PHYS 127 Introduction to Modern Physics Laboratory

Photoelectric Effect

Student Name and I.D.: Peter

Lab session: Lab 2B

Submission Date: 28-2-2001

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1.      Introduction

One of the experiments that classical picture of electromagnetic waves is unable to explain is the photoelectric effect.

This experiment aims to determine experimentally the Planck’s constant and the Intensity dependence of photocurrent.

2.      Theory

Photoelectric effect is the emission of electrons by matter due to the action of incident light.

The voltage at which the current vanishes is called the stopping potential or the backing voltage and is related to the maximum kinetic energy of the photoelectrons by the energy relation,

mvm2 = eVo

where vm is the maximum vellcoity which any electron has when it leaves the photosensitive surface, Vo is the voltage at which the current is reduced to zero, and e and m are the charge and mass of the electron respectively.

In terms of the quantum or photon nature of light, each photo has an energy hν, where h is Planck’s constant and νis the frequency of the incident light. In the photoelectric effect all or none of the energy hνis transferred to an electron in the metal. Some of the energy the electron may acquire is used in escaping from the metal. This energy is called the work function and represented by Φ. The rest of the energy supplied by the photon goes into kinetic energy of the electron. From these considerations, we have the following relation:

 hν= ½ mvm2 + Φ = e Vo + Φ       ------------------------- [1]

3.      Procedure

The electrical connections shown in Figure 1 were made.

Figure 1: Electrical Connection For Measuring Planck’s constant

Part I: Determination of Planck’s constant

The equipment were setup as shown in Figure 2.

Figure 2: Arrangement of Apparatus for Part A

Figure 3: Optical part used in the experiment

The board band colour filter (a set of 6 shown in Figure 3) were placed one by one on the cell window. For each filter, with the backing-off voltage set to zero, the large signal on the electrometer was observer when the lamp illuminates the photocell. The magnitude of the signal was recorded. The backing-off voltage was gradually increased until the signal on the electrometer became zero and the wavelength of the filter and backing-off voltage were recorded.

The above steps were repeated with narrow band colour filter but the mercury lamp was used as light source.

Part II: Intensity dependence of photocurrent

The pinhole in the front of the photocell was inserted and mercury violet filter was inserted in front of the pinhole. The polarizers was then placed in front of the apparatus window, as shown in Figure 4.

Figure 4: Arrangement of apparatus for Part II

The backing-off voltage was set to be zero and the output voltage of the electrometer was adjusted. The polarizer angle was varied from 0o to 180o and the photoelectric current was recorded.

4.      Result and Analysis

Part A: Determination of Planck’s constant

For board band colour filter,

A graph of backing-off voltage versus frequency is plotted.

Figure 5: Backing-off voltage versus frequency (Board band colour filter)

The graph is a straight line. Hence backing-off voltage has a linear relation with the frequency.

From equation [1],        

Planck’s constant, h = slope x e = 0.2495 x 10-14 x 1.602 x 10-19 = 3.997 x 10-34 Js

Cut-off frequency, ν= 3.5 x 1014 Hz 

Work function = hν = 1.4 eV

For narrow band colour filter,

A graph of backing-off voltage versus frequency is plotted:

Figure 6: Backing-off voltage versus frequency (narrow band colour filter)

The graph is a straight line. Hence backing-off voltage has a linear relation with the frequency.

From equation [1],  

Planck’s constant, h = slope x e = 0.2858 x 10-14 x 1.602 x 10-19 = 4.58 x 10-34 Js

Cut-off frequency, ν= 3.488 x 1014 Hz

Work function = hν= 1.598 eV

Part II: Intensity dependence of photocurrent

The graph of the voltage of the electrometer versus polarizer angle is plotted. The cosine function is also plotted on the same graph.

Figure 7: voltage of the electrometer versus polarizer angle

Now consider,

Figure 8: Intensity versus polarizer angle

From the graph in Figure 8, the straight is not a horizontal, which is inconsistent with the expected result (a horizontal line). This is due to the error in photocell.

5.      Error Analysis

In Part A,

For Board band filter:

By Excel,

Δ h = (Δ slope / slope) x h

   = (0.0377 / 0.2495) x 3.997 x 10-34

   = 0.54 x 10-34 Js

Hence h = (4.0 + 0.5) x 10-34 Js

Δ Ф = (Δ y-intercept / y-intercept) x Ф

    = (0.2098 / 0.8733) x 1.4

    = 0.336 eV

Hence Ф = 1.4 + 0.3 eV

For narrow band filter:

By Excel,

Δ h = (Δ slope / slope) x h

   = (0.0237 / 0.2858) x 4.58 x 10-34

   = 0.38 x 10-34 Js

Hence h = (4.6 + 0.4) x 10-34 Js

Δ Ф = (Δ y-intercept / y-intercept) x Ф

    = ( 0.1397 / 0.997) x 1.598

    = 0.224 eV

Hence Ф = 1.6 + 0.2 eV

6.      Discussion

1)      The experimental value of the Planck’s constant is smaller than the accepted value (6.63 x 10-34). This is due to the error source in the experiment.

For board band colour filter, percentage difference = 26.32%

For narrow band colour filter, percentage difference = 10.46%

The data form the narrow band colour filters is more accurate than that from board band colour filters. This is because at higher wavelength, light is more capable to eject electrons.

2)      The theoretical value of the work function of Cesium is 1.9 eV. The experimental value is smaller than the theoretical one.

For board band colour filter, percentage difference = 26.32%

For narrow band colour filter, percentage difference = 15.79%

3)      When light falls onto the surface of a metal it can liberate electrons from the metal, forming a photoelectric current. When the intensity of the light falling on the cathode is increased, while keeping the wavelength constant, the greater intensity and corresponding greater electric and magnetic field strengths give some electrons more energy than they had before.

4)      The kinetic energy of the emitted electrons remains the same as long as the wavelength of the incident light is not changed. Increasing the intensity of the light serves only to increase the photoelectric current. Therefore light is quantized.

5)      In classical wave theory, the maximum kinetic energy should be proportional to the intensity of the radiation. Also, the photoelectric effect should occur for light of any frequency or wavelength. The first electrons should also be emitted in a time interval of the order of seconds after the radiation first strikes the surface.

The experimental results suggest the failure of the wave theory to account for the photoelectric effect. First, the maximum kinetic energy is totally independent of the intensity of the light source. Doubling the intensity of the source leaves the stopping potential unchanged, indicating no change in the kinetic energy of the electrons. Second, the photoelectric effect does not occur at all if the frequency of the light source is below a certain value. Third, the first photoelectrons are emitted virtually instantaneously after the light source is turn on.

7.      Error sources

Source of errors includes:

a)      The room is not dark enough. If the room is totally darkness, we will have difficulty in recording data.

b)      Errors in photocells, which is due to improper use from the previous users.

8.      Suggestions and improvements

Precautions:

1)      Do not place the filters directly in front of the mercury lamp. The lamp is very hot and will melt the filters if you do so.

2)      The cell window is covered by a black plate to prevent the cell from being exposed to the light directly when there is no filter in place. Direct exposure of the cell to any light may damage the cathode.

3)      Do not look directly at the mercury lamp. This may damage your eyes. As a precaution, block the mercury lamp when it is not being used.

Improvement:

1)      Use as less light for lamination as possible.

2)      Handle the equipment carefully. For example, do not touch the optical part of the filter.

9.      Conclusion

The Planck’s constant and the work function are found to be 4.58 x 10-34 Js and 1.6 eV. The cut-off frequency is found to be 3.488 x 1014 Hz. Also photocurrent depends on the intensity of light.

 

 

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