You cannot boot into dos in ME unless you hack it.

Up the FILES= statement if CONFIG.SYS is present,
Up the FILES= statement if CONFIG.NT is present, and
Add the PerVMFiles= statement to SYSTEM.INI in 

[386Enh]
PerVMFiles=99



CONFIG.SYS is replaced by C:\WINNT\SYSTEM32\CONFIG.NT.
AUTOEXEC.BAT is replaced by  C:\WINNT\SYSTEM32\AUTOEXEC.NT.

How do I set FILES= in Windows ME?

  Short answer:
  Add "PerVMFiles=<value>" to section [386enh] of SYSTEM.INI where the
the following link will allow you to modify Windows ME to boot with
config.sys and autoexec.bat

http://www.oocities.org/mfd4life_2000/

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