Introduction and regional geology
The Austroalpine basement between the Mürztal and the crest of
the Fischbacher Alpen, Styria, consists predominantely of the Lower Austroalpine
Semmering unit. It comprises mainly phyllites and phyllitic micaschists,
subordinate concordant granitoid gneisses of Carboniferous age (Grobgneis),
and is covered by Permo-Mesozoic sediments. Alpine metamorphism reached
greenschist facies conditions, the typical mineral assemblage in the metapelites
is quartz + muscovite + chlorite +/- albite +/- chloritoid +/- epidote
+/- kyanite. Garnet and a part of the white mica represent relics of a
pre-Alpine metamorphism.
In addition, there are two lithologies which are
dominated by pre-Alpine textures and mineral parageneses, the Tommer schists
and the Traibach schists. In the field they can be recognized by abundant
pseudomorphs and are therefore termed “Pseudomorphosen-Schiefer".
Schists of the Tommer type are characterized by
a garnet-staurolite assemblage indicating pre-Alpine medium-P amphibolite
facies metamorphic conditions. During the Alpine overprint, staurolite
is replaced by chloritoid and white mica. Garnets show a distinct Alpine
overgrowth.
The Traibach schist in the area Freßnitzgraben-Traibachgraben
exhibit evidence for two pre-Alpine metamorphic events. Large almandine-rich
garnets with locally staurolite inclusions feature the oldest phase, suggesting
a similar early metamorphic history as the Tommer schist. The second event,
a high-T, low-P metamorphism, resulted in prograde staurolite breakdown
and formation of a biotite-andalusite assemblage with locally sillimanite.
The pre-Alpine minerals suffered severe alteration during the Alpine overprint.
Chloritoid + staurolite + white mica +/- kyanite replaced andalusite, biotite
reacted to muscovite + ilmenite and plagioclase to muscovite + biotite.
Alpine garnets grow preferably within plagioclase pseudomorphs. A characteristic
feature of both types of “Pseudomorphosen-Schiefer" are discordant leucocratic
granitoid veins and dikes and tourmaline-bearing pegmatites.
About 10 major occurrences of hydrothermal lazulite-quartz
veins are known in the Fischbacher Alpen. These up to one meter wide veins
are located in the phyllitic micaschists and the Tommer schists. Some veins
clearly crosscut an older, most probably Variscan foliation. On the other
hand, lazulite-quartz veins are also affected by the Alpine metamorphic
overprint, and show local recrystallisation, alteration and remobilisation.
An alteration zone with Mg-rich chlorites accompanies the veins.
The ages of the two pre-Alpine metamorphic events (Carboniferous-Permian?),
as well as the formation age of the lazulite-quartz veins are uncertain
up to now.
Monazite model ages in the “Pseudomorphosen-Schiefer"
The method of monazite dating with the electron microprobe has been
introduced by SUZUKI et al. (1991). Its theoretical background, its potential
and the major error risks are described in MONTEL et al. (1996) and FINGER
& HELMY (1998).
Monazites in a sample of typical Traibach schist
with andalusite relics from Freßnitzgraben yielded a chemical Th-(U)-Pb
age of 310 +/- 17 (2s) Ma (weighted average
age from 11 analyses in four grains). These monazites are up to 0.15 mm
large, rounded and in most cases unaltered. One of the measured monazites
is corroded and surrounded by apatite. Some monazites are enclosed in pseudomorphosed
andalusite and show lobate contacts toward the former andalusite. Texturally,
these monazites appear older than andalusite. Most monazites are enclosed
in biotite or are in contact with Alpine minerals. Inclusions in monazite
are biotite and quartz.
A ca. 0.5 mm large monazite crystal in a micaschist
from Freßnitzgraben yielded 323 +/- 35 Ma (six analyses). This monazite
is partly altered to REE-bearing epidote. An undeformed narrow tourmaline-bearing
pegmatite vein crosscuts the pre-Alpine fabric of the schist and characterises
the sample as a “Pseudomorphosen-Schiefer". However, the mineral assemblage
is typically Alpine (quartz + muscovite + chlorite +/- garnet) and monazite
appears to be the only relictic mineral of the pre-Alpine metamorphism.
Due to the consistency of the single point analyses
(no evidence for lead loss or relictic cores), it may be assumed that the
mean model ages given above are close to the primary crystallization ages
of the monazites.
Xenotime model ages in lazulite-quartz veins
Accessory xenotime from the lazulite-quartz vein in phyllitc micaschists
at Höllkogel/Alpl contains in some domains enough U to permit EMP
dating. Six analyses on four grains from one sample yielded a weighted
mean age of 246 +/- 23 Ma. As the model ages of all analyses overlap within
error, it is assumed that this mean age constrains the formation age of
the lazulite-quartz veins (BERNHARD et al., 1998).
Monazite model ages in alteration zones adjacent to lazulite-quartz
veins
In these zones, monazites are typically altered to florencite. A sample
from Höllkogel was investigated. Analyses in the 5-10 mm
large monazite relics within florencite yielded geologically meaningless
results. Fourteen measurements on six grains gave model “ages“ between
273 +/- 106 and 67 +/- 41 Ma.
Discussion and conclusions
The monazite model ages of ca. 310 and ca. 323 Ma, combined with the
observed textures and mineral assemblages, suggest a medium-P, amphibolite
facies metamorphic event during Variscan time for the “Pseudomorphosen-Schiefer",
especially for the Traibach schist. It is possible that the low-P, high-T
metamorphism, which is only documented in the Traibach schists, followed
immediately after the medium-P, amphibolite facies event. A P-T-t-path
of this kind has been, for example, recorded in the extra-Alpine Variscides
(e.g. BÜTTNER & KRUHL, 1996). Alternatively, the andalusite forming
metamorphism may be related to a Permian high-T event, which has been documented
in many other parts of the Eastern Alps (SCHUSTER & THÖNI, 1996;
BERKA et al., 1998).
Formation of hydrothermal lazulite-quartz veins
in the phyllitic micaschists and the Tommer schists took place at ca. 246
Ma. Their formation may be related to the widespread magmatism and metamorphism
in the Austroalpine units during the Permian (e.g. MORAUF, 1980; MILLER
& THÖNI, 1997; BERKA et al., 1998). On the other hand, Permo-Triassic
Pb-Zn-fluorite-barite veins and pure quartz veins are abundant in extra-Alpine
basement units (see BERNHARD et al. (1998) for a brief summary). These
veins are in most cases not related to a distinct igneous or metamorphic
event. However, very distinct sources and mobilisation, transport and precipitation
conditions seem neccessary for the formation of the localized, but abundant
lazulite-quartz veins in the Fischbacher Alpen.
References
BERKA, R., SCHMIDT, K. & SCHUSTER, R. (1998): Hercynian and Permian
metamorphism in the eastern part of the Austroalpine basement units. -
Mitteilungen der Österreichischen Mineralogischen Gesellschaft, 143,242-245.
BERNHARD, F., SCHITTER, F. & FINGER, F. (1998): Zur Alterstellung
der Lazulith-Quarz Gänge im unterostalpinen Grobgneiskomplex der Nordoststeiermark
und des südlichen Niederösterreich. – Mitteilungen des Naturwissenschaftlichen
Vereins für Steiermark, 128, 43-56.
BÜTTNER, S. & KRUHL, J.H. (1997): The evolution of a late-Variscan
high-T, low-p region: The southeastern margin of the Bohemian massif. -
Geologische Rundschau, 86, 21-38.
FINGER, F. & HELMY, H. M. (1998): Composition and total-Pb model
ages of monazite from high-grade paragneisses in the Abu Swayel area, sourthern
eastern Desert, Egypt. - Mineralogy and Petrology, in press.
MILLER, Ch. & THÖNI, M. (1997): Eo-Alpine eclogitisation of
Permian MORB-type gabbros in the Koralpe (Eastern Alps, Austria): new geochronological,
geochemical and petrological data. - Chemical Geology, 137, 283-310.
MONTEL, J.-M., FORET, S., VESCHAMBRE, M., NICOLLET, Ch. & PROVOST,
A. (1996): Electron microprobe dating of monazite. - Chemical Geology,
131, 37-53.
MORAUF, W. (1980): Die permische Differentiation und die alpidische
Metamorphose des Granitgneises von Wolfsberg, Koralpe, SE-Ostalpen, mit
Rb-Sr- und K-Ar-Isotopenbestimmungen. - Tschermaks Mineralogische und Petrographische
Mitteilungen, 27, 169-185.
SCHUSTER, R. & THÖNI, M. (1996): Permian Garnets: indication
for a regional Permian metamorphism in the southern part of the Austroalpine
basement units. - Mitteilungen der Österreichischen Mineralogischen
Gesellschaft, 142, 219-221.
SUZUKI, K., ADACHI, M. & KAZJIZUKA, I. (1994): Electron microprobe
observation of Pb diffusion in metamorphosed detrital monazites. - Earth
and Planetary Science Letters, 128, 391-405.
Abstract of the paper about the age
of the lazulite-quartz veins.