Black powder


NOTE: Black powder is the one composition in pyrotechnics that varies greatly from type to type. The most important component of black powder (BP) is charcoal. It is important to use a very reactive charcoal such as willow or grapevine that contains many volatiles (oxygen and hydrogen) to increase the speed of burning.

Simply mixing the three components together does not give good results. It is usually wise to "impregnate" the charcoal with the potassium nitrate by ball milling the two chemicals together for several hours, or by the precipitation method where the potassium nitrate is dissolved in hot water and charcoal is added.

The following table gives a number of BP formulas. If a specific type charcoal is required for a composition, it will be noted in brackets beside the charcoal percentage. Bear in mind that if the charcoal is not very reactive the BP will merely fizzle and burn slowly. Examples of unreactive charcoals are activated charcoal, and barbeque briquettes which usually contain clay.

General black powder

NOTE: The term "general" is applied loosely here, referring to any black powder composition that was not designed for a specific purpose, or if it was then the specific application was not given.

  Watson Graecus Graecus Graecus Bacon Bacon Urbanski
name Standard BP (composition as
of 8th century)
(composition as
of 8th century)
Ignis Volatilis (composition
as of 1249)
(composition
as of 1252)
(composition
as of 1300)
Potassium nitrate 75 66.66 69.22 50 41 37.5 67
Charcoal 15 22.22 23.07   29.5 31.25 16.5
Sulphur 10 11.11 7.69 25 29.5 31.25 16.5
Resin       25      

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General black powder II

  Arderne Whitehorne Bruxelles Studies British Government
  (laboratory recipe,
composition as of 1350)
(composition
as of 1560)
(composition
as of 1560)
(powder made under contract,
composition as of 1635)
Potassium nitrate 66.6 50.0 75.0 75.0
Charcoal 22.2 33.3 15.62 12.5
Sulphur 11.1 16.6 9.38 12.5

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Lift-specific powder

NOTE: The following composition is optimized for firing aerial shells from fireworks mortars.

  Pyrotechnics Guild
International
  PGI optimum
Potassium nitrate 74
Charcoal 14
Sulphur 12

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Firearms-specific powder

NOTE: These compositions are intended for firing projectiles from small-bore, hand-held weapons. They may also be used for lifting aerial shells from fireworks mortars, however some testing as to the suitability of a certain composition might be necessary.

CAUTION: Cocoa powders are more sensitive to friction than ordinary black powder. Accidents have resulted from shaking of the composition in a canvas sack.

  Davis Davis Davis Davis Davis Noble and Abel
name English Cocoa
powder I
English Cocoa
Powder II
German Cocoa
Powder I
German Cocoa
Powder II
French Cocoa
Powder
Cocoa powder
Potassium nitrate 79 77.4 78 80 78 80
Charcoal 18 (rye straw) 17.6 (rye straw) 19 (rye straw) 20 (rye straw) 19 (rye straw) 18 (rye straw)
Sulphur 3 5 3   3 2

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Military-specific powder

NOTE: The following compositions were used in France for military purposes. Specific applications are listed in the table. A date as to when these compositions were put into use was not given.

  Urbanski Urbanski Urbanski Urbanski Urbanski
name Cannon Sporting Normal (rifle powder) Cannon modified Delay fuse powder
Potassium nitrate 75 78 75 78 75
Charcoal 12.5 12 15 19 13-15
Sulphur 12.5 10 10 3 10-12
grain size 7 - 21 mm 0.1 - 1 mm various hexagonal "nut" 0.3 - 0.6 mm

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Blasting-specific powder I

  Urbanski Urbanski Urbanski Urbanski Urbanski Urbanski Urbanski Urbanski Urbanski
name Strong blasting Slow blasting No.1 blasting powder No.1 Bobbinite No.2 Bobbinite No.1 black blasting powder American blasting powder No.3 black blasting powder (Petroclastite or Haloclastite) No.2 black blasting powder
Potassium nitrate 75 40 73-77 62-65 63-66        
Sodium nitrate           70-75 70-74 71-76 70-75
Charcoal 15 30 10-15 17-19.5 18.5-20.5 10-16 15-17 15-19 of coal-tar pitch 10-16 of lignite
sulphur 10 30 8-15 1.5-2.5 1.5-2.5 9-15 11-13 9-11 9-15
Paraffin       2.5-3.5          
Starch         7-9        
Ammonium sulphate and copper sulphate       13-17          

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Blasting-specific powder II

  Davis Davis Davis
  French Forte French Lente French Ordinaire
Potassium nitrate 72 40 62
Charcoal 15 30 18
Sulphur 13 30 20

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Ammonium-based powders

NOTE: These compositions were generally used as propellants, but have been largely superceded by smokeless nitrocellulose mixtures.

  Gaens   Brugere Starke
name Amide powder Ammonpulver Brugere powder Gold Dust Powder
Ammonium nitrate 35-38 85    
Potassium nitrate 40-45   57  
Charcoal 14-22 15    
Ammonium picrate     43 55
Potassium picrate       25
Ammonium dichromate       20

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Sulphurless powders

  Lancaster Noble Noble Thomas
name sulphurless powder sulphurless powder sulphurless powder
(stoichiometric)
sulphurless powder
SFG.12
Potassium nitrate 70.5 80 87.1 70
Charcoal 29.5 20 12.9 30

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