BEVERAGES

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Institute of Food Technology

BUNDELKHAND UNIVERSITY,Jhansi

 



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Coffee (Coffea)

Production

Processing

Chemical Composition of Coffee

Coffee Making: Vacuum coffee, Drip coffee, Percolator coffee, Steeped coffee, Espresso coffee, Iced coffee

Soluble Coffee

Acknowledgement : 

N. Shakuntala Manny

M. Shadaksharaswamy


 

Tea (Camellia sinensis)

Production

Processing: Black tea, Green tea, Oolong tea

Composition of Tea

Preparation of Tea

Instant Tea

Acknowledgement : 

N. Shakuntala Manny

M. Shadaksharaswamy


 

Cocoa (Theobroma cocoa)

Production

Processing  

Composition

Cocoa Beverages

Acknowledgement : 

N. Shakuntala Manny

M. Shadaksharaswamy


 

Soft Drinks

Ingredients: Sugars, Flavouring materials, Colouring materials, Acids and preservatives, Water, Carbon dioxide

Acknowledgement : 

N. Shakuntala Manny

M. Shadaksharaswamy


 

Fruit Beverages  

Fruit juice

Fruit drink

Fruit squash

Fruit cordial

Fruit juice concentrate

Sherbats

Acknowledgement : 

N. Shakuntala Manny

M. Shadaksharaswamy


 

Alcoholic Beverages 

Wines

Beer

Distilled Spirits

Acknowledgement : 

N. Shakuntala Manny

M. Shadaksharaswamy


 

BEER MANUFACTURING

Acknowledgement : 

Ret. Prof. B.K. Mital

FST, GBPUA&T, Pantnagar


 

 

 

 

 

BEVERAGES : Many liquids or liquorous foods, such as coffee, tea, cocoa, soft drinks and alcohol-containing drinks are considered as beverages. These contain stimulants or flavouring agents which perform some useful functions but are not essential for the proper functioning of the body. Soft drinks are non­alcoholic beverages containing syrup, essences or fruit concentrate that are mixed with water or carbonated water. The basis of all alcoholic drinks is ethyl alcohol or simply alcohol.  

 


Coffee (Coffea)


Coffee is an evergreen shrub or small tree indigenous to central Africa and Asia. There are many species of coffee, but three species are of commercial importance: Coffea arabica, which supplies the largest and best quality of coffee beans, Coffea robusta, (C. canephora) which yields beans of lower quality and Coffea liberica, whose beans are of still lower quality. C. arabica is indigenous to Ethiopia and was introduced to India through Arabia. It is cultivated in South India, mainly in the states of Karnataka, Kerala and Tamil Nadu. It is best grown in the American tropics, where Brazil is by far the largest producer and exporter of Arabica coffee.

Considerable quantities of C. robusta are also produced in India because the plant can be cultivated at a lower elevation, is longer living and disease resistant, and the yield of coffee bean is greater than from arabica. The robusta variety gives thick, strong decoction. C. liberica has not been popular in India as the tea plant is susceptible to diseases and the beans have not found favour in the market.

 

Production:   The world production of coffee is estimated at 6.4 million tonnes. The Indian production during 1997-98 was 223,000 tonnes and about 140,000 tonnes were exported bringing in foreign exchange of Rs. 390 million dollars. Though India's export is only about 3 per cent of the total world export; there is a good demand for Indian coffee because of its superior quality and use in blending. India, during 1981-82, occupied the second position in , productivity rating among the coffee producing nations, advancing from the previous fifth position. Coffee production is being introduced in the non­traditional areas of Andhra Pradesh, Orissa and the North-Eastern States. The yield per hectare increased from 609 kg in 1975 to 926.8 kg in 1998.

Coffee flowers are white and sweet smelling, producing green berries which turn red when ripe. The berry contains a mucilaginous pulp with two greenish grey seeds or beans, each covered by a thin membrane, the silver skin, and both are enclosed in a common husk-like membrane or parchament. Sometimes a single bean fills the berry instead of two, when the seed is called a peaberry, since it is like a pea. The berries are picked when ripe. Unripe berries give defective beans (Triage) and overripe ones are difficult to beat to a pulp.

 

Processing:   Coffee processing consists of removing the skin, pulp, parchment and silver skin. The quality of the final product depends upon the manner of processing. Two methods are employed for processing, viz., the dry and the wet (washed coffee process) methods. In the former method, the berries are sun dried by spreading them out on drying floors and the coverings are removed by hulling. The beans are later cured in curing sheds. The product obtained is known in trade as cherry or native coffee. In the wet method, the ripe fruits are squeezed in a pulping machine which removes the soft outer pulp, leaving a slippery exposed layer of mucilage. The mucilage is removed by spontaneous fermentation. This is sometimes facilitated with added enzymes. The seeds separating from the pulp are washed and subsequently dried to a moisture content of 12 per cent. The wet method gives better quality coffee with a bluish-green colour (green coffee). The green seeds are then graded and packed. Green coffee may be stored for prolonged periods with no adverse effects.

Each variety of coffee has its own flavour and other characteristics. Gene­rally, marketed coffee is a blend of different varieties of coffee beans. The blends are controlled for flavour, aroma, colour and strength or body of the beverage from the roasted bean.

Roasting: Raw or green coffee has no flavour or aroma and has an unpleasant taste. For use as a beverage, it is roasted, powdered and brewed and the aqueous extract used as a beverage with or without the addition of milk, sugar and other substances. During roasting many physical and chemi­cal changes occur. The beans swell in size to almost double their original size, the dull-green colour changes to brown and the characteristic coffee aroma develops. The beans lose their hard horny structure and become brittle, with the outer surface still smooth and firm. During roasting, pres­sure develops in the beans ,and this appears to be necessary for the proper development of coffee flavour. It is said that pressure holds the initial breakdown products together until the proper stage of roasting is reached, when they react with each other to produce coffee flavour. The flavour is due to a mixture of numerous components rather than a definite chemical entity and is apparently produced during roasting. Some moisture is lost during roasting and carbon dioxide is produced in a comparatively large quantity, some of it escaping and some being absorbed within the texture of the roasted bean. Carbohydrates decompose, caramalize and, perhaps in combination with other substances, contribute to the aroma of the beverage produced from the roasted beans. Fatty constituents are also affected, vola­tile fatty acids are driven off and complex fats and waxes are cracked to form simple ones. Proteins may be hydrolyzed and give cleavage products. There is little change in the caffeine content of coffee during roasting.

The flavour of roasted coffee, to a large extent, depends upon the manner and extent of roasting. The flavour and aroma of coffee are best. when it is freshly roasted and deteriorate on standing. Coffee exposed to air changes more rapidly than coffee not exposed. The staleness of coffee exposed to air is due to the oxidative changes that take place with certain coffee con­stituents. This is prevented by the presence of carbon dioxide in roasted coffee. On storage, carbon dioxide is lost and so are the flavour and aroma. Moisture also has a profound effect on the flavour of coffee. Coffee exposed to moisture loses all its flavour in a relatively short time. The loss of flavour in vacuum packed coffee or coffee packed under pressure using carbon dioxide is less. Since the loss of flavour and aroma is more in ground coffee than in beans, the roasted beans should be freshly ground to obtain quality coffee. In spite of many investigations, it has not been possible to clearly understand the many complex physical and chemical changes taking place during the roasting of coffee beans.

 

Chemical Composition of Coffee: The constituents of coffee that are important in making a good beverage are the flavour substances, the bitter substances, and caffeine which is responsible for the stimulating effect of the drink.

Caffeine is present in the coffee bean in both the free and combined states. Its content in the bean varies in different species-C. arabica contains 1.0-1.2; C. robusta 1.5-2.5 and C. liberica 1.4-1.6 per cent. There is a variation in the amount of caffeine in the seeds of the same species from different parts of the world., Caffeine, in addition to stimulation, also contri­butes to the bitterness of the coffee. The caffeine content of a cup of coffee (150 ml) is about 100 mg. Most people consume three cups of coffee a day and thus 300 mg of caffeine. While caffeine is a stimulant, its excess use causes undesirable effects on mental and physical health. It is as much a health hazard as alcohol and nicotine. Chronic caffeine intoxication results in a number of symptoms (caffeinism) which include sleep disturbance, frequent urination, muscular tension, jitteriness, anxiety, etc. Thus, many people who like the taste of coffee but are afraid ot adverse health effects of caffeine use decaffeinated coffee. By chemical methods, most of the caf­feine can be removed from green coffee. Decaffeinated coffee retains most of the characteristic aroma of coffee. The average composition of green and roasted C. arabica beans is given in Table.

Composition of green and roasted C.arabica beans (g for 100 g coffee):

 

Moisture

Protein

Fat

Sugar

Dextrose

Ash

Caffeine

Chlor ogenic acid

C. arabica(green)

8.98

9.87

12.60

9.55

0.87

3.74

1.08

8.46

C. arahica(roasted)

0.63

11.23

13.59

0.43

1.24

4.56

0.82

4.74

Source: Wealth of India, Vol. II, Council of Scientific and Industrial Research (CSIR), New Defhi, India, 1950, p. 299.

Several organic acids are present in the aqueous extract from green coffee beans, the predominant being chlorogenic acid and the least acetic acid. During roasting, formic and acetic acid contents are increased and chlorogenic and other acids like citric and malic are partially destroyed. The pH of the coffee brew comes down. Acidity affects coffee flavour, the more acid tasting the coffee, the better are its flavour and aroma. Robusta beans produce coffee beverage that is less acid-tasting than the arabica-coffee beverage and is generally less desirable so far as taste is concerned.

As already indicated the flavour of roasted coffee is due to a number of components to which the name "coffeol" has been given. More than 600 volatile compounds have been identified in roasted coffee. Low-boiling sulphur compounds in coffee are the main flavour contributors. Chlorogenic acid contributes to the body and astringency of the coffee beverage, and its decomposition products contribute to the aroma of coffee. The decomposition products of sucrose contribute much to the colour of the beverage and also to some extent the aroma, bitterness and sourness. Protein decomposi­tion compounds seem to be the major precursors of coffee aroma.

Polyphenolic substances (tannins) present in coffee contribute to the bit­terness of coffee beverage. They are readily soluble at the boiling tempera­ture of water. There are also present in coffee other substances, extracted on boiling, that contribute to the bitter taste and combine with certain metallic salts to give a metallic flavour to the beverage.

 

Coffee Making: Coffee, fresh from the roaster and ground fresh, makes a good beverage. If it is not possible to roast coffee fresh, it is better to buy small quantities of the powder and keep it covered to exclude air and moisture. The beverage is at its best when freshly brewed. If it is cooled and reheated, it become bitter and unpleasant.

Coffee is ground and marketed to meet a range of brewing methods. The basic grinds are fine, medium and coarse. A variation can be found within each of these categories. Fine grind is used in vacuum coffee makes; medium or drip grind is used for making coffee in a drip pot or by steeping; and coarse grind is used in a percolater. It is always best to match the grind to the coffee making equipment to obtain a good quality beverage.

Preparation of coffee beverage of high quality requires that the extraction of caffeine and flavouring materials be maximum and that of tannin minimum. Different methods are used to obtain this object. The methods differ in the type of utensils used and the ground coffee, but they are all based on the principle of bringing ground coffee in contact with hot water to extract the soluble constituents. Whatever the method employed, the ves­sels used to prepare coffee must be very clean. The material used for coffee making is important. Some metals influence the flavour of the beverage. Stainless steel, glassware and enamelware are preferred. Water used in coffee making should be soft or of low hardness. A temperature between 8S° and 9S°C is optimum for preparing coffee. If the water is heated to boiling point, it over-extracts soluble solids and the beverage is bitter, and there is also a loss of flavour substances. However, pouring boiling water on the coffee powder is permissible, as the temperature drops as soon as the water comes in contact with the grind.

 

Vacuum coffee: Vacuum coffee is made in a two-part container. The upper compartment holding the coffee has an open tube that extends to the bottom of the lower compartment containing water. By heating water in the lower compartment, sufficient pressure is created in the bottom container to force water through the coffee grind into the upper compartment. When the water and grounds are in contact for about 3 min, the heat is reduced on the lower compartment resulting in a reduced pressure and the brewed coffee is pulled down to the bottom compartment. Powdered coffee is usually pre­vented from pouring into the lower compartment by the use of cloth covered disk, held in place over the tube opening. The advantage of vacuum coffee is its convenient preparation; its disadvantage is that the coffee prepared thus is slightly bitter because the water and grounds are in contact for a few minutes at a high temperature.

 

Drip coffee: Drip coffee is made in a dripolator (coffee filter) consisting of an upper compartment which is perforated and a lower compartment which receives the filtered coffee. The perforation of the upper compartment is covered with a thin cheese cloth or a perforated disc with a stem, to prevent the passage of the grind into the beverage. Drip grind coffee is placed in the upper compartment and boiled water poured into the compartment. The water drips or flows through coffee into the lower compartment. The drip method is easy and is used by a majority of persons. This method extracts less of the bitter substances and retains more flavour constituents than other methods.

 

Percolator coffee: Percolator coffee is made by placing coarse ground coffee in a basket suspended in a stem near the top of the percolator and is inserted into the percolator. Cold water is placed in the lower part of the percolator and heated. The heated water is forced up the tube of the perco­lator and sprays on the grounds, extracting the soluble materials. The usual percolation time is 6 to 8 min. Percolator coffee is likely to be somewhat bitter because very hot water goes through the grounds several times. Also, the constant aeration of the, brew as the liquid is forced up and sprayed over the grounds results in the loss of flavour.

 

Steeped coffee: This coffee (misnamed as boiled coffee) is made by heat­ing water and medium ground coffee, without allowing it to boil. If coffee is boiled it becomes bitter. Steeping time is about 6-8 min. During steeping, the coffeepot should be lightly covered to prevent loss of volatile flavouring compounds. The coffee is then passed through a strainer. This method of making coffee is convenient, since no special equipment is required. If care is taken not to boil it, the beverage will have goad aroma, desirable flavour and will not be bitter.

 

Espresso coffee: This is made by a special machine which brews the beverage a cup at a time. It is derived from brewing finely ground coffee with a mixture of steam and hot water.

 

Iced coffee: This is made by pouring a freshly made strong coffee infusion over crushed ice. The infusion is obtained by using more of coffee grounds per cup. This offsets the dilution that takes place as the ice melts in the hot beverage, resulting in a pleasing beverage with a distinctive flavour. .

 

Soluble Coffee: Soluble coffee is a dry, powdered, water-soluble solid made from very strong coffee brew. It is marketed as "instant" and "freeze-dried" coffee. Instant coffee is made by the vacuum spray drying of the brew from the ground coffee, obtained from the percolation method. Freeze-dried coffee is made by first freezing the strong brewed coffee and then drying by vaporization in vacuum. Instant coffee has a flavour similar to freshly brewed coffee but lacks the aroma of the fresh beverage. At­tempts are being made to improve aroma by using additives. Freeze-dried coffee is being obtained in granulated form, the particle size being roughly that of ground coffee. Attempts to recover the volatile aromatic substances lost during the processing of the coffee brew and adding them to freeze­dried coffee to obtain a product with an aroma similar to that of freshly brewed coffee have been successful. Though India is producing and export­ing instant coffee, we have not yet made freeze-dried and granulated coffee. The world export of soluble coffee amounts to around 300,000 tonnes of green coffee equivalent.

Chicory (Cichorium intybus) is a well-known substitute for coffee, often used blended (up to 50 per cent) with the latter, in liquid coffee extracts. It gives a bitterness to the beverage, which some people find refreshing. The part of the plant used is the root which is chopped, roasted and ground.


Tea (Camellia sinensis)


Camellia is an evergreen shrub or tree, which grows wild from India to China. There are about 45 species of Camellia of which Camellia sinensis, considered native to India; is the important one from which tea of commerce is made. Commercial tea is obtained from plants propagated by seed sown in a nursery; cuttings can also be rooted. Trees for plucking are regularly pruned to obtain a bush shape, which encourages maximum leaf production. Amongst cultivated C. sinensis there are two types: `China' and `Indian'. The former type is a slow-growing smaller tree with narrow leaves, while the latter is fast growing with large drooping leaves. The yield from Indian types is higher than that of the China type. The important tea growing countries are India, China, Sri Lanka, Japan and Kenya.

Tea leaves are usually plucked by hand. The average interval between pluckings is about a week. In India, about 5-6 pluckings are made in a season. Usually, the terminal bud and two terminal leaves from the end of each shoot are plucked. In some cases, the bud and three leaves are taken giving a higher yield and a poorer quality product. Some of the best teas come from high-altitude areas, such as Darjeeling, while teas from the plains are often of `common' quality. The yield at high elevation is poor compared to that at lower elevation for the same kind of plant.          .

 

Production:   In India, the two main tea-growing regions are the hilly districts of Assam and West Bengal, and the Western Ghats of Kerala, Tamil Nadu and Karnataka. India tops the list in production and export of tea, in the world. In 1998, the world production of tea was 2.96 million tonnes of which India's share was 0.87 million tonnes. Of the total world export of about 1.13 million tonnes during that year, India exported 203,000 tonnes valued at Rs. 990 crore. The tea exported from India is mostly black tea and the export of green tea is small. However, large quantities of tea waste and fluff (pieces of leaves, leaf hair, fibre, etc.) are exported and used for the manufacture of caffeine. India has also been exporting consumer tea packets instead of bulk tea chests and instant tea.

 

Processing: Commercial tea is available mainly in three forms­ black tea, green tea and oolong tea. The three forms of tea differ only in the method of processing the leaves. Black tea is by far the most popular among the three.

 

Black tea:   The various processing steps in the manufacture of black tea are withering, rolling, fermentation, drying, grading and packing. Wither­ing is carried out by spreading tea leaves thinly on racks or shelves, to dry the leaves partially. Generally withering is allowed till the water-content in the leaf is lowered by about 40 per cent. The withered leaves are then rolled to break open the cells and release the juices and enzymes. Various rolling techniques are employed and the flavour characteristics inherent in various teas partially depend on the technique used. After rolling, the leaves are shifted and spread out thinly on suitable platforms and allowed to ferment for 2-6 hours at temperatures between 21° to 27°C. During this process, the enzymes bring about the oxidation of the various polyphenols present in the juices, resulting in the change of colour from green to reddish copper. Two of the important polyphenols that undergo oxidative changes are catechin and gallocatechin.

When the fermentation has proceeded to the desired degree, further change is arrested by drying or firing. This comprises the passing of the fermented leaves through a chamber in which hot air is circulating,; At the entrance of the chamber, the temperature is 93°C which drops to about 49°C near the exit. The time required for this process is about 3U-40 minutes and the dried product contains 3-4 per cent moisture. Besides halting the fer­mentation process, firing causes some caramelization to occur resulting in the characteristic colour of black tea leaves.                                                                                      .

The aroma of tea is believed to develop during the fermentation and firing processes. Although a large number of volatile compounds have been identified from tea leaves, none has -been found to make any significant contribution to the tea aroma.

The dried product is cleaned and sorted into various grades of tea of commerce. The quality of black tea is related to the polyphenol and enzyme content of the leaves used in processing. They are maximum in the buds and the first and the second leaves (28, 28 and 27 per cent respectively) and teas obtained from these are the most desirable. On this basis, tea is categorized as "leaf' grade and 'broken' grade. The broken grade comprises the smaller : sizes sifted from bulk or those obtained by cutting the longer leaf grades to desirable sizes. Both leaf grade and broken grade are further categorized as orange pekoe, pekoe and souchang. Orange pekoe and pekoe refer to the size of the leaf only. Orange pekoe has the largest leaves, followed by pekoe and souchang in decreasing order. Orange pekoe is perhaps the best quality.

Other things being equal, the broken grades usually give a stronger tea than leaf grade. Besides the above grade, there are the waste products­ Fannings and Dustings.

Tea is generally blended before it reaches the consumer. In India, the blended tea is packed in plywood boxes lined with aluminium foil and parchment paper. During packing, tea absorbs moisture. If the moisture content increases to 6-7 per cent, tea is to be subjected to a second firing before packing. India is also exporting tea in consumer tea packs instead of bulk tea chests.

 

Green tea: Green tea is made in the same manner as black tea, but the withering and fermentation steps are omitted. The leaves are heat treated, rolled and dried. The heat treatment consists of pan-firing or steaming to inactivate the enzymes. The aroma, flavour and colour of green tea are significantly different from those of black tea. Green tea is a light, yellow­green beverage when brewed correctly. The Japanese mainly produce and consume green tea.

 

Oolong tea: Oolong tea is an intermediate between black and green tea in colour and taste characteristics. Its production method is similar to that employed for green tea, except that the leaf is slightly withered and light fermentation allowed before the leaf is dried.

 

Composition of Tea: The important constituents of tea contributing to the flavour of tea beverage are caffeine, polyphenols and essetial oils. Analysis of fresh leaves of Indian tea gives the following values: Polyphenols, 22.2; protein, 17.2; caffeine, 4.3; crude fibre, 27.0; starch, 0.5 and ash, 5.6 per cent. Fresh tea leaf also contains carotenes, B -vitamins and ascorbic acid. During the manufacturing of black tea, ascorbic acid is lost.

The maximum amount of caffeine is present in the bud and the first two leaves. Small quantities of compounds related to caffeine, viz., theophylline, theobromine, xanthine and hypoxanthine are also present.

The important polyphenols present in tea leaves are catechins and gallocatechins. These undergo changes during fermentation in black tea manu­facture. Enzymes involved in fermentation are polyphenol oxidases.

No change takes place in green tea as its manufacture does not involve fermentation. During fermentation, polyphenols undergo oxidation and the oxidized products polymerize and part of them combine with caffeine. The caffeine-polyphenol complexes are soluble only in hot water and this accounts for the 'creaming' observed when hot tea infusions are cooled.

Tea leaves contain a volatile oil consisting of alcohols, aldehydes, phenols and some fatty acids. On steam distillation, black tea gives an essential oil. The characteristic aroma and flavour of tea is due to the essential oil.

Tea, like coffee, has no nutritive value. The proteins present in tea leaves are rendered insoluble in the processing. Tea infusion contains negligible quantities of carbohydrates and fat. Whatever nutritive value tea has comes from added milk and sugar. Tea as a beverage is consumed mainly for its stimulating value.

 

Preparation of Tea:    A good cup of tea will be sparklingly clear and not have a surface film. It should have maximum flavour with minimum polyphenoi compounds which contribute to bitterness. In order to obtain this, the water used in making tea should be fresh and soft. If water is hard, the dissolved salts form an undesirable precipitate with polyphenols and this will be present as an unattractive film that floats on the surface of tea. The water should be freshly boiled but still contain sufficient oxygen to give the tea a fresh and pleasant odour. Metallic teapots impart a metallic flavour. It is best to use china, glass or enamelled ware. Water heated to 85°C to boiling should be added to the appropriate amount of tea (generally one teaspoonful for 150 ml contained in the pot). The pot should be covered with a lid which helps retain the heat and prevents the escape of volatile compounds. Flavour substances and caffeine are readily extracted by: short infusion periods. Generally, a steeping period of about 3 min gives a stimu­lating, but not astringent, beverage.

A very convenient method of making tea is by -the tea-ball or bag method. In this method, water at the boiling -temperature is poured over tea con­tained in a cheese cloth or paper bag or a silver ball. The bag or ball is allowed to remain in contact with water till-the desired strength is obtained. Milk or lemon may be added to the tea infusion-for body and flavour, and sugar for taste.

 

Iced tea: Iced tea is popular in some countries. Hot tea is prepared in the usual way by using twice as much tea leaves. The hot tea-is thoroughly chilled before pouring it over ice. It may also be poured over ice while it is still hot. This will result in a beverage which dilute to normal strength as ice melts. Cloudiness is generally a problem with iced tea, as tannins precipitate when tea cools.

 

Instant Tea: Instant tea (soluble tea) products have become popu­lar in recent times. These products are hot and cold water solubles, iced tea concentrates, carbonated tea, etc. In the preparation of hot water soluble instant tea, the fermented tea leaves are extracted with hot water, centri­fuged and dried in drum drier or freeze drier. For the manufacture of cold water soluble tea, the aqueous extract is cooled to 5°C, the separated caffeine-polyphenol compound is removed by centrifugation and then dried. Iced tea concentrate is cold water soluble and contains sugar, citric acid and essences. Ready tea is instant tea with sugar and milk powder. India pro­duces all these varieties of instant tea and sizeable quantities are exported. The export in 1980-S1 was 10.76 million kg.

Instant tea is largely used in making iced tea because of its solubility in cold water. However, the flavour and aroma of instant tea is less full than that of the beverage freshly prepared from tea leaves.  

 

 


Cocoa (Theobroma cocoa)  


Cocoa plant is a small tree native to the American tropics. It is now grown in all tropical regions of the world. The chief cocoa-producing countries of the world are Ghana, Nigeria, Ivory Coast and Brazil. Cocoa was introduced to India from Sri Lanka and is a comparatively new crop. Its production is fast picking up and it is grown in Kerala, Karnataka and, to some extent, in Tamil Nadu.

Cocoa tree has the unusual habit, like the jackfruit tree, of bearing its flowers and, subsequently, its pods on the main trunk as well as on the branches. Cocoa pods, when mature, are yellow in some varieties and red in others. The pods are 10 to 18 cm in diameter, having thick leathery rinds containing 20-50 beans inside in rows. The seeds are embedded in white or pinkish pulp. Seeds are the principal source of cocoa or cocoa powder highly prized as a nutritious beverage, and chocolate used as food all the world over.

 

Production: The world production of cocoa is of the order of 2.9 million tonnes. India's output in 1997-98 was only 6,000 tonnes. The demand for cocoa products till recently was mainly met by imports. We have been importing about 1,000 tonnes of cocoa bean a year and some of the imported cocoa is re-exported as cocoa powder, chocolates, cocoa butter, etc. We are becoming self-sufficient and are at the stage of discontinuing imports.

 

Processing: Cocoa pods, after harvesting, are cautiously opened. The beans and mucilage are scooped out and subjected to natural fermentation either in heaps, wooden boxes (sweat boxes) or baskets. Fermentation generally takes five to ten days. At the end of fermentation, the pulp breaks down and there is a change in the colour of the seeds from pale yellow or violet to brown. The endogenous enzymes, activated by the heat of fermen­tation, bring about changes in proteins and polyphenols in the kernel and there is also a reduction in the astringency of the kernel. The beans are then dried to six to eight per cent moisture level in sun or in artificial dryers. The bean is then ready for export or further processing to manufacture cocoa products.

The dried beans are cleaned, sorted and roasted. Roasting develops the characteristic flavour. Although a large number of compounds have been identified in cocoa and chocolate, no single constituent is found responsible for the characteristic subtle aroma. Roasting also causes changes in the chemical structure of polyphenols, producing less astringent compounds. While roasting, the beans are passed through corrugated rollers to break their shells and removed by winnowing. The cotyledons are known as 'nibs'. Usually there is some blending of the nibs from different varieties of cocoa before they are processed further.

The nibs are used for the manufacture of cocoa and chocolate. The nibs are ground using stone mills or other suitable mills to a fine paste or liquor. The heat produced during grinding causes cocoa fat to melt and the melted fat carries with it, in suspension, finely ground particles of cocoa. This is known as "cocoa mass", "chocolate liquor" or "bitter chocolate". This mass solidifies at about 30°C.

Cocoa mass is very rich (50-55 per cent) in fat and cannot be used directly for the preparation of any beverage. It is subjected to filter-pressing to separate out a major part of fat (cocoa butter). The amount of fat left in the pressed cake can be varied by the conditions of pressing. The pressed cake is used for producing cocoa powder. The fat-content of cocoa used- for beve­rage is fixed by law. According to Indian Standards Institution (ISI) specifica­tions, cocoa used for beverage should contain 20 per cent cocoa fat. Medium-fat cocoa, containing between 10 and 20 per cent fat and. low-fat cocoa, containing less than 10 per cent fat are made. Flavouring substances like vanilla and cinnamon are generally incorporated into cocoa powder.

The pressed cake, after the removal of cocoa butter, contains 1.8-1.13 per cent free acids. In one of the methods of cocoa processing the acid is neutra­lized with the addition of a requisite amount of alkali. This is known as the "Dutch process", because it originated in Holland. Cocoa processed by this method is dark in colour and the flavour will be somewhat more bitter and astringent than the same material not treated with alkali.

 

Chocolate:   Cocoa mass not treated with alkali is generally used for the manufacture of chocolate. There are many types of chocolate depending upon the level of cocoa mass, added cocoa butter, sugar, milk and other ingredients. Plain chocolate (sweet chocolate) is cocoa mass processed with cocoa butter and sugar. Milk chocolate contains, in addition to these ingre­dients of plain chocolate. milk solids. Plain chocolate contains 44-55 per

cent sugar and 32-42 fat, while milk chocolate contains 35--55 per cent sugar, 28-39 per cent fat and 12 per cent milk solids. Plain and milk choco­late are extensively used in confectionery and ice cream.

 

Composition: The analysis of cocoa beans (processed) gives the following values: moisture 2.13; fat, 54.68; total nitrogen, 2.16; starch, 6.14; pentosesans, 11.19 and tannins 6.15 per cent. The total nitrogen includes that of protein, theobromine and related alkaloids. The theobromine content of cocoa is hgh (about 2.8 per cent). Cocoa is the natural source of theobromine. There is some loss of theobromine content during fermentation and roasting. Cocoa also contains caffeine (about 0.6 per cent). The proteins of cocoa bean are present in combination with polyphenols. Unlike coffee and tea, which are strained forms of beverage, cocoa and chocolate remain in the beverage and contribute to the nutritive value of the beverage. Because of their high content of fat, cocoa products are good source of energy. Milk, a usual constituent of cocoa and chocolate drink, adds to the nutritive value of the beverage. The theobromine and caffeine contribute to the stimulating effect of the beverage.

 

Cocoa butter:   Cocoa butter which accounts for more than 50 per cent of cocoa bean is a valuable byproduct of the cocoa industry. The world trade in 1979 in cocoa butter was of the order of 175,000 tonnes. The butter is mostly used in the manufacture of chocolate.

The butter is a pale yellow liquid with a characteristic odour and flavour of chocolate. It is brittle at temperatures below 25°C, softens in the hand and melts (34°C) in the mouth. It is not greasy to touch. It is rich in saturated fatty acids (palmitic and lower acids 26.21, stearic and higher acids 34.4 per cent). Oleic and linoleic acids are present to the extent of 37.3 and 2.1 per cent respectively. The butter keeps well due to the presence of fat-soluble antioxidants in it.

 

Cocoa Beverages: Cocoa and chocolate, apart from their many uses in cooking; find extensive use in the preparation of beverages. When chocolate is used, it sticks to the container and gets scorched when heated. This can be eliminated by heating chocolate over hot water or by heating it at a low temperature. The melted chocolate is then blended with other ingredients. Owing to its high starch content, cocoa will lump if put directly into a hot liquid. It should be mixed with a small amount of cold liquid before-being combined with other ingredients. Cocoa and chocolate thus treated are heated to boiling and held at that temperature for sometime to gelatinize the starch. This gives body and flavour to the beverage and reduces the amount of sediment that settles from either of the beverages.

Apart from coffee, tea and cocoa, a number of preparations are available in the market such as Ovaltine, Bournvita, Boost etc., which are consumed as hot drinks. While the former group of beverages are stimulants the latter are energy foods and are consumed as supplementary foods to regular diet. They. contain mainly malted cereals, creamy milk, sugar and artificial flavour, and sometimes are fortified with nutrients and minerals. Some preparations also contain cocoa. The drink is prepared by stirring the mate­rial in warm water or milk and is generally consumed as hot drink; but could also be used as a cold drink.  

 


Soft Drinks


Soft drinks constitute one of the largest food industries in the world today. Tremendous advances have taken place in process technology in the soft drink industry in the past one or two decades.

In India, in the organized sector alone, annual production of soft beve­rage is about 45 million cases. The flavoured component of most of the well-known brands of soft drinks is a well-guarded secret. The most popular soft drinks sold throughout the world today are `cola' (an extract from the tree cola), orange, root beer, ginger, lemon and lime. Most of the cold drinks sold in the country belong to this class.

Soft drinks are divided into three classes: the carbonated, fruit flavoured (still) and sparkling (soda water). The carbonated beverages, in turn, are divided into two groups, those with artificial flavour and those with natural fruit juice.

 

Ingredients: The major ingredients of soft drinks are: 

(i) sugar and sugar substitutes 

(ii) flavour emulsion and cloudifiers 

(iii) colouring agents 

(iv) acids and preservatives 

(v) water 

(vi) carbon dioxide 

A quality soft drink should have a balanced blend of flavour at the proper intensity leaving a clean mouth taste with no lingering flavour or unpleasant after taste and should have proper carbonation to impart zest and sparkle to the drink.

The process of manufacturing carbonated beverages consists of several steps. Syrup is prepared from sugar or substitutes and water. To the syrup, acids, colour and flavouring agents are added as required. The components are blended. A suitable aliquot of the mixture is diluted with chilled car­bonated water and bottled. Alternatively, ready syrup is diluted, chilled, carbonated and then filled in the bottle. The bottles are then capped, labelled and marketed.

 

Sugars: Sugar and sugar substitutes contribute the sweetness necessary to balance the various ingredients, give body and mouth feel and also act as carriers to distribute the flavour components uniformly throughout the drink. Sugar component also contributes to the food value of the beverage and, to some extent, to the flavour. Sucrose is the most widely used sweetening agent. Some sweetening agents like cyclamates which were being used formerly are now banned as they are found to be harmful. Because of the high cost of crystalline sugar, sugar syrups are used as sweeteners. Fructose syrup (processed from corn starch) or high fructose corn syrup (HFCS) are used these days. 55 per cent fructose corn syrup has approximately the same sweetness as sucrose, while 90 per cent fructose syrup is approximately 50 per cent more sweet than sucrose. Use of fructose syrup in soft drink manu­facture has other advantages; it permits substantial reduction in calorie content of the drink and it also reduces the cost of the drink. Fructose syrup is not yet available in India.

 

Flavouring materials: Three types of flavouring materials ate used in soft drinks: those obtained from natural sources, such as fruit concentrates or extracts from natural flavour materials; synthetic compounds identical to those obtained from natural products; and synthetic chemicals not found in nature. Most flavours, however, are wholly natural or a blend of natural and synthetic materials identical to those found in nature. The flavouring agents should have complete solubility, compatibility, clean mouthfeel without an after taste, resistant to acid and heat, and stable to light. Flavours are used generally emulsified in vegetable gums. This prevents the flavour substances (particularly oils) from separating out in the beverages.

 

Colouring materials: These are used in soft drinks in order to maintain a uniform colour in the beverage from batch to batch. In some cases colour is derived from flavouring substances used. Generally, synthetic food colours and natural colouring ingredients like caramel are used. Caramel in beverages gives them a dark to light brown colour and is usually associated with flavour of the type derived from roots, leaves, herbs and berries.

 

Acids and preservatives: Acids, in addition to taste, enhance the flavour of soft drinks. The acid most widely used is citric acid. Other acids used in considerable quantities are tartaric and phosphoric acids. Lactic and Malic acids are also used in lesser amounts. Citric acid (present in citrus fruits) adopts itself well to nearly all light and fruity flavours. Phosphoric acid is used in beverages with leaf, root, nut or herbal flavours.  Tartaric acid (present in grapes) is used in grape flavours.

The acids, besides giving taste and flavour, also act as mild preservatives. However, to ensure against spoilage, sodium benzoate is commonly used as a preservative.       

 

Water: Water constitutes the largest (about 92 per cent) component of soft drinks. Water used in beverage manufacture must be free from suspended matter and colouring matter. It should not contain minerals which would interfere with the flavour and colour of the beverage. It should also be free from objectionable odours. Thus, water used should conform to the specification set for beverages.

 

Carbon dioxide: Carbon dioxide is an important constituent of soft drinks. The gas used must be absolutely pure. It enhances the flavour of the beverage and gives it its sparkle. It also extends the life of the drink. The level of carbonation is determined by the flavour component and quality of flavour.

Carbonated beverages are mostly packaged in bottles. In some countries they are also packed in cans with a pull ring top. Besides glass bottles and cans, plastic containers (polyethylene terephthalate, PET) are coming into use. Glass bottles are covered with crown lined with PVC or cork. In recent times, glass containers are being covered with a foil lid.

 

 


Fruit Beverages  


There has been a considerable increase in the consumption of fruit and vegetable juices in the world during the last few years and there are pos­sibilities of its further increase. The export of fruit juices from developing countries has more than doubled during the period 1977-82. India exported Rs.10 crore worth of fruit juices in 1982.

The beverage industry is by far the largest outlet for fruit juice and concentrates absorbing over 80 per cent of production. In India a little over 60 per cent of the fruit produced is used in fruit based beverages. Many different types of beverages, such as fruit juices, fruit drinks, squashes, cardials and fruit punches, are available. They are broadly defined as follows: 

Fruit juice: This is a natural juice pressed out of a fruit. This is unaltered in its composition during preparation and preservation.

Fruit drink: This is made by liquefying the whole fruit and at least 10 per cent of the volume of undiluted drink must be whole fruit. It may be diluted before being served.

Fruit squash: This consists essentially of strained juice containing moderate quantities of fruit pulp to which sugar is added for sweetening, e.g., orange squash, lemon squash, mango squash, etc.

Fruit cordial: This is fruit squash from which all suspended material is completely eliminated and is perfectly clear, e.g., lime juice cordial.

Fruit punches: These are made by mixing the desired fruit juices at the time when it is served.

Fruit juice concentrate: This is fruit juice which has been concentrated by the removal of water either by heat or by freezing.

Sherbats: This is a cooling drink of sweetened diluted fruit juice.

 

Fruit juices are valuable from the nutritional point of view; they are rich in minerals, vitamins and other nutritive factors. Besides, fruit juices are delicious and have a universal appeal, In developed countries fruit juices commonly form part of the breakfast and are produced in very large quantities. (In the USA, the annual production of juices is more than 50 crore kilo litres.) Fruit juices do not form the normal diet in our country and the fruit juice industry is in its infancy in India. Preparation of the juice is limited mostly to home scale production. The fruits generally used for making juice are orange, grape, apple, pomegranate, melon, mango, etc. Of late, the manufacture of squashes on a commercial scale has made some progress.

Fruit juices are best in taste, aroma and colour, when freshly expressed. The most important problem, therefore, in the fruit juice industry is to use such methods as would help retain these properties to the maximum extent. The steps involved in the processing of juice are selection of fruit, extraction of juice, deaeration, straining and preservation.

Freshly picked, sound and suitable varieties of fruits are selected and thoroughly washed. The juice is extracted by crushing and pressing the fruits; while extracting the fruit juice, fruit components other than sacs or cells in which juice is present are to be avoided as far as possible. Further; the juice should not be unduly exposed to air. The juice (particularly pure orange juice, which is susceptible to the action of air) is immediately deaerated by subjecting it to a high vacuum. Afte, deaeration, the vacuum is released with nitrogen gas, the juice is transferred into containers which are hermitically sealed and frozen. Fruit juices-in sealed containers keep well for about 2 years in the frozen condition. In the alternative, the fruit juice is spray dried.

When clear juice is required, the juice is strained and complete removal of all suspension is effected by filtration and clarification. Clarification needs the removal of colloidal suspensions of the fruit juice. This can be brought about by freezing, heating, use of enzymes or of finning agents. The finning agents produce a voluminous flocculant precipitate which gradually settles, carrying down with it colloidal suspensions. The clarified juice, as in the case of whole fruit juice, is preserved by freezing, pasteurization or the addition of chemical preservatives, such as sodium benzoate or bisulphite.  

 


Alcoholic Beverages


 

Alcoholic beverages have been known since antiquity. These are judged in terms of flavour and stimulant effect and hardly at all as sources of calories. However, the calorific value of alcohol in 7 Kcal/g and excess of alcohol consumed could add to the total calorie intake of a person. In the case of distilled liquors (whisky, brandy, gin and rum), the calorific value is only due to alcohol and consu ption of 10(l ml of these, beverages would yield about 230 Kcal of energy and wine contain some nutrients present in the original malted barley and the fruit juice used in their preparation and naturally their energy value would be higher than that of distilled liquors; 350 ml of beer gives about 150 Kcal and 100 ml of wine about 80 Kcal.              Alcohol is absorbed without prior digestion but the body has limited capacity to oxidize it. That is the reason why alcoholic beverages are to be sipped instead of gulping them. As a drug the effects of alcohol vary from mild stimulation, when small amounts are consumed, to loss of coordination and even death when large amounts are consumed.

There are three main classes of alcoholic beverages-wines, malted beverages (beer) and distilled liquors. Different starting materials and different methods are used in their manufacture. But there is one common characteristic in all of them, namely, they are made by the process of fermentation. The essential step in all the fermentation processes is the conversion of glucose into alcohol by yeast.. The enzymes present in yeast catalyze the breakdown of glucose.

                    Yeast enzymes

C6H1206  --------------------------------> 2C2H5 OH + 2C02

 

Wines:   Wine is the oldest of the alcoholic beverages made by the fermentation of grape juice. Wine, strictly speaking, is a product of vine, but often includes all fermented liquors obtained from different fruit juices (fruit wines). Wines differ greatly in their character, because grapes grown in different regions differ in their composition, particularly with respect to their volatile components which contribute to flavour and bouquet and in the method used for wine making.

There are different varieties of wines and in many cases they are named by reference to their place of origin, e.g., champagne is produced in the district of Champagne in France. Most of the wines produced in the world  are natural and still (without excess of carbon dioxide). Sparkling wines, such as champagne, contain excess of carbon dioxide due to the secondary fermentation that occurs after bottling. The carbon dioxide generated is stored within the liquid under its own pressure and gives the wine a 'sparkle'. Some wines like port and sherry are fortified wines and differ from natural wines in that some alcohol (grape brandy) is added to them before the completion of fermentation. Vermouth is also a fortified wine prepared by the addition of spice mixtures or their extracts at various stages during fermentation.

Wines also differ in their colours. The colour of wine may be white or red. However, the colour does not depend on the colour of the grapes from which it is made; in fact, white wines may easily be made from black grapes by using only the juice. In making red wines both juice and skin are used; the pigment giving colour to the grapes lies just under the skin and is extracted from it during fermentation. Wines may be either 'dry' or 'sweet' depending upon the extent to which the fermentation has taken place. If fermentation has taken place until all the sugars are used up, the resulting wine will be dry, whereas if it is stopped while some sugar remains, it will be sweet. Yeast cannot tolerate an alcohol content greater than 16 per cent. Most of the natural wines contain 8--10 per cent alcohol. Fortified wines contain about 20 per cent alcohol, which is sufficiently high to kill the micro­organism that attack natural wines. Wines containing less than 14 per cent alcohol are table wines while those which contain more are dessert wines.

In the manufacture of wine, grapes are picked at the proper time when the sugar and acid contents are in the right proportion. The composition of the grapes varies according to the climatic conditions prevailing during their cultivation and thus the quality of wine varies from one year to another. Therefore, there is the practice of 'vintage dating' the wine with the year of the crop from which it is made. Immediately after picking, in the case of red wines, the grapes are crushed and the juice together with he skin, pulp and seeds are transferred to the fermentors. After fermentation is completed, the fermented juice is pressed out. In the case of white wines, pressing takes place before fermentation.

'Wild' yeast and other microorganisms are present on the skin of the grapes and these pass into the juicy pulp (known as must)  when the fruit is crushed. These are destroyed by adding sulphur dioxide (or potassium metabisulphite) in the required quantity. If the sugar content is low, sucrose is added to the desired strength and the pH is adjusted to 3.2-3.4 by the addition of tartaric acid. Next, the must is inoculated with a pure culture of actively growing yeast (Saccharomyces ellipsoideus). The temperature and duration of fermentation depend upon whether dry or sweet wine is required. Fermentation usually lasts 4 to 10 days.

When fermentation is complete, the clear wine is syphoned from the yeast sediment into barrels (raking) and the wine allowed to age. During this period secondary fermentation takes place and the wine also loses its raw and harsh flavour and mellows down. During this period of maturation clarification takes place in the natural way.  It can also be achieved by finning and filtration. Next, the wine is bottledand allowed to mature; the time of this maturation extends to a number of years depending upon the quality desired.

Wines are also made from juices of other fruits and berries. Cider is fermented apple juice. The method of fermentation with fruit juices other than of grapes is almost similar to that of preparation of grape wine.

 

Beer: Beer, next to wine, is the oldest alcoholic beverage to have been made. There is evidence to show that fermented beverage from barley existed in Indus Valley civilization about 5,000 years ago and in China, Egypt and other cultures even earlier. The first brewery in India was started in 1860; in 2000, there are 55 breweries and the beer production is about 50.7 million hectolitres, which is very insignificant compared with a world production of 120 billion hectolitres in the same year. It is projected that world consumption will be 180 billion litres in 2001-2010. The chief beer producing countries in the world are USA, FDR or Germany, USSR, UK and Japan.

The term beer is normally applied to a beverage made by the fermentation of barley malt. However, terms like ale, stout, lager and porter are also used for beer, the difference between them being the method of production. The materials used in the manufacture of beer are barley, malt, cereal adjunct, hops, water and yeast. The principal operations involved in the production of beer are malting, mashing and fermentation.

The starting material for the production of beer is bareley malt.

Starchy materials that are cheaper than malt are used as 'adjuncts' to replace some malt. The most commonly used cereal adjunct is maize in the form of grits or flakes. Other adjuncts suitable for brewing are broken rice, wheat, raw barely, tapioca, starch and sorghum. Such adjuncts should not impede the fermentation process or have an undesirable effect on the quality of the product. The entire starch of the adjunct is to be converted into sugar. Thus, the percentage of adjunct that can be added is restricted by the amount of enzymes in the malt. The introduction of microbial enzymes has increased the flexibility of varying adjunct proportion, as these enzymes supplement malt enzymes. They also reduce the cost of raw material and maintain the quality of beer. Liquid syrup adjuncts can also be used, but they are yet to enter the brewing field in India.

Hop (Humulus lupulus) is a vine native to Europe and ' Western Asia. During the early 1970s, hop growing has been introduced to Kashmir and successfully cultivated. Varieties grown in Kashmir have satisfactory brewing quality regarding bitterness but are low in flavour. From about the 15th century, beer is being flavoured with hop. The part used in brewing is the female 'cone' consisting of a cluster of pale, yellowish green bracts and bracteoles enclosing the flowers and later the fruits. Hop contains essential oils and resins which impart the characteristic bitter flavour and pleasant aroma to beer. It also destroys the enzymes and helps sterilize the brew before fermentation.

Suitability of water for brewing is of great importance in beer making. Water should be hard; if soft, salts are added to the required hardness. If the water is too hard, it may have to be boiled to remove most of the temporary hardness.

The yeast used depends upon the type of beer to be manufactured. For the production of ale, "top fermentation" systems are used with the yeast Saccharomyces cerevisiae. In top fermentation, the yeast is carried to the top of the fermentating vats by rapidly evolving bubbles of carbon dioxide. For the production of lager, the "bottom fermentation" system is employed with Saccharomyces carlsbergensis. During fermenlation, the yeast settles at the bottom of the vats.

In the manufacture of beer, the malt is 'mashed', i.e., the ground malt is steeped in hot water in vessels called mash tun. Two mashing methods are generally employed: infusion mashing, followed in India, and decoction mashing. In infusion mashing, hot water at 65.5°C is mixed with ground malt to the consistency of porridge. Cereal adjuncts (gelatinized) are added to the malt grit. Sugar syrups, if desired, are also added at this stage. The period of infusion is about 2 hours and the temperature is maintained at 65.5°C. During this period, malt amylases degrade starch in aqueous solution to produce sugars approximately in the following ratios: 7-10 per cent monosaccharides, 48-55 per cent disaccharides, 12-15 per cent trisaccharides and 20-30 per cent dextrin. By regulating the mashing conditions, the proportion of various carbohydrates can be varied to suit the requirement of the beer to be brewed. When steeping is complete, the extract, known as 'wort' is filtered off through barley husks which settle on the perforated false bottom of the mash tun.

    The wort is then boiled with hops. This boiling destroys the malt enzymes and sterilizes the wort. The essential oil and bitter substances of hops are extracted and the proteins are coagulated. The coagulation of protein assists in clarifying the beer. The liquor is filtered through spent hops which retain the precipitated materials. The liquor, when cold, is seeded with yeast and allowed to ferment for a few days during which time sugars are converted into alcohol. When the fermentation is complete, the beer is allowed to stand for 1 or 2 days when yeast settles down.

After fermentation, the beer is run off to storage tanks for maturing when secondary fermentation takes place and the flavour and bouquet of beer develop. The maturing process varies from only a few days for mild beer to several months for strong beer: Next, the beer is pasteurized or sterile filtered and bottled or canned, with the introduction of carbon dioxide under pressure.

Variation in the quality of beer, such as the strength of alcohol, colour and extractives, depends upon the quality of malt, malt adjuncts used, mashing method, amount of hops added and the condition of fermentation. Beer, ale, porter and stout are beverages produced by top fermentation, while lager beer is a product of bottom fermentation. Ale is made like lager but is usually stronger in hop character and contains a higher alcohol content. Porter is a heavier and darker drink made with longer dried, roasted, or caramelized malt with less hops. Stout is like porter except that it has heavier malt flavour much darker than any other malt drink. It has a stronger hop taste than porter. The alcohol content of various beers varies from 2.5 to 7 g per cent. Beers produced in India contain 4--5 per cent alcohol and have a calorific value of about 30 Kcal per 100 ml.

Saki is Japanese beer, which is made entirely from rice. Whole grain rice is soaked until it is quite soft and then steamed. The steamed rice is partially dried by spreading on straw mats. It is then inoculated with a yeast-like mold and after 10-14 days, the completely fermented material is filtered. This fluid is placed in barrels to settle. After a few days, the clear liquid is withdrawn and pasteurized giving Saki. It contains about 17 per cent or more alcohol by volume.

 

Distilled Spirits: Distilled spirits are made by distilling fermented liquors. Whisky is made by the fermentation and distillation of fermented cereal grains, brandy from wine and rum from fermented molasses. Gin is a distilled spirit flavoured with juniper (Juniperus communis) berries or some other aromatics. Distilled liquors usually have 40 per cent alcohol and thus have excellent keeping qualities. Usually, distilled liquors, other than gin, are allowed to mature before consumption, e.g., whisky is matured in wooden caks for 5-15 years to become smooth and mellow.

An essential stage in making spirits is distillation. The liquid obtained by fermentation from different materials contains dilute alcohol and is con­centrated by distillation. Originally, distillation was carried out in a pot still. To obtain a concentrated alcoholic liquor, the distillation in a pot still has to be repeated a number of times. To overcome this disadvantage, continuous distillation stills have been developed. In spite of this development, pot still distillation is still used for making the finest whiskys, brandies and other renowned spirits. Pot still allows many of the volatile components which contribute characteristic and subtle flavours to the drink to pass over with the alcohol during distillation. The best of brandies, cognac, is made by distilling twice in a pot still.

For the preparation of gin and vodka, and for fortification of any other beverage with alcohol, a colourless and tasteless spirit is required and this can be obtained by distillation in a continuous still. Dilute alcohol from any source when distilled in a continuous still can give 95 per cent alcohol. Such alcohol is very pure and has only the odour and flavour characteristic of alcohol. Such alcohol is known as neutral spirit (silent spirit).

    Whisky is made using different cereals. Scotch malt whisky, the original whisky, is made from malted barley and scotch grain whisky from barley malt and other unmalted cereal grains. US whiskys are generally made from rye (straight rye whisky) and maize (straight maize whisky). Canadian whisky is made from maize, wheat, rye or barley. Irish whisky is made from malted barley alone or with a mixture of unmalted barley, wheat, rye and oats.

In the manufacturing process, the grain is converted into beer except for the omission of hops and is distilled to obtain a distillate containing 80 per cent alcohol by volume. It is then diluted with water and stored in charred barrels. After the desired period of aging, the whisky is adjusted to the required alcohol strength and bottled. The characteristic flavour of scotch whisky is said to be due to the fumes from the peat used for firing malt kilns and the characteristics of the water used.

Brandy can be made from any fruit. Generally, `brandy' refers only to the distillate from grape wine. Grape wine obtained from selected grapes is completely fermented using pure cultures of yeast and distilled. The brandy obtained is stored in oak casks and is allowed to age in a damp storage building for as long as 20 years.

Rum is an alcoholic beverage distilled directly from fermented sugarcane products, such as sugarcane juice, syrup or molasses. The rum obtained by distillation is stored in either charred, plain or reused barrels or vats. Rum readily improves in character and flavour with aging. After aging, the strength of alcohol is adjusted to 40 per cent and bottled.

Gin is produced by diluting neutral spirit with distilled water so that the alcohol content is 60 per cent. This is distilled in a pot still in the head of which are placed juniper berries and other aromatics. During distillation, the alcohol water vapour extracts the flavouring principles. The distillate is then reduced to the required alcohol strength by the addition of water and bottled. No aging is required for gin; in fact, it may be harmful as the essential oils in gin may decompose with time.

Vodka is a distilled liquor without any identifying characteristics except that of dilute alcohol. It is free from all traces of colour and flavour. Vodka is made by diluting neutral spirit obtained from wheat or other cereal grains or potato.

Liqueurs are products obtained by steeping herbs, fruits, flowers or plants in neutral or distilled spirits and distilling the resulting produce. To the distillate, sugar is added to the extent of 2.5 per cent. As a rule, liqueurs are sweet, and caramel colour or other colouring may be added. Liqueurs like Benedictine, Drambuie, Creme-de-menthe are obtained this way. The recipes of most liqueurs are closely guarded secrets.

 



       

   BEER MANUFACTURING: 

 

1. MALTING

       2. BREWING

MALTING is the process of controlled germination followed by controlled drying of barley. Such conditions are provided so that the enzymatic requirements of raw material reaches to its optimumum level.

BREWING (production of malt beverages) is the combined process of preparing beverages from grains that have undergone sproughting and fermentation  of the sugar solution by yeast where a portion of the carbohydrate is converted to alcohol and CO2.

Raw materials use in beer manufacturing : cereal grains like barley, wheat, rice, maize etc.

The complex starches and proteins in these grains must be changed to a more readily usable mixture of simple carbohydrates and amino acids. Process involves germination of the barley grains and activation of their enzymes to produce a malt. The malt is then mixed with water and the desired grains(adjuncts), and the mixture is transferred to the mash tun or cask in order to hydrolyze the  starch to usable carbohydrates .Once this process is completed ,the mash is heated with hops (dried flowers of the female vine  Humulus lupulis which are originally added to the mash to inhibit spoilage  micro organisms. The hops also provide flavour and assist in clarification of the wort. In this heating step, hydrolytic enzymes are inactivated and the wort is inoculated with the desired yeast for fermentation.

INGREDIENTS OF BEER

  1. Water: portable 
  2. Barley & malt:- Malting is basically the initiation of germinating process carrying it to a desired end point and then applying hot air to dry and stabilize the germinated grain so that the enzyme activity that has developed is preserved. Malt is an excellent source of α-amylases.
  3. Adjuncts:- additional source of cheaper carbohydrate to be acted upon by amylase. e.g. corn, corn syrup, corn sugar, rice, sorghum grits, barley, low protein wheat flakes .
  4. Hops: plant material impart bitterness and is a source of tannins, resins & essential oils.
  5. Brewer's Yeast: Saccharomyces cerevisae, Saccharomyces carlsbergensis

 BEER CONSTITUENTS

  1. water: 90%

  2. Alcohol: vary from 4-8%, in general 2.5-5.0%

  3. Carbohydrates (unfermented): 4%, include mono, di or tri polysaccharides

  4. Inorganic  compounds: Chlorides, sulfates, bicarbonates of Mg & Ca: 0.8%

  5. N- compounds:  0.3%

  6. Organic acids: 0.2%

  7. CO2 : 0.5%

  8. Other compounds: 0.2%.

Most beers are fermented with bottom yeast, related to Saccharomyces  carlsbergensis  which settle at the bottom of the fermentation vat. Beer flavour is also influenced by production of small amounts of glycerol and acetic acid. Bottom yeast produce beer with a pH is 4.1 to 4.2 and require 7-10 days of fermentation.

With a top yeast such as Saccharomyces cerevisiae, the pH is lowered to produce ales. Freshly fermented (green beers are aged or lagered and when they are bottled, CO2 is usually added. Beer can be pasteurized at 140oF or higher or sterilized by passage through membrane filters to minimized flavour changes.

BARLEY

  1. Not used for direct human consumption.
  2. Mostly used as barley malt for beer production.
  3. Added in some special foods such as Bournvita, Maltova, Boost etc. as source of sugar & energy.
  4. Rest is used for cattle feeding, because of fibrous nature.

General requirements:

1. Clean, sound, undamaged grains free from mould are used for beer manufacturing.

2. Moisture content of grains should be <12%.

3. Germination percentage of grains should be >90%.

4. Low protein & high starch content grains are desirable.

5. Husk of grains should be thin as required for proper hydration.

Process of beer manufacturing

    Preliminary Steps

a) Drying of Barley: reduces moisture content up to 10-14%

b) Cleaning & Grading

c) Storage : 3 month  storage period is required to break dormancy of grains.

 

I)   MALTING

II)  BREWING PROCESS

1.      Milling

2.      Mashing

3.      Lautering

4.      Wort Boiling & Cooling

5.      Cold Wort Aeration & Yeast Pitching

6.      Fermentation

7.      Aging & Finishing

v     Flavour maturation

v     Carbonation

v     Standardization

v     Chill proofing

v     Clarification

8.      Packaging

v     Filling

v     Pasteurization

 

MALTING

a) Steeping  of  barley 

b) Draining and spreading over malting floor  

c) Germination, under controlled conditions

  ENZYMES either synthesized or activated during germination.

d) Drying / klin drying: Preserves enzymatic activities as they depend on 

temperature and moisture content.

high temperature of drying gives dark colour product - dark beer

        e) Screening: remove shootlets & rootlets 

 

BREWING

      MILLING

       Mixing of Malt & other ingredients (Hops).

 

MASHING

 Process by which malt & malt adjuncts are dissolved, heated  & digested. A number of biochemical changes occur in presence of enzymes.

     

 

 

 

Carbohydrates- α & β amylases

Phosphatase- release inorganic phosphorus from organic compounds eg. Phytate

Some proteases- active only in early stage of germination.

Mashing Temp 50 - 70°C and  pH  5.0 – 5.

Temp of mashing influences enzymatic activities (specifically α & β amylase) and also control alcohol content.

Higher temp- greater  α & β amylase activities results more dextrins & low alcohol

Low temp-  less dextrins & high alcohol

When α  amylase is fvoured and β amylase is inhibited , dextrins accumulate at the expense of maltose .

Therefore, by selecting temp , the ratio of sugars to dextrins is maintained.

 

 

 

During the kilning of malt , activities of the synthesized enzymes are drastically reduced with the exception of α & β amylase.

Phosphorylase (in embryo), attacks on 1 – 4 links and starch chain is shortend at non-reducing end by one unit (phosphorylated) of glucose .

α- glucosidase (in embryo), attacks  on 1 – 4  or  1 – 6 linkage and  starch chain is shortend by one units of glucose.

α & β - amylases yield a carbohydrate product with a carbon bearing its hyroxyl group at α or β positions respectively.

 

α- amylase is a metallo-enzyme, and is an endo-enzyme

β- amylase is a thiol– enzyme, and is an exo-enzyme

 

Activities of α and β- amylases

a) ATTACK ON STARCH CHAIN

α-amylase acts randomly (except near chain ends and branch points)

β- amylase cutts off maltose units from non–reducing ends

b)  GLUCONOSIDIC LINKS ATTACKED

α- amylase: at 1-4 linkage

β- amylase: at 1- 4 linkage

c) PRODUCTS OF ATTACK

α - amylase: produces mainly dextrins, few sugar

β- amylase: produces maltose (mainly), branched dextrins

d) PRODUCTION OF REDUCING GROUPS

α - amylase: one per attack

β- amylase: one per attack

e) PRODUCTION OF NON – REDUCING ENDS

α - amylase: one per attack

β- amylase: one per attack

f) GENERAL REQUIREMENTS  

α - amylase: calcium ions

β- amylase: reducing conditions to maintain thiol groups  

g) INHIBITORS

α - amylase: calcium sequestrants

β- amylase: heavy metals & Na- idoacetate

 

h)  OPTIMUM  pH for activities

 

α- amylase: 5.5

β- amylase: 5.2

i)  OPTIMUM TEMPERATURE FOR MOST RAPID ACTION

α - amylase: 70OC

β- amylase: 60OC

j) PRESENCE BEFORE GERMINATION

α - amylase: not present in mature barley grains, begins to form during germination.

β- amylase: present in mature barley grains but become active enzyme during germination.

LAUTERING 

involve process of filtration and separation of sweet wort from spent grains.

WORT  BOILING 

HUMULONES « ISOHUMULONES « ALLOISOHUMULONES

Cooling 

Hot trub/Hot break- Insoluble flocculants material formed during kettle boil.

Cold trub/Cold break- Material soluble at high temperature but precipitates on cooling 

Cold wort Aeration and yeast pitching  

Yeast growth and fermentation rate depend on the initial presence of some dissolved oxygen. since dissolved oxygen is expelled from wort during kettle boil, it must be replaced and this is done by saturating to 100% . It is equivalent to oxygen saturation at about 20%. At this initial conc. of O2, achieved fermentation rate is at its max level. Therefore acts as growth factor, not involve in respiration.

Pitching- Inoculation of cooled wort with yeast culture. 

FERMENTATION

 A. Lagar fermentation    

B. Ale fermentation

Aging and finishing

Low temperature storage  for 30-35 days results:

Many more interaction between compounds takes place.

Flavor maturation: Young or green beer is stored or lagared in vats at about 0°c for several weeks to several months, during this period precipitation of yeast, protein, resins, and  other undesirable substances take place and beer become clear and mellowed or matured.

Ester and other compounds are produced to add to the taste and aroma, and the body change from harsh to smooth.

 

Carbonation: CO2 is incorporated @0.4 to 0.52 %

Traditional method: by means of gas, collected during fermentation.

Mechanical process: by mechanical means.

Standardization: Blending process, to obtain desired level of alcohol in beer.

Chill proofing & stabilization: Done to remove proteins, which tend to precipitate at lower temperature 0-3 oC and cause cloudiness /haze.

It is done by using:

1. Clays and silica hydrogel

2. Polyphenol absorbent such as polyvinyl polypyrolidne (PVPP)

3. Gallotennin (tannic acid)

4. Enzymes- like pepsin

As a general rule beer is chilled at 0oC at the end of this treatment.

Clarification

It is done to remove insoluble materials by 

1. Centrifugation

2. Fining- collagen is used

3. Diatomaceous earth

4. Filtration

Packaging operations

 

Types of beer

Draft beer: fresh unpastuerized beer kept cool until served.

Lager beer: Lagern (German word i.e. to store)

Ale beer

Porter beer

 

Defects in beer

1. Diacetyl content: >0.2 ppm gives unpleasant taste.

2. Metallic taste: >0.1ppm Fe, >0.2 ppm Cu, >2 ppm Al 

    Precipitation of Al – haze formation

3. Light struck beer: Exposure to sunlight develops unpleasant taste.

 

4. Oxidized beer: due to oxidation of polyphenolic compounds.

5. Medicinal odour: due to formation of ortho-dichlorophenol compounds, even 6 ppb amount can develop unpleasant taste.

6.Grainy harsh/astringent taste: because of incomplete fermentation of grains. 

7. Turbidity

Biggest problem caused by unstable proteins, protein tannin complex, resin or microbial activities.

a) Gluten/ Albumin Turbidity

Occurs at low temperature.

Due to high protein content barley / barley malt.

Disappear on warming.

b) Oxidative Turbidity/ Haze

O2 stimulate formation of protein tannin complex.

CO2 minimize or eliminates turbidity.

C) Starch Turbidity

Caused by Incomplete conversion of starch.

d) Yeast Turbidity

    Due to Incomplete clarification.

 

e) Resin Turbidity

Due to presence of insoluble resin , not removed as hot/ cold trub.

f) Microbial Turbidity

Due to microbial contamination.

Some proteolytic enzymes are added after fermentation during chill proofing to eliminate the problem of haze.

Microorganism associated with haze formation

Gram +Ve bacteria

Lactobacillus delbruekii

Pediococcus cerevisiae

Micrococcus varians

Gram -Ve bacteria

Acetobactor suboxygens

Gluconobacter suboxygens

Yeast

Candida utilis (fat producer)

Pichia membranefeciancs

Bretanomyces bruxellansi

Hansenuala anomla

8. Faulty beer- due to

a) low grade raw material in mash

b) poor quality hops

c) contact of beer with Fe of the can


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