Miscellaneous US Patents

3028398 Peracetic acid process for making P2Ps from allyl benzenes, isoeugenol --> 4-hydroxy-3-methoxy-P2P in examples 1 and 3, isosafrole --> 3,4-MDP2P in example 2

3231620 Wacker process using palladium chloride and hydrogen peroxide

4273943 Peracetic acid process, note use of NaHSO₃ for destroying excess CH₃COOOH

4337360 Peracetic acid process, note use of NaHSO₃ for destroying excess CH₃COOOH

4393242 Peracetic acid process, note use of NaHSO₃ for destroying excess CH₃COOOH

1076039 sodium perborate (NaBO₃) + H₂O --> NaBO₂ + H₂O₂

5462692 sodium acetyl peroxyborate from sodium perborate and acetic acid. When sodium acetyl peroxyborate is contacted with water peracetic acid is formed

2701813 Wacker-like process using cobalt or manganous acetate catalyst and O₂

1982545 I₂ + H₂O + ethylene --> glycol

2304064 CH₃COOH + H₂O₂ --> peracetic acid + H₂O at 80-85 degrees C 1 hr, cool, add alkene

2071395 I₂, Mn salts, ferrous salts, persalts

2510905 use of ammonium persulfate and acetic acid for making diols from olefins

3928474 I₂ + ethylene, autoclave

4008286 Cu and Fe, Br-

4045500 I₂ + H₂O + ethylene, autoclave

4195190 I₂ + H₂O + ethylene with Br compound

4202995 Fe, Cu, Br-, I-

4390738 Cu peroxide, from Cu salt and H₂O

4562299 Na metabisulfate destroys H₂O₂

5210336 O₂, CO₂, CaI₂, CuI, Cu₂O on MnO₂

5268493 CH₃COOOH + catalyst

5850086 Fe complexes enhance bleaching and epoxidation

3432556 CH₂=CH-CH₃ + Hg(NO₃)₂ ---Fe³⁺---> CH₃COCH₃ + Hg + HNO₃

3965185 Pd Wacker with NH₄NO₃ maintains catalyst active for continuous conversion of olefin to carbonyl compound

4419525 Regeneration of Wacker type catalysts

4731482 allyl benzene Wacker, safrole example 1

4929765 styrene oxide/glycol --> phenylacetaldehyde

2613223 WO₃ or MoO₃ and H₂O₂, Wacker-like

1594608 styrene --> glycol uses NaOCl and CO₂

2802025 CH₃COOH + H₂O₂ ---H₂SO₄---> peracetic acid, 12-16 hr equalibrium column 2 of patent

5098598 stability of peracetic acid

4168274 continuous process for the production of a peracid in an organic solvent; epoxidation

2984687 low pressure

2397705 NH₃ + propylene, cobalt catalyst 650-800 degrees F

2518528 NaNHR + -C=C- ---> amine

4827031 NH₄X catalyst 170-450 degrees C, 1 atm-8500 psi

4929758 zeolite catalysts

4937383 NH₄(SO₄) catalyst, autoclave, autogenous pressure

2501509 Na, isopropylamine

2501556 higher C's less reactive, Na

2627526 RR'NH ---H₂O₂---> RR'NOH possibly relevant to CAT

4454321 C 2-18 column 1 lines 41-42, salt/coordination compound Ru, Fe, Pd, Pt, Rh propylene column 2 line 6, salt can be halide, nitrate, sulfate, phosphate, formate, acetate or hydrates (see patent)

5107027 clay catalysts

5900508 zeolite catalysts

2449644 phenethylamines by direct amination

3889600 1-(2-(Phenyl-lower-alkyl)-Aziridines Munition Payload

1962476 benzaldehyde ---yeast---> phenyl-CHOH-CO-CH₃

2490842 anisole from phenol and CH3MSO4 where M can be a metal such as sodium or potassium or it can be NH4+. Example 2 uses methyl sodium sulfate to make anisole from phenol.

2031719 on condensing phenol and alcohols with ZnCl2.

1411215 Na2SO4

2062454 RHSO4 + MCl --> RMSO4 + HCl (M = metal)

2176005 RCaSO4

2688035 use of alkali carbonates

3305578 R(amine)SO4, ie. R(R'NH2)SO4

4146551 Mg salt of RHSO4

3829457 RMSO4 from ROH & SO2 and O2

1599119 ferrous and cuprous catalyst for ethylene

1589372 ethylene catalysts

1574796 ethylene catalysts

1478498 ZnCl2

1484249

1641005 SO2Cl2 & alcohol --> alkyl sulfates

1998411 RMSO4

3024263 2NaHSO4 + C2H5OH = C2H5HSO4 + Na2SO4 + H2O ; Na2SO4 dehydration

3047604 Na2SO4

3232976 interesting aspirator pump apparatus

2052745 refining anethole

2233080 ArOH + RX + MOH --> ArOR + MX + H2O (M = metal)

2516412 syringaldehyde, Mep for MeO-

797024 CH3Cl

1801901 EtCl

2031719 ZnCl

2070848 RCl

2103736 phospho Mo/W catalyst

2487832 dimethyl ether used to make ArOMe

2490842 M(Me)SO4, (M = metal)

2727926 ØCOOH --> ØOH

3911022 ØOH + ester --> ØOR

5817886 phenol + MeOH + catalyst

4918241 aryl iodides --> phenols

4765455 phenols + alcohols, sulfated oxide of Cr/Mo/mixture catalyst

4675454 phenols + alcohols, sulfated oxide of Cr/Mo/mixture catalyst

4611084 phenols + alcohols, sulfated oxide of Mn/Re/mixture catalyst

4638098 phenols + alcohols, sulfated oxide of Zn/Cd/Hg/mixture catalyst

2067960 hydroquinone + RX in ROH

2235884 hydroquinone + RX in ROH

2439375 3,4-MD-phenyl --Ni--> phenol

2676947 dimethoxystyrene

2694736 Hg and Ni catalyst

2782239 alcohols & catalyst, hydroquinone and alumina-silicate catalyst 550º F

2847477 Hg acetate catalyst

3734842 electrolytic synthesis of NaBH4 from NaBO2

2942935 MgB2 --> borohydrides

3077376 borax to borohydrides

2898184 apparatus with three neck flask, Wood's metal bath

3253884 borohydride H2 source

3379511 NaBH4

3458531 IR spectra

3637516 cyanoborohydride

3993732 recycling LiBH4

5294423 a mixture of an alkali metal hydride, boric anhydride and a hydrogenation catalyst such as Raney nickel is raised to a temperature of 250.degree. to 300.degree. C. under a hydrogen atmosphere.

6251349 Method of fabrication of complex alkali metal hydrides

3016288 aluminothermic process

1858413 calcium boride

2893841 MgB4

3253886 interesting apparatus

3379647 borides and carbides

3392059 Ni and NaBH4

4604368 AlB2

4038290 olefins to epoxides using a boride catalyst

3676515 aluminum mercury alloy

3381050 aluminum copper alloy

1972956 hydrated ferric chloride as catalyst

3678122 use of allyl halide and copper halide catalyst

4551573 AlX3 and I2

1216174 AlCl3 and Fe turnings, appears to produce higher yield of monoalkylated benzene, ie. toluene in 97.5% yield

patents from class 502:

2542610 highly active Friedel-Crafts double salts

2853533 clay attenuated AlCl3

1941884 X --> HX, Al --> AlX3

2057306 Al --> AlCl3

2271299 AlCl3 and support

2309263 AlX3 and support

2370788 Al-Hg --> AlCl3, aluminum carbide --> AlCl3

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