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Structure
Leaders:
The leaders are supposed to run the guild. Everything the Council or the sub-guilds decides goes thru them. The Leaders and the Council are the people who decides if a person could join or not.
They can also kick bad members out of the guild.
Chaos Lords (Council)
The Chaos Lords are the next highest rank in the guild. They decides with the Leaders about everything in the guild.
The Sub-Guilds
The sub guilds are CWoM, CRoS and MWoK. All sub-guils stands under the guild. If you are a Knight you join as a Chaos Warrior. If you are a Paladin you join as a Chaos Ranger. And if you are a Druid or Sorcerer you join Mad Wizards.

The leader of the their own sub-guild,
Are mentors for the rest of the members in the sub-guild. He must be a very good soldier for the leaders, so he can be a good example for the rest of the brotherhood.
Recruits
The recruit army is for people who want to join but who is under level 15.
Or a person who must show that they  are a worthy member of the brotherhood.
Official uniform for members.
The hair is the members choice.