[General | States | Energies | Oxidation & Electrons]
[Appearance & Characteristics | Reactions | Other Forms]
[Radius | Conductivity
| Abundance | History]
Name |
Berkelium |
Symbol |
Bk |
Atomic number |
97 |
Atomic weight |
(247) |
Density @ 293 K |
? |
Atomic volume |
? |
Group |
Rare Earth, Actinides |
Discovered |
1949 |
State (s, l, g) |
s |
Melting point |
1259.2 K |
Boiling point |
K |
Heat of fusion |
? |
Heat of vaporization |
? |
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1st ionization energy |
601 kJ/mole |
Electronegativity |
1.3 |
2nd ionization energy |
kJ/mole |
Electron affinity |
kJ/mole |
3rd ionization energy |
kJ/mole |
Specific heat |
? |
Heat atomization |
kJ/mole atoms |
Shells |
2,8,18,32,26,9,2 |
Electron configuration |
[Rn] 5f9 7s2 |
Minimum oxidation number |
0 |
Maximum oxidation number |
4 |
Minimum common oxidation number |
0 |
Maximum common oxidation number |
3 |
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Structure |
fcc: face-centered cubic |
Color |
silvery |
Uses |
|
Toxicity |
|
Hardness |
mohs |
Characteristics |
Radioactive |
Reaction with air |
|
Reaction with 6M HCl |
|
Reaction with 6M HCl |
|
Reaction with 15M HNO3 |
|
Reaction with 6M NaOH |
|
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Number of isotopes |
0 |
Hydride(s) |
|
Oxide(s) |
BkO Bk2O3 BkO2 |
Chloride(s) |
BkCl3 |
Ionic radius (2- ion) |
pm |
Ionic radius (1- ion) |
pm |
Atomic radius |
170 pm |
Ionic radius (1+ ion) |
pm |
Ionic radius (2+ ion) |
pm |
Ionic radius (3+ ion) |
110 pm |
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Thermal conductivity |
J/m-sec-deg |
Electrical conductivity |
1/mohm-cm |
Polarizability |
22.7 A^3 |
Source |
Synthetic |
Rel. abund. solar system |
log |
Abundance earth's crust |
log |
Cost, pure |
$/100g |
Cost, bulk |
$/100g |
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History:
(Berkeley,
home of the University of California) Berkelium,
the eighth member of the actinide transition
series, was discovered in December 1949 by
Thompson, Ghiorso, and Seaborg, and was the fifth
transuranium element synthesized. It was produced
by cyclotron bombardment of milligram amounts of
241Am with helium ions at Berkeley, California.
The first isotope produced had a mass of 243 and
decayed with a half-life of 4.5 hours. Ten
isotopes are now known and have been synthesized.
The evidence of 249Bk with a half-life of 314
days, makes it feasible to isolate berkelium in
weighable amounts so that its properties can be
investigated with macroscopic quantities. One of
the first visible amounts of a pur berkelium
compound, berkelium chloride, was produced in
1962. It weighed 1 billionth of a gram. Berkelium
probably has not yet been prepared in elemental
form, but is expected to be a silvery metal,
easily soluble in dilute mineral acids, and
readily oxidized by air or oxygen at elevated
temperatures to form the oxide. X-ray diffraction
methods have been used to identify various
compounds. As with other actinide elements,
berkelium tends to accumulate in the skeletal
system. Because of its rarity, berkelium
presently has NO COMMERCIAL OR TECHNOLOGICAL USE.
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