These pictures are taken from Daniel Dae Kim's Official Website. They are all character shots, except for the black and white shot with another male actor. I believe that was a promotional shot for "The Tempest", a theatre production.
Daniel Dae Kim was quoted, saying, "I was actually really surprised at how difficult it was [to shoot that scene]. I haven't done anything like that on stage or on screen in a really long time and I certainly haven't done it in my personal life, so I knew it might be difficult, but I was still surprised by how moved by it I actually was. At the end of the day, I found myself a little bit shaken." He agreed that overall, the episode's subject matter of violence against women was terrifying, saying, "The reality of it is pretty grim." Daniel also acknowledges that the show dealt with a sensitive topic in a thoughtful and considered way, but from a personal standpoint it was still rather difficult to handle. " - Bronze Shelter Webzine, Jan. 2002
Nabbed this from a photo section of DDK's website, which you can get to by clicking here. Daniel modeled for this when he got out of college, and the box was specifically for Canandian packaging.