Steady-state, non-equilibrium, multimedia partitioning model in spreadsheet format, Draft PBT List, Pennington D.W., Support documentation for docket number F-98MMLP-FFFFF, Appendix H&I, Office of Solid Waste, US EPA, 1998 ( www.epa.gov/wastemin/ )

WASTE MINIMIZATION PRIORITIZATION TOOL SPREADSHEET DOCUMENT  FOR THE RCRA WASTE MINIMIZATION PBT CHEMICAL LIST DOCKET

(# F-98-MMLP-FFFFF)
September 1998

PREFACE
In November 1994, U.S. EPA released the Waste Minimization National Plan (WMNP). The WMNP focuses on reducing the generation and subsequent release to the environment of the most persistent, bioaccumulative, and toxic chemicals in hazardous wastes, and establishes three goals:  
1) To reduce, as a nation, the presence of these chemicals in hazardous wastes by 25 percent by the year 2000 and by 50 percent by the year 2005.
2) To avoid transferring these chemicals across environmental media.
3) To ensure that these chemicals are reduced at their source whenever possible, or, when not possible, that they are recycled in an environmentally sound manner.
Stakeholders involved in development of the WMNP emphasized the need to prioritize source reduction and recycling activities based on risk and requested a flexible screening tool that would assist them in identifying priorities. EPA subsequently committed in the WMNP to develop a tool that would prioritize chemicals based on persistence, bioaccumulation potential, toxicity, and quantity. On June 23, 1997, EPA issued the Beta Test Version 1.0 of the Waste Minimization Prioritization Tool (WMPT), a tool developed to assist in waste minimization efforts, for public review. In response to public and Agency comments, EPA has modified the WMPT and used the Revised WMPT as input to developing the proposed RCRA Waste Minimization PBT Chemical List.

The WMPT is a joint product of EPA�fs Office of Solid Waste (OSW) and EPA's Office of Pollution Prevention and Toxics (OPPT). It provides a screening-level assessment of potential chronic (i.e., long-term) risks to human health and the environment.
The relative chemical rankings derived from the WMPT can complement other risk or cost information in the decision-making process. 

This document provides background and technical documentation for the Revised WMPT as used for input to the RCRA PBT List process. The document includes background on the technical approach used in the Revised WMPT along with technical information on the WMPT spreadsheets included in the RCRA PBT List docket.

The WMPT remains a work in progress. EPA plans to re-release the WMPT in Windows format by early 1999.
 


TABLE OF CONTENTS
DISCLAIMER i

PREFACE ii

ACRONYMS AND ABBREVIATIONS viii
 

CHAPTER 1: BACKGROUND INFORMATION AND FUTURE PLANS

1.1 Origins of WMPT 1-1
1.1.1 Federal Statutory Language Promotes Source Reduction and Recycling
1.1.2 Waste Minimization National Plan Established Source Reduction and Recycling Goals and Promised Development of Risk Screening Tool
1.1.3 EPA Adopted WMNP Goal as Part of Government Performance and Results Act Implementation
1.1.4 EPA Established Regional/State Team to Recommend Approach for Developing Risk Screening Tool
1.2 Release of WMPT Beta Test Version 1.0
1.3 Workgroup Modified WMPT Beta Test Version 1.0 to Develop Revised WMPT
1.4 Use of Revised WMPT in Development of the RCRA Waste Minimization PBT Chemical List
1.5 Future Release of WMPT

CHAPTER 2: OVERVIEW OF REVISED WMPT
2.1 Persistence, Bioaccumulation, and Toxicity (PBT)
2.2 Scoring Algorithm
2.3 Universe of Chemicals of Concern for RCRA PBT List
2.4 Consideration of Additional Data Sources
2.5 Elemental Metals and Metal Compounds
2.6 References

CHAPTER 3: PERSISTENCE SCORING
3.1 Overview of Persistence and the Decision to Use a Partitioning Model
3.1.1 Comments Received
3.1.2 Consultation with Experts
3.2 Models Considered and Model Selection
3.3 Spreadsheet Partitioning Model
3.3.1 Overview
3.3.2 Formulas Included in the Spreadsheet Partitioning Model
3.3.3 Model Limitations and Issues
3.4 Input Parameters
3.4.1  Constants and Conversion Factors
3.4.2  Modeled Environment
3.4.3  Compartment-specific Parameters
3.4.4  Emission Rates
3.4.5  Chemical Properties and Data Sources
3.4.6  Acceptable Temperature Range for Data
3.4.7  Persistence Data Preference Hierarchy
3.4.7.1 Data Included
3.4.7.2 Data Not Included
3.4.8  Half-life Data
3.4.8.1 Handbook of Environmental Degradation Rates
3.4.8.2 Illustrated Handbook of Physical-Chemical Properties and Environmental Fate of Organic Chemicals
3.4.8.3 Mercury Study Report to Congress
3.4.8.4 Agricultural Research Service Pesticide Properties Data Base
3.4.8.5 AOPWIN
3.4.8.6 Ultimate Survey Model
3.4.8.7 HYDROWIN
3.4.9  Melting Point, Vapor Pressure, n-Octanol-Water Partition Coefficient, and Henry's Law Constant
3.4.9.1 PhysProp
3.4.9.2 MPBPWIN
3.4.9.3 KOWWIN
3.4.9.4 HENRYWIN
3.4.10 SMILESCAS
3.4.11 Chemical Type
3.4.12 Roadmap of the Spreadsheet Partitioning Model Input Data Spreadsheet
3.4.13 Quality Assurance of the Spreadsheet Partitioning Model Input Data Spreadsheet
3.4.14 Issues
3.5 Fenceline Determination
3.6 Scoring of Elemental Metals
3.7 Roadmap for the Persistence Spreadsheet
3.8 Quality Assurance of Spreadsheet Partitioning Model Output and Persistence Scores
3.9 References

CHAPTER 4: BIOACCUMULATION SCORING

4.1  Scoring Algorithm
4.2  Bioaccumulation Data Preference Hierarchy
4.2.1 Data Included
4.2.2 Data Not Included
4.3  Mercury Study Report to Congress BAF
4.4  Draft HWIR BAF and BCF Data
4.5  SRC ISIS BCF File
4.6  Ambient Water Quality Criteria Document BCFs
4.7  BCFWIN
4.8  Fenceline Determination
4.9  Superlipophilic Compounds
4.10 Scoring of Elemental Metals
4.11 Roadmap for the Bioaccumulation Spreadsheet
4.12 Quality Assurance of Bioaccumulation Scores
4.13 References

CHAPTER 5: HUMAN TOXICITY SCORING

5.1 Chronic Toxicity Focus
5.2 Taking the Higher of Human Noncancer and Cancer Toxicity Scores
5.3 Human Noncancer Toxicity
5.3.1  Scoring Algorithm
5.3.2  Human Noncancer Toxicity Data Preference Hierarchy
5.3.2.1 Data Included
5.3.2.2 Data Not Included
5.3.3  IRIS RfD and RfC
5.3.4  ATSDR MRL
5.3.5  HEAST RfD and RfC
5.3.6  OERR Chronic Toxicity RQ
5.3.7  TSCA Section 4 NOAEL and LOAEL
5.3.8  Draft Cal/EPA REL
5.3.9  TSCA Section 8(e) Triage
5.3.10 CESARS Oral Mammalian Sublethality Score
5.3.11 OPPT Human Health Structure Activity Team Ranking
5.3.12 Fenceline Determination
5.3.13 Roadmap for the Human Noncancer Toxicity Spreadsheet
5.3.14 Quality Assurance of Human Noncancer Toxicity Scores
5.4 Human Cancer Toxicity
5.4.1 Scoring Algorithm
5.4.2 Human Cancer Toxicity Data Preference Hierarchy
5.4.2.1 Data Included
5.4.2.2 Data Not Included
5.4.3 Weight-of-Evidence
5.4.3.1 IRIS
5.4.3.2 HEAST
5.4.3.3 IARC
5.4.3.4 NTP
5.4.4 Cancer Slope Factor and Unit Risk Factor
5.4.4.1 IRIS
5.4.4.2 HEAST
5.4.4.3 EPA Cancer Data
5.4.4.4 CERCLA Section 102 RQ Potency Factor
5.4.4.5 Draft Cal/EPA
5.4.5 Fenceline Determination
5.4.6 Roadmap for the Human Cancer Toxicity Spreadsheet
5.4.7 Quality Assurance of Human Cancer Toxicity Scores
5.5 Scoring of Elemental Metals
5.6 Quality Assurance of Human Toxicity Scores
5.7 References

CHAPTER 6: ECOLOGICAL TOXICITY SCORING
6.1  Scoring Algorithm
6.2  Ecological Toxicity Data Preference Hierarchy
6.2.1 Data Included
6.2.2 Data Not Included
6.3  Sediment Quality Criteria Tier I FCV
6.4  Great Lakes Water Quality Initiative Tier I FCV
6.5  Ambient Water Quality Criteria FCV
6.6  Great Lakes Water Quality Initiative Tier II SCV
6.7  OPPT Measured Data
6.8  OPPT Predicted Data
6.9  Great Lakes Water Quality Initiative Tier I FAV
6.10 Ambient Water Quality Criteria CMC
6.11 OERR Aquatic Toxicity RQ
6.12 AQUIRE
6.13 TSCA Section 8(e) Triage Screening Results for Aquatic Toxicity Study Types
6.14 ECOSAR
6.15 Fenceline Determination
6.16 Scoring of Elemental Metals
6.17 Roadmap for the Ecological Toxicity Spreadsheet
6.18 Quality Assurance of Ecological Toxicity Scores
6.19 Issues
6.20 References

CHAPTER 7: HUMAN HEALTH AND ECOLOGICAL CONCERN SCORING
7.1 Score Aggregation Algorithm
7.2 Roadmap for the Human Health and Ecological Concern Scores Spreadsheet
7.3 Quality Assurance of Human Health and Ecological Concern Scores


Appendix A: Printout of the WMPT Persistence Scores Spreadsheet
Appendix B: Printout of the WMPT Bioaccumulation Scores Spreadsheet
Appendix C: Printout of the WMPT Human Noncancer Scores Spreadsheet
Appendix D: Printout of the WMPT Human Cancer Scores Spreadsheet
Appendix E: Printout of the WMPT Ecological Toxicity Scores Spreadsheet
Appendix F: Printout of the WMPT Human Health and Ecological Concern Scores Spreadsheet
Appendix G: Printout of the WMPT Distribution-based Fencelines Spreadsheet
Appendix H: Printout of the Spreadsheet Partitioning Model Input Data Spreadsheet
Appendix I: Printout of the Spreadsheet Partitioning Model Calculation Spreadsheet, Formaldehyde Example
Appendix J: TSCA 8(e) Triage Calls (Human Noncancer)
Appendix K: SAT Calls (Human Noncancer)
Appendix L: Environmental Toxicity Profiles for Existing Chemicals
Appendix M: Documentation of Derivation of Secondary Chronic Values for the Sediment Quality Advisory Levels
Appendix N: Improved Method for Estimating Bioconcentration Factor (BCF) From Octanol-Water Partition Coefficient.Third Update Report-August 1997. W. M. Meylan et al. Prepared by SRC for EPA.

 
 
 
 


 

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Last update: 23/Aug/1999