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Professor Tomoe, the man in charge of the Death Buster's mission, must find the Holy Grail to create a pathway between our galaxy and the Tau Ceti. In order to do this he must find the three talismans, which are sealed in the pure hearts of 3 humans. Tomoe sent out daimons to find these people, eggs that have been combined with a normal object. When the daimon found a human with a pure heart, they either took the heart crystal or protected a Death Buster taking the crystal. If the heart crystal is taken from a person for a long period of time, they eventually die.
Tomoe sent Kaolinite to do this, and Kaolinite found a lot of pure hearted humans, but the Sailor Scouts always destroyed the daimon. Two mysterious scouts had arrived, Sailor Neptune and Sailor Uranus. They told the Sailor Scouts that it was their job to save the world, and to do this they must find the talismans. When Kaolinite found a heart crystal, Uranus and Neptune would always snatch the heart crystal and see if it was the talisman. But none of the humans had talismans sealed in their pure hearts, including Mina, Raye, Lita, Amy, and even Serena. The Scouts all had very pure hearts, but no talisman was sealed in them.
Sailor Neptune and Sailor Uranus are in human form Michiru and Haruka. They both are in tenth grade, and became friends with Raye, Amy, Lita, Mina, and Serena. When the scouts first met Haruka and Michiru, they believed that Haruka was a boy. Mina, who had had a crush on Haruka, hoped that Michiru wasn't Haruka's girlfriend. Haruka played along with this for awhile, never telling Mina she was a girl, but eventually told Mina. Both are nice people in person, but when they transform into Sailor Scouts, they become enemies of Sailor Moon and are willing to sacrifice anything to get the talismans. They believe that, because the world will be destroyed if the death busters get the talismans, the sacrifices are necessary.
In the episode where Serena had her pure heart taken out, Kaolinite had discovered Serena's transformation locket, and thought that Serena was Sailor Moon. But suddenly Sailor Moon arrived. Or someone who looked very similar to Sailor Moon.
So Kaolinite wouldn't know Serena's identity, Sailor Venus had used the luna pen to disguise herself as Sailor Moon. As Serena looked on in dismay, the scouts told Kaolinite how Serena couldn't possibly be Sailor Moon.
Sailor Mars said: "How can somebody so klutzy and a cry baby be a Sailor Scout?"
Kaolinite, believing them, dropped the heart compact with dismay. Sailor Neptune and Sailor Uranus were about to leave, but Kaolinite destroyed part of the building, and told the daimon to destroy the Scouts. Neptune and Uranus had left, and Kaolinite ran after them.
As soon as Kaolinite left, Serena dove for her compact and transformed. They destroyed the daimon, and ran out onto the roof. Kaolinite was battling with Neptune and Uranus, and the Scouts joined the fight. Kaolinite created a shield around herself, and shot flying glass at the Scouts. Mercury said the only way to destroy her was to use Sailor Planet Power. While Tuxedo Mask distracted Kaolinite, the Scouts powered up and unleashed their energy at Kaolinite. She was badly wounded, and Uranus finished her off with her World Shaking attack. Kaolinite fell off the building to her death.
Annoyed at Kaolinite's failure, Tomoe handed the mission over to Eudial, one of the Witches 5. Eudial would first use a computer to find a human with a pure heart. Then she would use a special gun, called the Heart Buster, that would extract someone's heart crystal when she shot it at someone. When she uses her Fire Buster, she yells "Witchy Eudial Fire Buster!"
Meanwhile Serena and Haruka had been trapped in a warehouse together by a monster, so they both transformed and learned each other's identity.Also, Rini returned to the 20th century to receive training as a Sailor Scout. Her mother, Neo-Queen Serenity, told her that she must learn how to make friends. Rini also became a sailor scout, Sailor Chibi Moon (translated Little Sailor Moon).
After several failures at getting the talismans, Eudial made a program that would find the talismans. Haruka and Michiru had had a dream that something important would happen that day. They believed they would find the talismans very soon.
When Eudial returned and looked at her program, and was very surprised. She called Haruka, and told her that she knew Haruka's identity. She said she had found the owner of the talismans, and faxed them a map of the place to meet her. Haruka called up Serena.
Serena met Haruka and Michiru on top of an aquarium. Haruka, claiming they didn't want Serena to slow them down anymore, ripped Serena's heart compact away from her. Haruka and Michiru transformed and left in a helicopter. Setsuna, an old friend of Haruka's and Michiru's, told Serena they went to a battle, and that they were in danger.
Sailor Uranus and Sailor Neptune went to the Marine Cathedral, a church under construction. They searched for Eudial, who was in the control room. Eudial started moving blocks to attack Neptune and Uranus, and both of them used their attacks to destroy the blocks. One piece was left and it went hurtling toward Uranus. Neptune jumped in front and got hit into the wall. Then, suddenly the wall and Neptune disappeared.
Eudial appeared and told Uranus that Neptune had the talisman. And that if she wanted to watch Eudial take the talisman from her, go to the prayer hall.
Sailor Uranus rushed to the prayer hall, where Neptune was bound to a block. Uranus ran across a bridge, but tiny arrows starting hitting Uranus at all sides. Eudial told Uranus that she would take the second talisman first, the one in Uranus. Uranus was surprised, and Eudial was about to shoot Uranus with her gun.
Neptune looked up. She realized what Eudial was going to do, and broke free from the block. She ran across the bridge crying "Haruka!", but got hit by a lot of arrows, but still struggled towards Eudial. Eudial shot Neptune, and her heart crystal came out. The heart crystal turned into a talisman, a mirror. Eudial was about to shoot Uranus, when Serena arrived and pushed Eudial off the bridge.
Sailor Uranus gave Serena back her brooch, and fired Eudial's gun at herself before Serena could stop her. The heart crystal turned into a talisman, a sword.
The scouts arrived, and Uranus told Serena to protect the Holy Grail, and to find the Messiah. She explained that when the Holy Grail was given to the Messiah, the world would be saved.
Eudial came back and took the talismans, and Serena transformed into Sailor Moon. Sailor Chibi Moon and Tuxedo Mask arrived, but Eudial sprayed some sticky stuff on the floor and everyone got stuck except for Sailor Moon. Sailor Moon ran across the sticky stuff by stepping on the stuck Sailors, and took off after Eudial. Sailor Moon and Eudial faced off together, and each used their attacks. But Eudial's was stronger, and Sailor Moon got beaten.
Setsuna arrived and transformed into Sailor Pluto. The other scouts arrived, and Sailor Pluto said she had found the last talisman, indicating the orb at the end of her Garnet Rod. Eudial was glad since she wouldn't have to search for the third one, but Sailor Pluto told her that talisman's weren't for evil people like her.
The orb floated to above Sailor Pluto's hand, and the two other talismans floated from Eudial's hands and formed a triangle. Sailor Pluto's tiara turned into her glowing planet symbol, and elsewhere so did Neptune's and Uranus'. The heart crystals floated back into their bodies, and they woke up. So the talismans could be recovered without anybody being scarified.
The talismans created the holy grail. Sailor Moon and Eudial both came after it, but Sailor Moon got to it first, and when she touched it she changed into Super Sailor Moon. Eudial attacked her, but Super Sailor Moon easily deflected it, and Eudial got blasted with her own attack.
Eudial got into her car and escaped. But Mimete, another one of the Witches 5, had rigged the car so the brakes didn't work. The car went off a cliff, and Eudial died.
Super Sailor Moon lost her power and turned back into Sailor Moon. She was very tired.
Rini had made a new friend, the pretty girl Hotaru. Hotaru is the daughter of Professor Tomoe, and had a strange power of healing wounds. She didn't have many friends, and instead spent her free time in her father's manchine. Hotaru was very pale, and got tired easily.
(flashback)
One day, Hotaru was with her father in his lab. He was working on something very important, but something went wrong and everyone was destroyed except for Tomoe. Holding his dead daughter in his arms, he agreed to sell his soul to the Daimon Master for his daughter's life. His soul was possessed by the Daimon Master.
(end flashback)
Kaolinite had survived her fall from the Tokyo tower. She spent her time in Professor Tomoe's manchine, keeping an eye on Tomoe and tormenting his daughter Hotaru.
The rest of the Witches 5 tried to get large amounts of heart crystals for their Anti-Messiah, but the Scouts saw through their attempts and destroyed them all.
Kaolinite captured Rini and fed her heart crystal to Hotaru, and Hotaru was possessed by Mistress 9. The Scouts took Rini to Darien's apartment, and he linked his life force with Rini's to keep her alive.
Tomoe congratulated Kaolinite on finding such a pure heart, and while she was distracted Mistress 9 blasted her from behind, killing her.
Sailor Neptune and Sailor Uranus went to the building where the Death Busters were summoning the Master Pharaoh Ninety. They were attacked by millions of daimons, and probably wouldn't have survived, but Sailor Pluto stopped time to save Neptune and Uranus. She teleported them inside the building, but had to leave for breaking a time taboo.
The Sailor Scouts had arrived at the building, and were attacked by the flood of daimons. They decided to combine their powers and use their "Sailor Planet Power" attack, but suddenly Mistress 9 appeared, grabbed Sailor Moon, and disappeared. The Sailor Scouts were horrified, and realized they couldn't perform the attack.
Sailor Moon appeared in the building, and Hotaru spoke to her, asking for the Holy Grail by her name, Serena. Sailor Moon asked how Hotaru could know that she was really Serena, and Hotaru began to laugh and changed back to Mistress 9.
Mistress 9 attacked Sailor Moon relentlessly.
Meanwhile, the Daimon Master appeared from Professor Tomoe, and Neptune and Uranus summoned their talismans and defeated it.
The Sailor Scouts outside decided to use Sailor Planet Power anyway. but it didn't work very well, and each of them were attacked and hurt badly by the daimons.
Since the Daimon Master was destroyed, Professor Tomoe was no longer evil, so he tried to stop Mistress 9. But she was too powerful, and he got badly beaten.
Suddenly Hotaru started to take over and had memories of the people she cared for. She destroyed Mistress 9 and transformed into Sailor Saturn. Saturn teleported to Darien's apartment and returned Rini's heart crystal.
The Mugged Gakuen building, where the Death Buster's were trying to summon the Pharaoh 90, exploded. Sailor Moon, Neptune, and Uranus were all badly injured, and the Holy Grail was destroyed.
Sailor Saturn appeared to Sailor Moon, and told her she would destroy the Master Pharaoh Ninety by destroying the earth. Sailor Moon tried to stop her, but Saturn held up her glaive threateningly, then left.
Sailor Moon saw her friends, and couldn't believe it. Mercury, Mars, Venus, and Jupiter were badly attacked and almost dead, and Sailor Moon was horrified.
Sailor Saturn jumped into the crater where the building use to be, and Sailor Moon tried to follow. She was blasted back, but cried out "Crisis, make up!" to turn into Super Sailor Moon.
Suddenly Sailor Moon's heart crystal appeared in front of her and she transformed into Super Sailor Moon. She passed through the crater and the Master Pharaoh Ninety was destroyed.
Butterflies flew around Sailor Moon in the sky, and she could be seen holding a baby in her arms. The baby was Hotaru.
Sailor Moon collapsed, and Neptune and Uranus took Hotaru away.
Haruka and Michiru visited Professor Tomoe in the hospital. Michiru showed Tomoe his daughter, and Tomoe was overjoyed to see her.