PROCEEDING
OF THE INTERNATIONAL CONFERENCE ON
EUROPEAN
ENVIRONMENTAL POLICY
“THE ENVIRONMENTAL and PUBLIC HEALTH PROBLEMS DUE TO TAILING PONDS OF COPPER MINE IN LEFKE, CYPRUS
Prof
Dr. Fethi DOĞAN
Ege
University Faculty of Medicine Department of Public Health, IZMIR-TURKEY
This
report had been prepared on the basis of the other instructor’s analysis for
the invitation of Environmental Protection and Presentation Society of Lefke
which informed to Turkish Republic of Northern Cyprus Government, on November
1999. Investigations and collecting the samples had been carried out during
three days and then the samples had been analyzed at Ege University.
After
literature searching, the following articles were obtained:
§
According to the
publication, dated June 6 ,1963,written by Turkish Cypriot Worker Association,
it had been reported that Silicosis being a member of Pneumoconiosis as a type
of lung illness had increased dramatically, therefore, indemnity payments had
been increased 50% in ratio.(1)
§
At the committee
meeting, carried by Dr. Fazıl Küçük’s presidency, of Cyprus Mine
Company, in 1967, it had been asserted that the mine dust had damaged
extremely to the citrus fruits especially lemon flowers and trees, therefore,
it had been stated that they would be unproductive in ten years and also
damages had been seen for last four years. The major concern of the meeting
had been the request of indemnity payments to the producers because of
decreasing in the orange product from 20 million in 1962 to 6 million and 4
million in 1963 and 1964 respectively.(2)
§
A committee had been
set up by Agricultural Division Agricultural Research Institute in 1970 for
searching of this Copper mine dust deposition on vegetation at Lefke, and the
leaf analysis had been done at Agricultural Division Chemical Research Centre
and also at State Laboratory. As a result, deposition of the mine dust on
leaves, decreasing in dimensions of fruit and trees, badly effecting in
colour, taste and quality of fruits had been determined.(3)
§
It had been stated in
the report, dated June 9th 1999, prepared by Environmental
Protection and Presentation Society of Lefke, sent to Mr. Mustafa Akıncı,
State Minister and Deputy Prime Minister, that the heavy metals in Gemikonağı
Gölet’s water had been found in very high ratio and besides some of them
had reached to 15-17 times higher than their own standard values according to
the water analysis carried by state Laboratories.(4)
Table
1: Results of Analysis (The Report prepared by Halil Çağnan, KKTC State
Laboratory Directorship, Director of Radiation and Environment Analysis, dated
October 28th,1999)
Location |
Sample |
Amount
of Sample For Analysis |
Al (mg/Kg) |
Cr (mg/Kg) |
Cu (mg/Kg) |
Fe (mg/Kg) |
Mn (mg/Kg) |
Vegetation
samples collected form CMC |
Şifa
otu 1 |
2.5770 |
195.03 |
15.50 |
63.72 |
|
39.43 |
Şifa
otu 2 |
2.7391 |
185.28 |
16.53 |
75.32 |
|
38.92 |
|
Pire
otu 1 |
2.3499 |
207.41 |
3.24 |
77.28 |
|
27.55 |
|
Pire
otu 2 |
2.3497 |
213.01 |
10.42 |
58.60 |
|
32.14 |
|
Gabbar
1 |
3.3694 |
48.97 |
0.79 |
7.13 |
70.04 |
|
|
Gabbar
2 |
3.5786 |
43.59 |
0.65 |
7.37 |
60.58 |
28.11 |
|
Ayrelli
1 |
2.3219 |
44.02 |
1.02 |
3.34 |
|
8.66 |
|
Ayrelli
2 |
2.2343 |
43.13 |
0.86 |
3.90 |
|
9.38 |
|
Akasya
1 |
2.3048 |
115.80 |
1.25 |
11.34 |
96.93 |
43.65 |
|
Akasya
2 |
2.3749 |
89.39 |
1.20 |
11.26 |
96.68 |
43.24 |
|
Ayrık
otu 1 |
2.0807 |
149.71 |
2.11 |
6.07 |
164.51 |
63.44 |
|
Ayrık
otu 2 |
2.1228 |
204.02 |
3.26 |
46.17 |
164.83 |
42.91 |
|
Kuzu
otu 1 |
2.0349 |
234.56 |
6.51 |
5.32 |
163.74 |
69.14 |
|
Kuzu
otu 2 |
2.0045 |
391.47 |
2.87 |
9.14 |
226.29 |
66.99 |
|
Çatırez
1 |
2.0403 |
64.11 |
1.33 |
0.42 |
52.10 |
12.86 |
|
Çatırez
2 |
2.0178 |
63.14 |
2.25 |
17.55 |
180.74 |
17.44 |
|
Vegetation
Samples Collected Form Assumed Clean Area |
Şifa
otu 1 |
2.3119 |
618.11 |
32.05 |
7.43 |
0.33 |
14.78 |
Şifa
otu 2 |
2.3905 |
684.82 |
22.40 |
19.57 |
0.26 |
9.54 |
|
Pire
otu 1 |
1.9515 |
67.18 |
1.04 |
3.99 |
179.33 |
7.35 |
|
Pire
otu 2 |
2.4124 |
121.99 |
1.37 |
4.39 |
102.84 |
7.68 |
|
Gabbar
1 |
2.3339 |
82.95 |
0.89 |
5.49 |
82.99 |
11.48 |
|
Gabbar
2 |
2.7112 |
70.49 |
0.66 |
4.74 |
77.42 |
9.93 |
§
According to KKTC State
Laboratory Directorship’s report, dated October 28th 1999, 8
vegetable samples collected from Gemi Konağı Maden İşleme Tesisleri at
different dates and 3 vegetable samples collected from assumed clean areas had
been investigated. As it is obvious at the enclosed analysis results; only
chrome among the carcinogen heavy metals had been analyzed and chrome value
had been found too much at Şifaotu and at
Pireotu collected from contaminated area and also at Şifaotu
collected from assumed uncontaminated area. As it is known that the heavy
metals deposited on vegetables pass to human by two ways i.e. directly and
indirectly; as eating of these vegetables by human and eating of meat and
drinking of milk of animals eating these vegetables respectively(6,7,8).
Certainly, due to only chrome among carcinogen heavy metals had been
investigated, we had to evaluate only chrome. It is assumed that other
carcinogen heavy metals especially arsenic and mercury are too much.
§
As a result; any work
and attempt relating with the public health problems resulting of Lefke Copper
Mine had not been done previously. It had been seen that there were some
searches but they had been prepared in the view of considering of economical,
agricultural and product concerns instead of public health. The effecting
level of residents from toxic, chemical and carcinogen heavy metals diffusing
from tailing storage had not been investigated.
B-
OUR INVESTIGATIONS BASED ON THE VISIT DATED NOVEMBER 1999.
The visit to Copper Mine had been realized by us obeying to previously
mentioned procedure. Since Gemikonağı Mine Processing Establishment had not
permitted to us for entering the gate, reaching to open mine ponds had been
realized by wandering around the land. All of
6 big 6 small ponds had been wandered, searched and also soil, leaf and
water samples had been collected by Prof. Dr. Ünal Altınbaş from Ege
University, Faculty of Agriculture, Department of
Soil. It had been observed that one of the big tailing ponds near the
stream had collapsed in the flood therefore the tailing pond mud having
extremely high amount of toxic chemicals and carcinogen heavy metals had
reached to the sea by flowing in this stream. It is obviously seen that these
dangerous factors of the tailing pond mud are not only for underground waters
but at the same time they are very danger for agricultural land and sea
because of reaching to there.
The
settlement areas had been visited, public health problems had been talked and
discussed with the residents, Lefke Municipality Minister had been visited and
importance of the subject and precautions had been investigated. Ideas on
improvements, advertisement needs and suggestions had been indicated.
The
fundamental factor in mining of valuable metals such as gold, silver, copper
etc. is separation of the metal from rock. The aim of the separation for all kinds of separation methods is
deposition of metal as elemental form from its salt mixtures.
Unfortunately,
all other heavy metals in the ore are also separated as valuable metals during
the separation process. These heavy metals transform from salt mixtures
to elemental form and become mobile. This mobility is more effective in
cyanide leaching method than the others.
RELATIONSHIP
BETWEEN SOME CARSINOGEN HEAVY
METALS IN LEFKE COPPER TAILING POND AND HEALTH
Type
of Carcinogen Heavy Metal |
(X)
Measured Amount At Tailing Pond ppm |
Permitted amount
at tailing ppm |
Permitted
amount at drinking water ppm |
Permitted
amount at fish ppm |
Permitted
amount at irrigation water ppm |
Effect
of chronic exposure in human to heavy metals in case of reaching of
heavy metals to drink water, fish and public |
|
Sandy
Soil |
Clay
Soil |
||||||
Cadmium |
Range:1.0-1.5 Average:1.2 |
1.0 |
0.01 |
0.1 |
0.05 |
2 |
Prostatic
cancer, lung cancer, Kidney
failure, bone fracture. |
Lead |
Range:11.3-82.8 Average:34.8 |
5.0 |
0.05 |
0.5 |
0.2 |
20 |
Lung
cancer, intestinal track cancer, kidney cancer, to destroying into brain
tissue, damages of eyes , kıdneysand muscles, aborted birth. |
Chrome |
Range:9.5-59.6 Average:32.2 |
5.0 |
0.05 |
0.5 |
5 |
20 |
İntestinal
track cancer |
Zinc |
Range:43-110 Average:77.8 |
5.0 |
5 |
60 |
5 |
10 |
Cancer
of all kinds, dermatologic diseases, respiratory irritation and
pneumonia. |
Arsenic |
Not
analyzed |
5.0 |
0.01 |
10 |
1 |
10 |
Cancers
of skin, lung, blood and lymphatic systems, anemi, heart disease, kidney
failure and aborted birth. |
Mercury |
Not
analyzed |
0.2 |
0.001 |
0.05 |
0.05 |
0.5 |
Cancers
in animals, respiratory diffievlty, parkinson disease, pulmoner eudemia,
uremy, hemorrhage. |
Table:
Carcinogen Heavy Metal on Leaves
Carcinogen Heavy Metal on Soil
Location
of Sampling and
Type of Vegetable |
Zn (ppm) |
Cr (ppm) |
Cd (ppm) |
Pb (ppm) |
Ni (ppm) |
|
Depth |
Zn (ppm) |
Cr (ppm) |
Cd (ppm) |
Pb (ppm) |
Azer
Baycan
|
|
|
|
|
|
|
0-10 |
217,5 |
11,3 |
1,17 |
16,3 |
Leaf
of mandarin |
15,0 |
6,0 |
0,90 |
14,5 |
5,3 |
|
10-28 |
132,5 |
9,2 |
1,02 |
12,5 |
Altan
Öksüz
|
|
|
|
|
|
|
0-14 |
92,5 |
11,5 |
0,93 |
45,0 |
Leaf
of orange |
10,0 |
26,0 |
0,95 |
16,49 |
4,9 |
|
14-40 |
92,5 |
20,3 |
1,12 |
23,8 |
Mehmet
Özakdenizli
|
|
|
|
|
|
|
0-14 |
87,5 |
25,9 |
1,07 |
22,5 |
Leaf
of bean |
27,0 |
2,0 |
0,48 |
22,5 |
5,3 |
|
14-33 |
80,0 |
4,5 |
0,78 |
11,3 |
Özdemir
Şamlıdağ
|
|
|
|
|
|
|
0-14 |
67,5 |
22,3 |
0,76 |
27,5 |
Leaf
of cabbage |
17,0 |
4,0 |
0,55 |
7,3 |
3,5 |
|
14-32 |
55,5 |
2,3 |
1,85 |
26,3 |
The
measurements were analyzed in Ege University Faculty of Agriculture Department
of Soil by Prof.Dr. Ünal ALTINBAŞ on 2nd March 1999
Another known geological information is that valuable metal ores such as
gold, silver, copper etc. have also other metals in high amount. There are many
mines all around the world but they must obey some rules in view of public
health, otherwise public health is damaged extremely. Some rules for mining are
as follows: being far away from settlements and underground waters, being
regardless in view of agriculture, tourist and environment, having waste
treatment ponds, to be taken necessary hygienic precautions, having impermeable
bed provided by thick clay geomembrane in storage. Mining must be operative
correctly. Since carcinogen heavy metals being together with valuable metals
such as gold, silver, copper etc. dissolve with them and become mobile and then
can pass from this dangerous pond mud to underground water, air, environment,
bird etc. In fact, the end point reached from all kinds of
contaminations is human and major concern is human’s chronic exposure.
In other way, residents, living there, drinking its water, eating its animals
and vegetables will have some systematical diseases and cancers in average 10
years or above. At the enclosed table, the carcinogen heavy metals passing from
the ores to human by water and other ways and the diseases caused by them are
illustrated. It should be defined immediately, arsenic and mercury are the most
dense metals among them reaching to human. There are many articles on increasing
in cancers and chronic diseases resulted of arsenic and mercury. Even mine ends
and/or is closed, due to presence of heavy metals, which are not decomposed, and not degraded,
mobil, and as a wakeful giant, public health problems continue 50years even 100
tears later. Therefore if these mines are near to settlements, they must not be
operated and must be waited until the new methods are found. It is obviously
seen at the enclosed tables. Zinc (Zn), chrome (Cr), cadmium (Cd), lead (Pb),
nickel (Ni), in the water, leaf and soil samples collected form Lefke abandoned
copper mine and around had been analyzed but analysis of arsenic and mercury had
not been able to done. Although arsenic and mercury are the most important
metals among them, they could not be analyzed since special equipments.
Treatments and attention are necessary during the sampling of arsenic and
mercury. Therefore, it hade been decided that to analyze arsenic and mercury at
KKTC state Laboratory instead of Ege University.
Investigated carcinogen heavy metals at tailing ponds and on the
residents’ land, fruit, vegetable the standard limits. Lead, chrome, cadmium
and zinc had been analyzed form the samples collected form the tailing pond, and
their values had been found high. Another carcinogen heavy metal Nickel (Ni) had
been also analyzed and its values had been determined also high. As cadmium,
being together with Zinc (Zn), chrome (Cr) and lead (Pb) on rural settlement,
had been stated less amount then them, but others () had been found too much.
Furthermore, sandy soil formation up to 50 % in ratio of the land is determined
by Prof.Dr. Ünal ALTINBAS’s analysis and the limit value had been lowered for
such land composition. Because, passing rate and amount of heavy metal of sandy
land to underground water is high.
CONCLUSIONS
Tailing Ponds of Lefke Copper Mines had been built very
primitive technology and they have very dangerous character. Tailing
amount has a huge emission level and covers a large area. Deposition of high
amount of carcinogen heavy metals in tailing, irrigation waters, rural
settlements and vegetable- fruit leaves had been sated. The area is contaminated
by carcinogen heavy metals, therefore residents consuming water, fruits,
vegetables, meat, milk of that area expose to cancers and chronic disease. In
order to overcome this danger which negatively effects the human health and
which will continue for al long
time, the necessary actions for improvements and advertisement must be started
as soon as possible.
REFERENCES
1
– Kıbrıs Türk İşçi Birlikleri Federasyonu ;06 Haziran 1963 tarihli ve
bila sayı resmi yazısı.
2
- Kıbrıs Türk İşçi Birlikleri Federasyonnu ;
26.07.1967 tarih
ve S.3907-4 / 65 ( 14 ) sayılı
yazısına ek , 25 Temmuz 1967 tarihli Dr. Fazıl KÜÇÜK
Başkanlığındaki Değerlendirme
Raporu.
3
– Kıbrıs Tarım Dairesi ve Tarım Araştırma Enstitüsü
; Lefke Yöresinde Maden Tozunun
Ağaçlar Üzerinde Yaptığı Etkiyi
Araştırmakla Görevlendirilen Komitenin Raporu, 1970.
4
– Lefke Çevre ve Tanıtma Derneği ; 9 Haziran 1999 tarih ve bila sayılı
resmi yazısı.
(
Devlet Bakanı ve
Başbakan Yardımcısı Mustafa AKINCI’ ya hitabeden
yazı. )
5
– KKTC Devlet Labratuarı Müdürlüğü
; 28.10.1999 tarih ve D.Lab. No
: 2099-00/99-Ç.A.
8/99-24440, 2273-75/99 , 2370-72/99 ,
4244-46/99 sayılı ve tahlil sonuçlarına dayalı rapor.
6
– DOĞAN , F :
Uygulamalı Çevre Bilimi ve Çevre Epidemiyolojisi .
I. Baskı ,
Ege Üniversitesi ÖSYO Yayın no ; 1
, Ege Üniversitesi Matbaası , İzmir, 1988.
7
– WHO : Evalvation of the
Carcinogenic Risks to Humans. IARC Monographs,
Volume : 1 – 42
Suplement ; 7 , Lyon ,France , 1987.
8
– WHO , UNEP , IARC : Environmental Carcinogens. Volume : 8 – Some Metals :
As, Be,
Cd, Cr, Ni, Pd, Se, Zn, IARC No : 71
, Lyon , France , 1986.