This implies that the matrix
number (a) may have a limiting value of four, and that the atomic number (Z)
may have a limiting value of 120.
Displacement from Diagonal (mℓ);
Displacement from a
major diagonal of a matrix is identified by the quantum number for magnetic
moment (mℓ).
A cell on the diagonal
is defined by ; mℓ
= 0
A column displacement is
defined by ; mℓ
= positive
A row displacement is
defined by ; mℓ
= negative
The Periodic Stack with cells labelled
as Atomic Numbers (Z);
a = 1
|
2 |
1 |
|
4 |
3 |
a = 2
|
9 |
8 |
5 |
6 |
|
10 |
12 |
11 |
7 |
|
18 |
20 |
19 |
15 |
|
17 |
16 |
13 |
14 |
a = 3
|
28 |
27 |
26 |
21 |
22 |
23 |
|
29 |
35 |
34 |
31 |
32 |
24 |
|
30 |
36 |
38 |
37 |
33 |
25 |
|
48 |
54 |
56 |
55 |
51 |
43 |
|
47 |
53 |
52 |
49 |
50 |
42 |
|
46 |
45 |
44 |
39 |
40 |
41 |
a = 4
|
67 |
66 |
65 |
64 |
57 |
58 |
59 |
60 |
|
68 |
78 |
77 |
76 |
71 |
72 |
73 |
61 |
|
69 |
79 |
85 |
84 |
81 |
82 |
74 |
62 |
|
70 |
80 |
86 |
88 |
87 |
83 |
75 |
63 |
|
102 |
112 |
118 |
120 |
119 |
115 |
107 |
95 |
|
101 |
111 |
117 |
116 |
113 |
114 |
106 |
94 |
|
100 |
110 |
109 |
108 |
103 |
104 |
105 |
93 |
|
99 |
98 |
97 |
96 |
89 |
90 |
91 |
92 |
The Periodic Stack with cells labelled as Atomic Orbitals;
a = 1
|
1s |
1s |
|
2s |
2s |
a = 2
|
2p |
2p |
2p |
2p |
|
2p |
3s |
3s |
2p |
|
3p |
4s |
4s |
3p |
|
3p |
3p |
3p |
3p |
a = 3
|
3d |
3d |
3d |
3d |
3d |
3d |
|
3d |
4p |
4p |
4p |
4p |
3d |
|
3d |
4p |
5s |
5s |
4p |
3d |
|
4d |
5p |
6s |
6s |
5p |
4d |
|
4d |
5p |
5p |
5p |
5p |
4d |
|
4d |
4d |
4d |
4d |
4d |
4d |
a = 4
|
4f |
4f |
4f |
4f |
4f |
4f |
4f |
4f |
|
4f |
5d |
5d |
5d |
5d |
5d |
5d |
4f |
|
4f |
5d |
6p |
6p |
6p |
6p |
5d |
4f |
|
4f |
5d |
6p |
7s |
7s |
6p |
5d |
4f |
|
5f |
6d |
7p |
8s |
8s |
7p |
6d |
5f |
|
5f |
6d |
7p |
7p |
7p |
7p |
6d |
5f |
|
5f |
6d |
6d |
6d |
6d |
6d |
6d |
5f |
|
5f |
5f |
5f |
5f |
5f |
5f |
5f |
5f |
The Periodic Stack with cells
labelled as Chemical Elements;
3D Periodic Table of Elements - Matrix 1 ;
|
He |
H |
|
Be |
Li |
3D Periodic Table of Elements - Matrix 2 ;
|
F |
O |
B |
C |
|
Ne |
Mg |
Na |
N |
|
Ar |
Ca |
K |
P |
|
Cl |
S |
Al |
Si |
3D Periodic Table of Elements - Matrix 3 ;
|
Ni |
Co |
Fe |
Sc |
Ti |
V |
|
Cu |
Br |
Se |
Ga |
Ge |
Cr |
|
Zn |
Kr |
Sr |
Rb |
As |
Mn |
|
Cd |
Xe |
Ba |
Cs |
Sb |
Tc |
|
Ag |
I |
Te |
In |
Sn |
Mo |
|
Pd |
Rh |
Ru |
Y |
Zr |
Nb |
3D
Periodic Table of Elements - Matrix 4 ;
|
Ho |
Dy |
Tb |
Gd |
La |
Ce |
Pr |
Nd |
|
Dr |
Pt |
Ir |
Os |
Lu |
Hf |
Ta |
Pm |
|
Tm |
Au |
At |
|
Tl |
Pb |
W |
Sm |
|
Yb |
Hg |
Rn |
Ra |
Fr |
Bi |
Re |
Eu |
|
No |
Uub |
|
|
|
|
Bh |
Am |
|
Md |
Uuu |
|
|
|
Uuq |
Sg |
Pu |
|
Fm |
Ds |
Mt |
Hs |
Lr |
Rf |
Db |
Np |
|
Es |
Cf |
Bk |
Cm |
Ac |
Th |
Pa |
U |
Inert Gases ;
The inert gases form two
vertical columns within the stack. The location of one vertical column
(18, 54, 118) is given by ;
ℓ
= 1 , mn = -½ , mℓ
= 1, ms = -½.
The location of the
other vertical column (10, 36, 86) is given by ;
ℓ
= 1 , mn = +½ , mℓ = 1 , ms
= -½.
The inert gases are
represented by blocks with red labels in the illustration below. The heavy
score line separates quarters of the stack.
Other chemical
commonalities may be viewed in vertical sections of the stack. Diagonal
sections are also interesting.
4. The Quantum Numbers
The
quantum numbers (n , ℓ , mℓ , ms)
are associated with electron motion and are defined as follows.
n is the principal quantum number
ℓ
is the azimuthal quantum number for orbital angular momentum
mℓ
is orbital magnetic moment
ms is spin magnetic
moment ( ms = ± ½ ) (spin up, spin down)
s is the quantum number for spin
angular momentum (s = ½ ).
Z is the atomic number and the MSE
identifier for a ground state atom
The spin
quantum number is usually omitted as it is the same value for all electrons.
5.
Orbital Angular Momentum
The
azimuthal quantum number is associated with orbital motion relative to the
nucleus6. The orbital angular momentum (L) of the electron is
quantized to ‘ℓ’ as follows;
L2 = ℓ(ℓ+1)ħ2
Where;
ħ = h/2π
h is Plank’s constant (a
fundamental unit of angular momentum)
A
magnetic moment (Lz) is associated with orbital motion; Lz = mℓ ħ
6.
Spin Angular Momentum
The spin
angular momentum (S) of the electron is quantized to ‘s’ as follows;
S2 = s(s+1)ħ2 = ¾
ħ2
S
= ½√3ħ
A
magnetic moment (Sz) is associated with spin motion; Sz = ms ħ
7. Trajectory
Spin Angular Momentum
It
is convenient to assume that orbital motion is confined to a single spatial
plane. The trajectory of the orbit surrounds the nucleus and is a closed path
such as a circle, ellipse, or lobe. A surface of electron motion is generated
by rotating the plane trajectory around an axis of rotation. This shall be
called “trajectory spin”. It shall be
assumed that the spin axis is confined to the trajectory plane and that it
passes through the nucleus. If the axis of spin is aligned with the major axis
of the trajectory a simple surface is generated. If the spin axis is tilted by
some angle from the major axis, then the surface has a self intersecting region.
The
angular momentum (N) associated with trajectory spin is quantized to ‘n’ as
follows;
N2 = CN2n(n+1)ħ2
Where;
CN is a constant depending
upon trajectory shape and the tilt of the axis of rotation.
A
magnetic moment (Nz) is associated with trajectory spin; Nz = CNmn ħ
Where; mn is a quantum
number for the magnetic moment of trajectory spin.
mn = ± ½ (rotation up, rotation down)
It may
also be conjectured that ‘mn’ represents a magnetic dipole with orientation
described as “dipole north” or “dipole south”.
8. The Quantum Matrix
If
a quantum number for trajectory magnetic moment (mn) is admitted,
then a quantum matrix (MZ) may be constructed as follows;
MZ = n ,
ℓ
, s
mn , mℓ , ms
The
top row represents various forms of angular momentum. The sum of all quantum
numbers for angular momentum (LT) is;
LT
= n + ℓ + s
The
bottom row represents various forms of magnetic moment. The sum of all quantum
numbers for magnetic moment (mT) is;
mT
= mn + mℓ + ms
9.
Couples
The
members of the quantum matrix may be arranged into couples of momentum and
magnetic moment which correspond to the columns of MZ.
Principal couple (N¢);
N¢
= n + mn
Orbital couple (L¢); L¢ = ℓ + mℓ
Spin couple (S¢); S¢ = s + ms
It
shall be assumed that an electron’s surface of motion precesses. The momentum
associated with precession will have a quantum number (a) which shall be called
the “Aufbau Number”. An associated magnetic moment (ma) completes
the Aufbau Couple (A¢).
A¢ = a + ma
Where;
'a' takes values 1, 2, 3, 4
The aufbau principle may be quantified using two
simple averages;
A¢
= ½( LT + mT) The
couple average
ma = ½( mℓ + ms) The magnetic average
Substitution
gives; 2a = n + ℓ + s + mn
If ; mn = - ½
Then the
Madelung rule is formed; 2a = n + ℓ
If ; mn = + ½
Then the
Madelung rule is modified; 2a = n + ℓ + 1
Atomic
orbitals (s, p, d, f ) are defined by ℓ
as follows;
s:
ℓ
= 0,
p:
ℓ
= 1,
d:
ℓ
= 2,
f:
ℓ
= 3
The
aufbau number (a) and the magnetic number (mn) summarize the
electronic filling sequence of an atom. Groupings of atomic orbitals (n, ℓ) corresponding to the aufbau-magnetic pair (a, mn)
are;
(1,
+½) = 1s
(1,
-½) = 2s
(2,
+½) = 3s, 2p
(2,
-½) = 4s, 3p
(3,
+½) = 5s, 4p, 3d
(3,
-½) = 6s, 5p, 4d
(4,
+½) = 7s, 6p, 5d, 4f
(4,
-½) = 8s, 7p, 6d, 5f
10.
Quantization
The
quantised rotational energy of a rigid rotor (ER) is ; ER = q(q+1)E0
Where; q is a generic quantum number
E0 is a
fundamental energy
The vibrational
energy of a simple harmonic oscillator (EH) is quantised; EH = (q+½)E0
The
energy ratio (rotation/vibration) is; ER
/ EH = q(q+1) / (q+½) = tan(fq)
q/(q+1) =
tan(½fq)
Where; fq is the angle of quantization of
rotation and vibration to quantum number q.
The
total energy (ET) is; ET2
= ER2 + EH2
ET
- EH = q2E0
ET
- EH - ER = -qE0
A
particle energy ratio is; EP
/ER
Where; EP is particle energy
EP = LP/t
Where; LP is angular momentum of a particle
t is a time interval
A wave
energy ratio is; hω /EH
Where; ω is frequency of vibration
h is plank’s constant
It shall
be assumed that a condition for steady state motion is;
Particle ratio = wave ratio
EP /ER =
hω /EH
EP /hω = ER/EH = tan(fq)
LP/thω = tan(fq)
If; LP = mvr
h = m0cλ0
Then; mvr/tm0cλ0ω = tan(fq)
If; r/t = λ0ω
and; sin(fq)
= v/c
Then; cos(fq)
= m0/m
Giving; 1 = (m0/m)2 + (v/c)2
This is the
definition of relativistic mass (m).
11. Quantum
Vectors
A
quantum vector has quantized magnitudes which are functions of the quantum
numbers. The unit vectors (i , j , k)
form the basis of an orthogonal co-ordinate system. The complex constant (i) may
identify an unobservable characteristic; i2 + 1 = 0
A fundamental magnitude of momentum
(p0) is; p0 = h/λ0
Two momentum vectors will be assumed
to act upon each MSE as follows;
Electric momentum (p1)
is;
p1 = 2[a(a+1)(a+½)/3]½ p0 i
+
i[2ℓ(ℓ+½)]½ p0 j + i[s(s+½)]½
p0 k
Magnetic momentum (p2)
is;
p2 = i[2a2(mn+½)]½ p0
i + i[2(ℓ+½)(ms+½)]½ p0 j + [(s+½)(mℓ+½)]½
p0 k
The
electro-magnetic momentum (p3) is; p3 = p1 + p2
If; p1 and p2
act orthogonally, then; | p3|2 = | p1|2
+ | p2|2
| p1|2
= (4/3)a(a+1)(a+½)p02 - 2ℓ(ℓ+½)p02 - s(s+½)p02
| p2|2
= -2a2(mn+½)p02 - 2(ℓ+½)(ms+½)p02 + (s+½)(mℓ+½)p02
| p3|2
= Zp02
Giving;
Z
= 4/3a(a+1)(a+½) - 2ℓ(ℓ+½) - s(s+½) - 2a2(mn+½) -
2(ℓ+½)(mS+½) + (s+½)(mℓ+½)
Where
the Aufbau principle gives; 2a = n + ℓ + s + mn
12.
Single Electron Systems
Electro-magnetic
energy (E3) is; E3
= | p3|2 /m0 = Zp02/m0 = ZE0
For a
single electron system the fundamental energy (E0) is; E0 = -e2/2ε0r
Where; e
is the charge of a proton
-e is the charge of an electron
r is the average distance between an electron
and the nucleus
The energy
balance for a single electron system shall be;
(ET)(Eω)2
+ (Em)(E3)2 = 0
Where; ET
is the total energy of a single electron
system
Eω is the wave energy
Em is the particle energy
E3
is the electro-magnetic energy (assuming
the magnetic part is minimal)
The
energies have values as follows;
Eω = nhω
Em = ½ mv2
E3
=
-Ze2/2ε0r
Giving
total energy; ET = -(½ mv2)(
-Ze2/2ε0r)
If; v = rω
Then; ET = -mZ2e4/
8ε02n2h2
13.
Calculations for Multiple Electron Systems
The
following calculations demonstrate that the atomic number of an element is
related to its location within the stack. This may also be restated as follows;
the MSE identification number is a function of the quantum numbers of the MSE.
Example
1;
Titanium
has atomic number ; Z = 22.
The
Quantum Matrix for Titanium is;
M22 = 3
, 2 , ½
+½ , -1 , +½
The
aufbau number is;
2a = n + ℓ
+ s + mn
2a = 3 + 2 + ½ + ½
a = 3
The MSE
number is;
Z = 4/3a(a+1)(a+½) -
2ℓ(ℓ+½) - s(s+½)
- 2a2(mn+½)
- 2(ℓ+½)(mS+½) +
(s+½)(mℓ+½)
Z = (4/3)3(3+1)(3+½) -
2(2)(2+½) - ½(½+½)
- 2(9)( ½+½) - 2(2+½)(½+½)
+ (½+½)(-1+½)
Z = 56 - 10
- >½
- 18 - 5
+ - ½
Z = 22
Example 2;
Bismuth
has atomic number ; Z = 83.
The
Quantum Matrix for Bismuth is;
M83 = 6 , 1
, +½
+½ , +1 , +½
The
aufbau number is;
2a = n + ℓ
+ s + mn
2a = 6 + 1 + ½ + ½
a = 4
The MSE
number is;
Z = 4/3a(a+1)(a+½) -
2ℓ(ℓ+½) - s(s+½)
- 2a2(mn+½)
- 2(ℓ+½)(mS+½) +
(s+½)(mℓ+½)
Z = (4/3)4(4+1)(4+½) - 2(1)(1+½) -
½(½+½) - 2(16)( ½+½) - 2(1+½)(½+½) +
(½+½)(1+½)
Z = 120 - 3
- >½
- 32 - 3
+ 1 ½
Z = 83
14.
Dynamic Matrices
The
Atomic Stack is a 3D Periodic Table. It places the MSE of an element in a cell
determined by quantum numbers. For an element in the ground state the atomic
number is the MSE number.
For
any element not in the ground state, or for any ion, or for an atom bound within
a molecule, the matrix may be used to show the “location” (condition) of each
electron. It will be observed that some type of symmetry with respect to major
diagonals is required. This means that orbital magnetic moment (mℓ)
is a determining factor when locating dynamic electrons.
Dynamic
matrices may be a useful technique to represent molecular interaction, they will
not be discussed in detail.
15. Fundamental Principles of Chemistry
The
following fundamental principles of chemistry have an application to the
periodic stack.
The Aufbau Principle;
The
Aufbau principle states that generally an electron will occupy the lowest
energy state available. This principle also indicates the order in which
atomic orbitals are occupied. It is possible to quantify the Aufbau
principle using the matrix numbers (a, mn),
which indicate the filling order of atomic orbitals.
The Exclusion Principle;
The
Pauli Exclusion Principle states that no two electrons within the same atom may
have the same set of quantum numbers. This principle may be restated as no two
electrons of the same atomic system can have the same quantum matrix.
The Hund Principle;
The
Hund principle states that atomic orbitals must be half filled by electrons of
the same spin before an electron of opposite spin enters the orbital. This is
easily observed in the atomic stack which has the right side of an orbital with
positive spin and the left side with negative spin. The right side of a square
ring must be completely labeled before the left side can be labeled.
Madelung’s Rule;
Madelung’s rule states that the orbitals fill with
electrons as; n+ ℓ .
This rule may be expressed generally as; 2a = n + ℓ
+ s + mn
If mn = -
½ ; Then
; 2a
= n + ℓ
If mn = + ½
; Then
; 2a
= n + ℓ + 1
Atomic Limit ;
There
is no known theoretical limit to the size of an atom. Chemical reactions
with ℓ > 3 have not been observed. If we assume that
ℓ = 3 is the limiting value of the azimuthal quantum number, then
the limiting value of the aufbau number is forced to be a = 4. This
suggests an upper limit on the size of an atom of Z = 120. Heavy
elements degenerate quickly making it unlikely that element 120 could be
synthesized.
16. The Periodic Stack of Particles
The
sub-atomic particles may also be arranged as square matrices. The particles
within a matrix are arranged by “family” into “square rings” surrounding a
central “core”. The core contains only
force carrier particles. The lepton and quark families (including
anti-particles) are arranged as square rings surrounding their associated
bosons. The matrices may be stacked vertically to form the Periodic Stack of
Particles. Some cells within a matrix may represent unknown particles.
The Periodic Stack of Particles labelled by symbol;
Matrix 1 ; This
matrix contains four gluons only.
|
g2 |
g1 |
|
g4 |
g3 |
Matrix 2 ; The
core is four gluons which are surrounded by quarks and anti-quarks.
Anti-particles are underlined and occupy the lower half of the matrix.
|
s |
d |
u |
c |
|
b |
g6 |
g5 |
t |
|
b |
g8 |
g7 |
t |
|
s |
d |
u |
c |
Matrix 3 ; The core contains bosons
which are surrounded by leptons and anti-leptons. The outer ring may represent
unknown leptonic matter. Anti-matter is confined to the lower half of the
matrix.
|
? |
? |
? |
? |
? |
? |
|
? |
Vu |
Ve |
e- |
µ- |
? |
|
? |
Vt |
W- |
p |
τ- |
? |
|
? |
Vt |
W+ |
z |
τ+ |
? |
|
? |
Vu |
Ve |
e+ |
µ+ |
? |
|
? |
? |
? |
? |
? |
? |
Matrix 4 ; This 8x8 matrix is not
shown. The core shall be assumed to be four gravitons surrounded entirely by
unknown matter particles. If Higgs
particles exist, they may be located in this matrix.
17. Particle Quantum Numbers
The
numbers used to locate a particle within a matrix may be called “particle
quantum numbers” (pqn). Unlike the chemical quantum numbers, no known physical
characteristic may be associated with a pqn. The pqn's may also be arranged as
a matrix (MP) as
follows;
MP = q1 , q2
, q3
q1- ,
q2- , q3-
Matrix Identification (q1) ;
Each
particle matrix is identified by a pqm (q1) where; q1
= 1,2,3,4
The
concept of spin does not apply to a pqn, therefore the corresponding pqn is
arbitrary; q3
=
½
Quadrant Identification (q1- , q3- ) ;
One
half of each matrix is identified by a pqn (q1- ). The upper half of each matrix
is defined by ; q1- = ½.
The lower half of each matrix is defined by ; q1- = -½.
One
half of each matrix is identified by a pqn (q3-). The right half of each matrix is defined by ;
q3-
= ½. The left half of each matrix is defined by ; q3- = -½.
Together q1- and q3- define a quadrant of any
particle matrix.
Concentric Rings (q2);
Each
matrix may be viewed as a set of concentric square rings arranged around a
core. The core is the inner four cells.
Each ring is identified by a pqn (q2).
The core of each
particle matrix is defined by ; q2 = 0
The outermost ring of
each matrix is defined by ; q2 = q1 - 1
Displacement from Diagonal (q2- );
Displacement from a
major diagonal of a particle matrix is identified by a pqn (q2-
).
A cell on the diagonal
is defined by ; q2-
= 0
A column displacement is
defined by ; q2-
= positive
A row displacement is
defined by ; q2-
= negative
18. The Particle Number
Each
sub-atomic particle may be assigned a “particle number” (P) as an identifier,
similar in concept to the use of an atomic number (Z) as the identifier of a
chemical element. Some particle numbers are;
P
= 5 represents the up quark
P
= 6 represents the charm quark
P
= 15 represents the anti-top quark
P
= 31 represents the electron
P
= 37 represents the photon
P
= 49 represents the positron
The
P number is related to a particle's location within the stack, which is
determined by its pqn matrix (MP). The P number is related to a
particles pqn's as follows;
P
= (4/3)q1(q1+1)(q1+½) - 2q12(q1- +½) - 2q2(q2 +½) - 2(q2 +½)(q3- +½) + (q2- +½) - ½
The Particle Stack with cells labelled as Particle Numbers (P);
q1 = 1
|
2 |
1 |
|
4 |
3 |
q1
= 2
|
9 |
8 |
5 |
6 |
|
10 |
12 |
11 |
7 |
|
18 |
20 |
19 |
15 |
|
17 |
16 |
13 |
14 |
q1
= 3
|
28 |
27 |
26 |
21 |
22 |
23 |
|
29 |
35 |
34 |
31 |
32 |
24 |
|
30 |
36 |
38 |
37 |
33 |
25 |
|
48 |
54 |
56 |
55 |
51 |
43 |
|
47 |
53 |
52 |
49 |
50 |
42 |
|
46 |
45 |
44 |
39 |
40 |
41 |
19. Nomenclature
Constants;
h Plank’s
constant (fundamental angular momentum)
ħ h barred (ħ = h/2π)
i complex constant
-e dynamic charge of an
electron
e dynamic charge of a proton
ε0 permitivity of
free space
μ0 permeability of
free space
c speed of light in
vacuum
m dynamic mass of an electron
Quantum
Numbers;
q generic
quantum number
n principal
quantum number
ℓ orbital angular
momentum (azimuthal number)
s spin
angular momentum
mn principal magnetic moment
mℓ orbital magnetic moment
ms spin magnetic moment
a aufbau
quantum number
ma aufbau magnetic moment
Z atomic number and MSE
identifier for ground state
(s,p,d,f
) atomic orbitals (conforming to ℓ)
Matrices;
MZ quantum matrix
a Aufbau
number, identifier of a matrix of the atomic stack
Variables;
l wavelength
w frequency
v
velocity
p linear momentum
L angular momentum
F force
E energy
V
potential energy
20. References
1. Hervé Le Cornec
THE
DISTRIBUTION OF ATOMIC IONIZATION POTENTIALS REVEALS AN UNEXPECTED PERIODIC
TABLE
Chemistry
Preprint Server, Item 0201007, 9 January 2002
2. Charles Janet,
CONSIDERATIONS SUR LA STRUCTURE
DU NOYAU DE L’ATOME,
3. Maurice Kibler, T. Negadi
THE
PERIODIC TABLE IN FLATLAND
Intl.
Journal of Quantum Chemistry, Article 57, 53-61, 1996
4. Albert Tarantola
PERIODIC
TABLE OF THE ELEMENTS (JANET FORM)
Chemistry Preprint Server, Item
0009002, 9 September 2000
5. Eric R. Scerri
THE
EVOLUTION OF THE PERIODIC SYSTEM
Scientific
American, September 1998
6. Phillip S.C. Matthews
QUANTUM
CHEMISTRY OF ATOMS AND MOLECULES
7. Edward G. Mazurs
GRAPHIC
REPRESENTATIONS OF THE PERIODIC SYSTEM DURING ONE HUNDRED YEARS
8. Mark J. Winter
CHEMICAL
BONDING