| CHAPTER 7 OUTLINE | |||||||||||
| CHEMICAL QUANTITIES | |||||||||||
| I. The Mole: A Measurement of Matter | |||||||||||
| A. What is a Mole? | |||||||||||
| 1. Quantitative world | |||||||||||
| a. Count -- pair, dozen, etc. | |||||||||||
| b. Mass -- lb. of beef, etc. | |||||||||||
| c. Volume -- gal. of gas | |||||||||||
| 2. Relationship between all 3 by conversion factors | |||||||||||
| a. Examples on p. 172 (1 doz. apples = 12 apples, 1 doz. apples = 2.0 kg apples, 1 doz. apples = 0.20 bushel apples) | |||||||||||
| 3. SI counting unit of chemistry = MOLE | |||||||||||
| a. Rel. to counting, mass, & volume | |||||||||||
| B. The Number of Particles in a Mole | |||||||||||
| 1. One mole (mol) = 6.02 X 1023 representative particles of a substance | |||||||||||
| a. Just like one doz. = 12 | |||||||||||
| b. 6.02 X 1023 known as Avogadro's Number | |||||||||||
| c. Representative Particles -- Atom, molecule, form. unit, or ions | |||||||||||
| 2. Use as a conversion factor | |||||||||||
| 3. Find # of atoms in molecule | |||||||||||
| C. The Mass of a Mole of an Element | |||||||||||
| 1. Gram atomic mass (gam) -- atomic mass of an element in grams (Remember amu!) | |||||||||||
| a. The ratios are the same for both (C amu:H amu is 12:1 ratio, C grams: H amu is 12:1 ratio!) | |||||||||||
| b. The gam of any element = 1 mol = 6.02 X 1023 atoms | |||||||||||
| D. The Mass of a Mole of a Compound | |||||||||||
| 1. Gram molecular mass (gmm) -- mass of 1 mol of a molecular compound | |||||||||||
| a. Add atomic mass of atoms in compound | |||||||||||
| 2. Gram formula mass (gfm) -- mass of 1 mol of a ionic compound | |||||||||||
| a. Calculated with the same method as gmm | |||||||||||
| II. Mole-Mass and Mole-Volume Relationships | |||||||||||
| A. The Molar Mass of a Substance | |||||||||||
| 1. Molar mass -- mass (g) of one mole of any substance | |||||||||||
| a. Which is gmm or gfm per mol | |||||||||||
| b. Units are in g/mol | |||||||||||
| c. Conversion Factor | |||||||||||
| d. Start with mol, then multiply or Start with grams, then divide | |||||||||||
| B. The Volume of a Mole of Gas | |||||||||||
| 1. Measured at Standard Temperature and Pressure (STP) | |||||||||||
| a. 0oC and 101.3 kPa (1 atm) | |||||||||||
| b. At STP, 1 mol of gas = 22.4 L | |||||||||||
| c. Molar volume = 22.4 L/mol | |||||||||||
| 2. Gases have different masses (therefore, different density) | |||||||||||
| a. Density to determine molar mass | |||||||||||
| C. The Mole Road Map | |||||||||||
| 1. See page 186 | |||||||||||
| III. Percent Composition and Chemical Formulas | |||||||||||
| A. Calculate the % Composition of a Compound | |||||||||||
| 1. % by mass of each element in the compound | |||||||||||
| 2. Total mass of each element divided by the total mass of compound, then multiply by 100% | |||||||||||
| B. Using Percent as a Conversion Factor | |||||||||||
| C. Calculating Empirical Formulas | |||||||||||
| 1. The lowest whole # ratio of the atoms of the element in a compound | |||||||||||
| a. Used to count atoms or moles | |||||||||||
| D. Calculating Molecular Formulas | |||||||||||
| 1. Simple multiple of Empirical Formula | |||||||||||
| Outline based upon: Matta, M. S., Staley, D. D., Waterman, E. L., & Wilbraham, A. C. (2000). Chemistry, Addison-Wesley. (5th ed.). Menlo Park, CA: Prentice Hall, pp. 171-195. |
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