Outline By Day

Unit I

• Nomenclature; binary and polyatomic Quick list of polyatomic ions or formulae that you will encounter
  1. acetic acid and the acetate ion CH₃COOH and CH₃COO^-1
  2. hydroxide OH^-1
  3. cyanide CN^-1
  4. ammonium ion NH₄
  5. chlorate, sulphate, nitrate, phosphate and carbonate
• Rutherford Bohr theory, electromagnetic spectrum, Shells K, L, M, N, .... and the filling of these shells to elements just beyond 22. Continuation of review, under these headings:
  • Chemical/physical changes & reactions, types & balancing equations.
  • Gas Laws & PV = nRT (just a quick mention, not really needed.)
  • The MOLE and stiochiometric calculations; these are the ratio calculations.
  • Solutions and Molarity (M) moles/litre
• A quick mention of the Thompson, Rutherford and Bohr models of the atom
• Introduction to spectroscopy and how light is produced. Photon emmission. Gas discharge tubes were viewed; emphasis on hydrogen. This is the one you must know.

Day Two: Monday Feb 23

• Give out books, I hope.
• an explination of the production of the lines observed, not specific.
• Sommerfeld's mathematical improvements (Idea of using an ellipse instead of a circular orbit to describe the "motion" of an electron around the nucleus) , which leads into .....
  de Brolie's wave model.
• Quantum numbers: n, l, m_b, m_s and diagrams with appropriate m values.
• A look at S and the three p orbitals p_z, p_x, & p_y
  Pictures drawn on the board, make sure you can do the same
• The concept of orbital degeneracy and a simplified look at the Zeeman effect; using a magnetic field to split orbital degeneracy
• Selection rule for quantum numbers: n>l>=|m_l| Energy level diagrams. == Electron configuration. === Zeeman effect (copied note).

Day Three: Thursday Feb 26

• Small test on what has been covered so far. Make sure you show up and are prepared to write a solid test!
• Books arrive
• The d and f orbitals
• Energy level diagram
• Making connections to the periodic table (worksheet)
• Orbital degeneracy, Hund's Rule, Aufbau principle, Pauli Exclusion principle, Heinsburger Uncertainty Principle
  Homework worksheet.
• Electron configurations & Energy level diagrams; make sure you know the difference Work on assigned text book questions. Introduction to some energy equations ( E = hf).
• Stability of half and full orbitals, electron configuration exceptions.
• Video entitled Electron Shell Structure
• Test next day
• Small assignment on paramagnetism, diamagnetism and ferromagnetism ; due next Monday March 2

Day Four: Monday March 2

• Ionic bonding, electronegativity, ionization energy, polar bond, polar molecules, Lewis dot diagrams, covalent bonding ==> shapes of molecules
  VSEPR theory and predicting molecular shapes.

Day Five Thursday March 5
Test on Bonding

Shapes of molecules VSEPR theory

Day Six: Monday March 9
Start of chapter four: Molecular aggragates

• In this chapter we are concerned with NOT what holds atoms together forming molecules, but what forces hold these molecules together with other molecules. If molecules did not stick together all materials would be gaseous. Hence, forces exist that hold molecules togetheforming liquids and very strong, solids. These different forces will be investigated.
• Molecular Architecture & Bonding
  Definitions, Topic Overview and Central Concepts.
  Forces holding atoms/molecules together with each other. Key word is INTERMOLECULAR
  Bonding Forces: Strong and Weak
  Strong => Ionic, Covalent, & Metallic
  Weak => Hydrogen bonding, Dipole-dipole, & London or Induced dipole
  Molecular forces
  Molecular Aggragates
  Metallic, Ionic, Covalent, Network aggragates. Network lattice structures in two and three dimensions.

Day Seven: Thursday March 12
The usual Thursday test,

1. Valence bond theory -- hybrid orbitals
   atomic orbitals rearange and fuse together to form bonding or molecular orbitals
2. VSEPR theory shapes of molecules, bond angles, names, etc
3. Intermolecular forces: Strong (Ionic, covalent, & metallic) Weak (Van der Waals 3 types)
4. Four types of substances (Ionic, molecular, network & metallic)

Start of Organic Chemistry

March Break is this week 16 to 20

Day Eight: Monday March 23

Unit Two

Day Nine: Thursday March 26
Test on second half of Unit One; Lewis diagrams, VSEPR and Molecular aggragates.
Sigma, pi bonds with sp³, sp², sp, hybridization. Bond rotations resulting in isomers.
Cis, trans isomers, naming chloro-alkanes, alkenes, alkynes
Preparation and reactions of the above listed series.
Make sure you know the families or classes of compounds and the functional groups.
Functional groups and how to name these compounds.

Day Ten: Monday March 30
Test back from Unit I; make sure you correct errors, will be taken up next day.
Simple reactions (Chapter Six), overhead note copied: tests for unsaturate bonds, formation of esters,

What type of reaction is this?

A couple of Organic sites. Unit II stuff.

Day Eleven: Thursday April 2
Wind-up of organic; reaction worksheet to be completed and handed in next time you come to class
Introduction to Thermodynamics, what is thermal energy, heat, temperature and calorimetry.
Heat capacity & specidic heat capacity -- what's the difference?
Heat questions using Q = mΔtc with molar heat capacity. A hand out work sheet to be taught.
Book assigned questions

Continue on to page two Page Two Units 3, 4, 5, 6