Batteries
More than you ever wanted to know
Several
Email requests have asked that I try to discuss battery life and
"Why Batteries Die". Please keep in mind that I am not a
battery engineer and as always, I hope to provide some information
which may be of service.
Let's
consider some aspects of battery theory which may be useful in
understanding how lead-acid storage batteries work. The battery which
we find in motorcycle and automotive applications is intended to
produce a high current for a short length of time for starting
purposes. A secondary (maybe considered primary depending on law)
purpose is to provide park lights and to allow for the operation of
lighting loads and some accessory loads such as cooling fans when the
engine is not running or is running at too low a speed to allow the
alternator to produce enough to keep up with the load. If we didn't
need to electrically start (crank) the engine, we could make do with a
much smaller battery or no battery at all. That would be another world
however so let's look at this one.
The
typical lead-acid battery is made up of a case, positive plates,
negative plates, plate separators, cell connectors, filler caps, and
electrolyte. The battery case used to be made of a type of rubberized
material but is now of a specialized type of plastic. I use the term
"specialized" to indicate that I don't know what kind of
plastic that is made from. (Saying that it is "specialized"
sounds more informed don't you think?) It has the ability to withstand
the effects of the sulphuric acid mixture, a fair amount of impact,
extremes of temperature from below minus 55 degrees C (60 below F) up
to over 150 degrees C (300 degrees F). I have observed batteries
surviving these extremes 60 below outside temp and 300 degrees under
hood temp.
The
positive plates are made of lead peroxide and the negative plates are
of sponge lead. "Sponge lead" in that the plates are formed
of lead which is manufactured with a surface having a great number of
surface irregularities as has a sponge. A battery's capacity is
dependent on the surface area of plates which is exposed to
electrolyte - the more plate area exposed to electrolyte, the more
capacity the battery has to deliver current.
At this
point, I should mention that the battery is called a
"battery" because it is a "battery" of
"cells" and that it is easier to refer to the construction
of one cell. A cell is made up of at least one positive plate (lead
peroxide) and one negative plate (sponge lead) which are surrounded by
a sufficient quantity of electrolyte to chemically involve the plate
material. In order to provide enough current (amps) to do the work
required, the plate area required (for one cell) is about 75 square
inches for the negative plate group and 85 square inches for the
positive plate group. If you put a light behind your battery next time
you have it out, you will be able to see the plates quite clearly. You
will also see that there are dividers, one for each filler cap which
divides the battery case into six separate sections or cells. Each
cell has its own electrolyte and its own set of plates. If you tip the
battery a bit, you will see that the electrolyte does not flow from
one cell into the next.
If you
have the opportunity to see a battery which has been cut apart, you
will see the construction quite clearly, you will see also that the
positive plate material (if new) is a brown colour (lead peroxide).
Looking
at a battery which has been taken apart or with a bit of persistence
and a flashlight looking down the filler cap holes, you will notice
that the plates are connected in two groups and that the plates
alternate in order. Starting at one end, they start with a positive,
then negative, then positive, etc. ending with an "extra"
positive plate.
Looking
at the cell nearest to the positive battery post, you will notice that
there are a number of plates in the first cell. Looking carefully, you
will be able to see that the first plate from the end is connected to
a connector bar off the positive battery post and that this connector
does not go through the cell wall into the next cell. Going from the
first plate in the cell which is a positive plate, you can see that
there is a separator between this first plate and the plate next in
line. Looking through the filler hole, you will see that the
separators extend beyond the plates to ensure that nothing can
"bridge" between two plates. The separator plate is of
porous material which (in the cells which I have taken apart) looks
like a heavy piece of unbleached craft paper. Sort of like a rectangle
of super heavy shopping bag paper. This separator plate is porous to
allow it to be fully impregnated with electrolyte so that it does not
impede the flow of electrons. The separator plate also has vertical
raised ridges which provide some small space between the separator and
the plate. The ridges allow small bits of material which can become
separated, to fall to the bottom of the battery case. The purpose of
these separator plates is to prevent the cell plates from coming into
contact with one another and to prevent the cell plates from moving in
response to shock or vibration.
Battery
plates:
As you
have seen, a cell is made up of positive and negative plates which are
constructed of different materials. You will also note that the area
required would make the cells (and thus the battery) very difficult to
fit into the bike if the cell were composed of only one positive and
one negative plate. It is also easier to support a number of smaller
plates to withstand shock and vibration than it would be if there were
only two large plates per cell. Those of us who are a bit "long
in the tooth" will remember some of the odd shaped 6 volt car
batteries which were in service in the 1940's and 1950's- the shape
doesn't matter as long as you can fit the right number of cells with
enough plate area in each to do the job.
When
the cell plates are made, they are created by first forming a plate
"grid" of solid metal. This grid looks like a coarse screen
with rectangular holes inside a heavier frame which surrounds the
"screen". The purpose of the "frame" is to support
the plate and to provide an electrical conduit for the flow of
electrons to and from the active material. The rectangular
"screen" holes are arranged so that the short sides are
vertical. The positive plate group is assembled by welding a connector
bar across the top of the plate "frames" along one side. If
the group is to form the first cell at the positive end of the
battery, the connector bar will have the positive battery post
(external connector for the cables) attached. The negative plate group
(often containing one less plate) is assembled in the same manner. If
the negative plate group were part of the cell at the negative end of
the battery, this connector bar would have the negative post attached.
In this case however we are discussing the cell nearest the positive
(post) end of the battery and the negative plate group will not have a
battery post attached. Instead of a battery post, the negative group's
connector bar will have a "U" shaped piece attached which is
connected (really it is part of the connector since these are all made
in one piece) to the connector bar for the next cell. If you look at
the top of your battery, you will note that there are two raised areas
on either side of the filler caps. The raised area on the same side as
the battery posts has a vent hose attached and is intended to vent
gases resulting from charging and to prevent electrolyte from
splashing out. On both sides of the battery top is a narrower raised
area which accommodates the "U" shaped connectors which go
between the cells.
Going
back to the subject of the plates, the grid or frame is composed of a
lead-antimony alloy or a lead-calcium alloy. Older batteries used
lead-antimony and the new generation of batteries (often called
"maintenance free") use the lead-calcium alloy. The active
material (lead peroxide or sponge lead) is placed into the spaces in
the grid (into the holes in the screen). The active material is not
very strong and requires the support of the grid.
The
battery electrolyte is a mixture of 36% Sulphuric Acid (H2 SO4) and
water. If the two plate groups together with their separators are
placed into the case and the electrolyte added the battery must be
"formed" by charging it for the first time.
Something
which applies a load to the battery (either inside or outside the
battery) will drain it given enough time. The small load required to
the "keep alive " circuits to radios and CB's to allow them
to remember stations will eventually drain a battery. It's a good idea
to disconnect the negative cable or main fuse (I prefer the cable)
when the bike is parked for a month or more. Shops are remarkable
stupid in this regard! A battery will self discharge, that is it will
drain internally given enough time which is why batteries need
periodic recharging when in storage even if the cable is disconnected.
Even more frequently if the cable is not disconnected. An unfortunate
fact of life is that batteries which are designed to produce high
starting currents do not like to be drained. You can completely
discharge a new automotive battery and recharge it 3 or 4 times and
then load test and you will often find that the battery's capacity
(ability to deliver current) is markedly less. I've seen many
occasions where a new auto battery was finished after being drained
(flat) dead two times. The best advice I can offer is to avoid at all
costs, deep cycling (draining down a lot and recharging) a bike or car
battery. At one time I worked for a Honda car dealer in northern
Canada and salvaged a lot of batteries which were not good enough to
provide good starting in the cold although they would have been fine
in cars in warmer climates. These Honda batteries were Yuasas and I
used them on a battery storage system to provide lighting and power to
a house in a remote location. The batteries were placed in two groups
in which they were connected in parallel to produce 12 volts with
large current potential. The two groups were used separately to power
the system so that one group was in use while the other was charged.
By having one group out of service at a time only one group could be
drained if a load was left on inadvertently. We experienced many
occasions where one or the other group was discharged due to an
internal fault in one battery of the group. The interesting thing (to
me anyway) was that the Yuasa batteries seemed to be remarkably
tolerant of cycling and some survived this treatment for several
years. In no occasion did another make (Delco, Motorcraft, Firestone,
ESB, Exide, Sears, you name it) survive for more than three or 4
months. This likely has little to do with our GW service but if this
is indicative of the relative tolerance of Yuasas to drain-charge
cycling, we should be glad that we don't have to use other types.
(Note* I say "other types" I did not say "other
makes". Someone else could make a battery of this type, I have
just never seen an auto battery which exhibits these characteristics).
Since car and bike batteries are not called upon to provide deep
cycling (deep levels of charge-discharge) this does not speak to their
ability to provide good service in a starting mode.
One
could finance a new SE and retirement on the value of batteries which
are unnecessarily replaced in this country in one week. If you have
time, disconnect the battery negative, top up the electrolyte with the
best water which you can reasonably obtain and charge the battery. Let
the battery sit for a few days (good winter test) and measure voltage
or specific gravity, if its below 12.6 - 12.8 volts (1.280 - 1.290
specific gravity @ 80 F) you've probably found an offender. I am
always surprised that people will continually recharge a battery which
is dead every morning. Why not disconnect the negative and see if it
still goes dead over-night? If is dies while disconnected the battery
is the problem. An unlikely problem with bike batteries is that there
is enough electrolyte on the battery top to provide a discharge route.
This
couldn't happen anyway because you rinse the top off with a bit of
baking soda and water a couple of times per year, right. Don't forget
to have the filler caps in place and tight!
If the
battery only goes dead when connected then the drain is via the bike's
wiring. If you have a sensitive induction ammeter or an ammeter to
connect in series, you can measure a drain on the battery and find the
drain by disconnecting things until the drain goes away. Keep in mind
the small drain to the radios & clock, etc.
Return
to

|