| Available Subtitles: English, Spanish, French, Portuguese
Available Audio Tracks: English (Dolby Digital 2.0 Mono)
Commentary by: Orson Welles biographer Peter Bogdanovich (Unknown Format)Commentary by: Roger Ebert (Unknown Format)
Disc 1:Feature Film1941 Movie Premiere NewsreelGallery of storyboards, rare photos, alternate ad campaign, studio and personal correspondence, call sheets and other memorabiliaDisc 2:Two-Hour Documentary: The Battle Over Citizen Kane, details the power struggle between Orson Welles and William Randolph Hearst
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| Joseph Cotten | Jedediah Leland |
| Dorothy Comingore | Susan Alexander Kane |
| Agnes Moorehead | Mary Kane |
| Ruth Warrick | Emily Monroe Norton Kane |
| Ray Collins | James W. Gettys |
| Erskine Sanford | Herbert Carter |
| Everett Sloane | Mr. Bernstein |
| William Alland | Jerry Thompson |
| Paul Stewart | Raymond |
| George Coulouris | Walter Parks Thatcher |
| Fortunio Bonanova | Signor Matiste |
| Gus Schilling | The Headwaiter |
| Philip Van Zandt | Mr. Rawlston |
| Georgia Backus | Bertha Anderson |
| Harry Shannon | Kane's Father |
| Sonny Bupp | Charles Foster Kane III |
| Buddy Swan | Kane, age eight |
| Orson Welles | Charles Foster Kane |
| Loretta Agar | Dancing Girl |
| Richard Baer | Hillman |
| Charles Bennett | Entertainer |
| Joan Blair | Georgia |
| Edmund Cobb | Inquirer Reporter |
| Eddie Coke | Reporter |
| Nat 'King' Cole | Pianist in 'El Rancho' |
| Gino Corrado | Gino |
| Herbert Corthell | City Editor |
| Thomas A. Curran | Teddy Roosevelt |
| Louise Currie | Reporter at Xanadu |
| Jack Curtis | Boss printer |
| Tim Davis | Copy boy |
| Donna Dax | House maid |
| Marie Day | Insert bit |
| Petra R. de Silva | Newswoman |
| John Dilson | Ward Heeler |
| Robert Dudley | Photographer |
| Suzanne Dulier | French maid |
| Al Eben | Solly |
| Edith Evanson | Leland's Nurse |
| Jean Forward | Opera Singer |
| Olin Francis | Expressman |
| Louise Franklin | Maid |
| Al Frazier | Gorilla man |
| Captain Garcia | General |
| Peter Gowland | Guest |
| Lew Harvey | Newspaper man |
| Edward L. Hemmer | Bit part |
| Mitchell Ingraham | Politician |
| Walter James | Ward Heeler |
| Arthur Kay | Orchestra Leader |
| Milton Kibbee | Reporter at Wedding |
| Alan Ladd | Reporter smoking pipe at end |
| Carmen Laroux | Bit part |
| Ellen Lowe | Miss Townsend |
| Buck Mack | Man |
| James T. Mack | Prompter |
| Herman J. Mankiewicz | Newspaperman |
| Joe Manz | Jennings |
| Major McBride | Shadowgraph man |
| Charles Meakin | Civic leader |
| Irving Mitchell | Dr. Corey |
| Philip Morris | Politician |
| Jack Morton | Butler |
| Louis Natheaux | Reporter |
| Frances E. Neal | Ethel |
| George Noisom | Copy boy |
| Joseph North | Male secretary |
| William H. O'Brien | Male secretary |
| Arthur O'Connell | Reporter |
| Edward Peil Jr. | Civic leader |
| Jack Raymond | Stagehand |
| Guy Repp | Reporter |
| Myrtle Rishell | Big governess |
| Benny Rubin | Smather |
| Shimen Ruskin | Hireling |
| Walter Sande | Reporter at Xanadu |
| Francis Sayles | Politician |
| George Sherwood | Hireling |
| Bruce Sidney | Newsman |
| Landers Stevens | Investigator |
| Karl Thomas | Jetsam |
| Gregg Toland | Interviewer in 1935 Newsreel |
| Kathryn Trosper | Reporter at Xanadu |
| Glen Turnbull | Flotsam |
| Gohr Van Vleck | Stagehand |
| Harry J. Vejar | Portugese laborer |
| Patrick Whitney | Reporter |
| Tudor Williams | Chorus Master |
| Richard Wilson | Reporter |
| Arthur Yeoman | Speaker |
| William Alland | Himself |
| Thomas Anderson | Himself |
| Richard Ben Cramer | Narrator |
| Peter Bogdanovich | Himself |
| Jimmy Breslin | Himself |
| Marion Davies | Herself |
| Leonard De Bur | Himself |
| Douglas Fairbanks Jr. | Himself |
| Richard France | Himself |
| William Randolph Hearst | Himself |
| William Herz | Himself |
| Sam Leve | Himself |
| Norman Lloyd | Himself |
| Nancy Loe | Herself |
| Frank Mankiewicz | Himself |
| David Nasaw | Himself |
| Lon Etta Santucci | Himself |
| John Tebbel | Himself |
| Ruth Warrick | Herself |
| Orson Welles | Himself |
| Vern Whaley | Himself |
| Gloria Widelock | Herself |
| Robert Wise | Himself |
| Jack Carter | Himself, Macbeth |
| Maurice Ellis | Himself, Macduff |
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