Here are all of the 24 enemy skills that you can learn. The first enemy skill materia is recieved after you find Red XIII. To learn them you must have the enemy skill materia equipped. The list is in order of when they can be gained.
1) Matra Magic - This fires small rockets at the opponents causing a light amount of damage (8 MP). It can be learnt from the Custom Sweepers (robotic tanks) outside Midgar.
2) Level 4 Suicide - Cast Mini and takes off loads of HP if enemy's level is a multiple of 4 (10 MP). It can be gained from a Mu (squirrel like creature) outside the Chocobo Farm
3) Beta - Average Fire damage to all enemies (35 MP). Learnt from Midgar Zolom in Swamp near the chocobo farm.
4) Flame Thrower - Average fire damage to one enemy (10 MP). Learnt from Archdragon in Myhthril Caves.
5) White Wind - Refill HP equal to the amount of the caster HP (34 MP). Learnt from Zemzelett (big winged creature) outside Junon.
6) Big Guard - Casts Barrier, M Barrier and Haste on party (56 MP). Learnt from Beach pulgs on the coastline near Cos dela Sol.
7) Laser - Reduces targets HP by 1/2 (16 MP). Learnt from Bull Motor in the farside of the GS Prison.
8) Frog Song - Casts Sleep and Frog (120 MP). It can be learnt from the frogs in the Gogonga Area
9) Death Sentence - Gives target one minute to end battle (10 MP). Learnt from GI Spector in Cave of the GI.
10) ???? - Damage to target equal to your Max HP minus your currunt HP (3 MP). Learnt from Judge (pumpkin head) in Shinra Mansion.
11) Trine - Powerful lightning damage to all enemies (20 MP). Learnt from Materia Keeper Boss in Nibel Mountains.
12) Magic Hammer -Drains 100 MP off a enemy (3 MP). It can be learnt from the Raxon Weeds outside Wutai.
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