中七化學TAS

實驗二：順反異構體的性質

背景資料

馬來酸的同分異構 Isomerization of Maleic Acid

www.wsu.edu/~pkuzmic/chem240/lab/pdf/isomer.pdf

同分異構的研討 Study of Isomers

http://capital2.capital.edu/faculty/wbecktel/Isomers.htm

推測反應基理 Deducing a Reaction Mechanism for the Isomerization of Maleic Acid to Fumaric Acid

http://www.chem.ndsu.nodak.edu/instruct/mallik/Chem_351_S99/Reaction_Mechanism.html

歷史背景 Historical Background

http://www.whitworth.edu/chemistry/classes/chem/ch271l/maleic/History/History.htm

馬來酸與富馬酸的測驗

http://chemed.chem.purdue.edu/chem255/tests/labfinals96/crib.html

酸的資料

馬來酸 Maleic Acid (MA) 順丁烯二酸

結構

簡介

http://www.gtamart.com/mart/products/chemical/zhitma.htm

http://www.oralchelation.com/technical/malic1.htm

 

富馬酸 Fumaric Acid (FA) 反丁烯二酸

結構

簡介

http://www.cdc.gov/niosh/ipcs/ipcs1173.html

http://www.inchem.org/documents/icsc/icsc/eics1173.htm

http://www.chemicalland21.com/arokorhi/petrochemical/FUMARIC%20ACID.htm

http://www.curj.caltech.edu/archives/vol1/1002036/

http://www.bartek.on.ca/images/fumaric.htm

http://www.allchem.com/specs/industrial/fumaric_acid.html

酸的pKa

http://www.petrik.com/PUBLIC/library/misc/acid_base_pk.htm

http://chemistry.csudh.edu/oliver/chemdata/data-ka.htm

http://dwb.unl.edu/Chemistry/LABS/LABS17.html

實驗過程資料

過濾法 Filtration

http://orgchem.colorado.edu/hndbksupport/filt/filtration.html

http://www.chem.ucalgary.ca/courses/350/expt3.html

結晶法 Procedure for Crystallization

http://orgchem.colorado.edu/hndbksupport/cryst/crystproc.html

熔點測試 melting point determination

http://orgchem.colorado.edu/hndbksupport/meltingpt/meltingpt.html

http://orgchem.colorado.edu/hndbksupport/meltingpt/MP.mov

http://www.csi.edu/ip/physci/faculty/rex/MPMain.HTM

http://chemlab.pc.maricopa.edu/labbooks/meltingPoint.html

http://www.oberlin.edu/chem/academics/chem205/205Laboratory/MeltingRange.html

 

其他資料

能學 - 馬來酸轉變成富馬酸 Enthalpy of isomerization of maleic acid by bomb calorimetry

The purpose of this experiment is to measure the enthalpy of combustion of maleic and fumaric acids, and then via Hess' Law determine the standard enthalpy for the isomerization reaction.

http://wendigo.unl.edu/~chem484/bomb/bomb.htm

http://science.csustan.edu/perona/4012/pcLbombcal.htm

 

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