The first picture of Enya has a white background.
If I make it transparent, her eyes and shirt will be transparent too.
The answer is to pick a different colour for the background, one that isn`t used in the picture.
Floodfill the white background with red or you could use dark blue, bright pink ect....
Open up the colour menu at the top of Page Shop Pro and follow the instructions below, making sure that the boxes are ticked the same as mine!
Press ok
Your picture won`t look any different, but to check it`s transparent,  click on the "View Palette Transparency" button.
If it`s worked your pic will look like this, if not you picked the wrong colour in the "Select colour from Palette" box so just change that part again, looking for the matching background colour.
Before                                   After