Introduction to Acids And Bases

The chemical formula of pure water, as you know is H2O. Pure water may dissociate into equivalent amonts of H+1 ions and OH-1ions. Hence, water is considered to be neutal. These two ions the H+1 and the OH-1 ion are what causes solutions to be either acid or basic.

When a solution has more H+1 ions in solution than OH-1 ion., the solution is considered to be acidic.

When a solution has more OH-1ions in solution than H+1 ions, the solution is considered to be basic or alkaline.

These two concepts are the basis of the Arrhenius theory of acids and bases.


Acids

Vinegar, orange juice Pepsi, & battery fluids are all examples of acids. What are the properties of acids?

When an acid dissociates or dissoves in water H+1 are released

HA -----------> H+1 + A-1

as shown in this picture


Bases

Common bases are baking soda, antacids, borax, some cleansing agents. What are the properties of bases?

A base dissociates in water to produce the hydroxide (OH-1) ion.

MOH ----------> M+ + (OH)-1
where M represents any metal ion


Her's a small list of some acids and bases and where they may be found and/or use

Common Name Formula and name Use &/or Product
Battery acid H2SO4
sulfuric acid
Car batteries
Citric acid C6H8O7 Orange and other fruit juices
Vinegar CH3COOH acetic acid Salad dressings
Muriatic acid HCl
hydrochloric acid
Cement cleaner and neutralizer
Phosphoric acid H3PO4 Coke and Pepsi.
Antacid Mg(OH)2 & Al(OH)3
Magnesium & aluminum hydroxides
Maalox
Oven cleaner NaOH in foam
sodium hydroxide
Easy-Off
Ammonia cleaner NH3 in solution Amex cleaner
Drain cleaners & openers NaOH & KOH
sodium& potassium hydroxides
Drano, Liuquid Plumber
Baking Soda NaHCO3
sodium bicarbonte
for cooking and neutralizing acids


The pH Scale

Definition: the pH of a solution is the negative logarithim of the hydrogen ion concentration. The hydrogen ion concentration is measured in moles per litre .
The formula is pH = - log[H+1 ] . See page 297 .

Converting pH values to concentration values and back again will be dealt with in class. Its a "calculator thing".

The pH scale is a range of values from 0 to 14, with 0 being the most acidic and 14 being the most basic. A pH of 7 is considered neutral (the pH of pure water is 7). Acids have low pH while bases have large pHs. a chart of pH's can be seen below or on page 296 of your text book.

Indicators

Indicators are chemicals that have a certain colour based on the pH of the solution that they are in. Hence if the pH is allowed to change the colour of the indicator will also change.
The five indicators that you may see are as follows
  1. litmus paper, red and blue
  2. phenolphthalein
  3. bromthymol blue
  4. methyl orange
  5. methyl red
Here's a diagram indicating their colour ranges at ph's ranging from 0 to 14. Make sure you read the chart carefully so that you don't mix up the indicators.
More are shown here than the five listed above.
Note: the white you see in the chart does not mean white it means colourless


Formation of acids and bases

from metallic and nonmetallic oxides click here

From the "R-Files"

And a wrap-up note from Miss Rossini