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Chevron Jet Fuels A, A-1, A-50
MSDS: 0513 Revision #: 15 Revision Date: 03/06/94
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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JET FUELS
PRODUCT NUMBER(S): CPS216100 CPS216101 CPS216103
CPS216111
CPS216140 CPS216150 CPS235611 CPS238142
CPS241078 CPS243791 CPS322001
SYNONYM: JET A
JET A-1
JET A-50
JP-8
COMPANY IDENTIFICATION
EMERGENCY TELEPHONE NUMBERS
Chevron Products Company
HEALTH (24 hr): (800)231-0623 or
575 Market St.
(510)231-0623 (International)
San Francisco, CA 94105-2856
TRANSPORTATION
(24 hr): CHEMTREC
(800)424-9300 or (703)527-3887
Int'l collect calls accepted
PRODUCT INFORMATION: MSDS Requests and Product Information
(800) 689-3998
SPECIAL NOTES: This MSDS covers Jet A, Jet A-1 and Jet A-50 fuels.
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2. COMPOSITION/INFORMATION ON INGREDIENTS
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100.0 % JET FUELS
CONTAINING
COMPONENTS
AMOUNT LIMIT/QTY
AGENCY/TYPE
KEROSENE
Chemical Name: KEROSINE
CAS8008206
NONE NA
HYDRODESULFURIZED KEROSINE
Chemical Name: KEROSINE, HYDRODESULFURIZED
CAS64742810
NONE
NA
HYDROTREATED, DISTILLATE, LT.
Chemical Name: DISTILLATES, HYDROTREATED LIGHT
CAS64742478
NONE
NA
ACID TREATED DISTILLATE, LIGHT
Chemical Name: ACID TREATED DISTILLATE, LIGHT
CAS64742149
NONE
NA
HYDROCRACKED DISTILLATE, LIGHT
Chemical Name: HYDROCRACKED DISTILLATE, LIGHT
CAS64741771
NONE
NA
ADDITIVES
< 1.00%
COMPOSITION COMMENT:
All the components of this material are on the Toxic Substances Control
Act Chemical Substances Inventory.
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3. HAZARDS IDENTIFICATION
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************************* EMERGENCY OVERVIEW *************************
Pale yellow liquid with petroleum odor.
- FLAMMABLE
- HARMFUL OR FATAL IF SWALLOWED - CAN
ENTER LUNGS AND
CAUSE DAMAGE
- CAUSES SKIN IRRITATION
- POSSIBLE CANCER HAZARD - MAY
CAUSE CANCER BASED ON
ANIMAL DATA
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POTENTIAL HEALTH EFFECTS
EYE:
Not expected to cause prolonged or significant eye irritation.
SKIN:
Contact with the skin causes irritation. Not expected to be harmful to
internal organs if absorbed through the skin.
INGESTION:
Because of its low viscosity, this material can directly enter the lungs,
if swallowed, or if subsequently vomited. Once in the lungs it is very
difficult to remove and can cause severe injury or death.
INHALATION:
Excessive or prolonged breathing of this material may cause central
nervous system effects. Mists of this material may cause respiratory
irritation.
SIGNS AND SYMPTOMS OF EXPOSURE:
Skin irritation: may include pain, reddening, swelling, and blistering.
Central nervous system effects may include headache, dizziness, nausea,
vomiting, weakness, loss of coordination, blurred vision, drowsiness,
confusion, or disorientation. At extreme exposures, central nervous
system effects may include respiratory depression, tremors or convulsions,
loss of consciousness, coma or death. Respiratory irritation: may include
coughing and difficulty breathing.
CARCINOGENICITY:
This product contains a mixture of petroleum hydrocarbons called middle
distillates (which means they boil between approximately 350F and 700F).
Because of this broad description, many products are considered middle
distillates yet they are produced by a variety of different petroleum
refining processes. Toxicology data developed on some middle distillates
found that they caused positive responses in some mutagenicity tests and
caused skin cancer when repeatedly applied to mice over their lifetime.
This product may contain some middle distillates found to cause those
adverse effects.
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4. FIRST AID MEASURES
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EYE:
No specific first aid measures are required because this material is not
expected to cause eye irritation. As a precaution remove contact lenses,
if worn, and flush eyes with water.
SKIN:
Wash skin immediately with soap and water and remove contaminated clothing
and shoes. Get medical attention if irritation persists. Discard
contaminated clothing and shoes or thoroughly clean before reuse.
INGESTION:
If swallowed, do not induce vomiting. Give the person a glass of water or
milk to drink and get immediate medical attention. Never give anything by
mouth to an unconscious person.
INHALATION:
Move the exposed person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical
attention if symptoms continue.
NOTE TO PHYSICIANS:
Ingestion of this product or subsequent vomiting may result in aspiration
of light hydrocarbon liquid, which may cause pneumonitis.
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5. FIRE FIGHTING MEASURES
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FIRE CLASSIFICATION:
Classification (29 CFR 1910.1200): Combustible liquid. See section 7 for
appropriate handling and storage conditions.
FLAMMABLE PROPERTIES:
FLASH POINT: (TCC) 38-41C (100-106F) range
AUTOIGNITION: NDA
FLAMMABILITY LIMITS (% by volume in air): Lower: 0.6 Upper: 4.7
EXTINGUISHING MEDIA:
CO2, Dry Chemical, Foam and Water Fog.
NFPA RATINGS: Health 0; Flammability 2; Reactivity 0.
FIRE FIGHTING INSTRUCTIONS:
For fires involving this material, do not enter any enclosed or confined
fire space without proper protective equipment, including self-contained
breathing apparatus.
COMBUSTION PRODUCTS:
Normal combustion forms carbon dioxide and water vapor; incomplete
combustion can produce carbon monoxide.
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6. ACCIDENTAL RELEASE MEASURES
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CHEMTREC EMERGENCY NUMBER (24 hr): (800)424-9300 or (703)527-3887
International Collect Calls Accepted
ACCIDENTAL RELEASE MEASURES:
Eliminate all sources of ignition in the vicinity of the spill or released
vapor.
Stop the source of the leak or release. Clean up releases as soon as
possible, observing precautions in Exposure Controls/Personal Protection.
Contain liquid to prevent further contamination of soil, surface water or
groundwater. Clean up small spills using appropriate techniques such as
sorbent materials or pumping. Where feasible and appropriate, remove
contaminated soil. Follow prescribed procedures for reporting and
responding to larger releases. Place contaminated materials in disposable
containers and dispose of in a manner consistent with applicable
regulations. Contact local environmental or health authorities for
approved disposal of this material.
This material is considered to be a water pollutant and releases of this
product should be prevented from contaminating soil and water and from
entering drainage and sewer systems. U.S.A. regulations require reporting
spills of this material that could reach any surface waters. The toll
free number for the U.S. Coast Guard National Response Center is (800)
424-8802.
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7. HANDLING AND STORAGE
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This material presents a fire hazard. Liquid quickly evaporates and forms
vapor (fumes) which can catch fire and burn with explosive violence.
Invisible vapor spreads easily and can be set on fire by many sources such
as pilot lights, welding equipment, and electrical motors and switches.
Fire hazard is greater as liquid temperature rises above 15F.
AVIATION FUEL SHOULD BE FILTERED DURING TRANSFER INTO FUEL TANKS.
Key operations which have the potential of generating a flammable
atmosphere and/or static include tank and container filling, splash
filling, tank cleaning, sampling, gauging, switch loading, filtering,
mixing/agitation, and vacuum truck operations. To minimize the hazard of
static electricity during these operations, bonding and grounding may be
necessary but may not, by themselves, be sufficient. For more
information, refer to OSHA Standard 29 CFR 1910.106, "Flammable and
Combustible Liquids", National Fire Protection Association (NFPA) 77,
"Recommended Practice on Static Electricity", and/or the American
Petroleum Institute (API) Recommended Practice 2003, "Protection Against
Ignitions Arising Out of Static, Lighting, and Stray Currents".
WARNING! Not for use as portable heater or appliance fuel. Toxic fumes
may accumulate and cause death.
Do not use pressure to empty drum or drum may rupture with explosive
force. Empty containers retain product residue (solid, liquid, and/or
vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose such containers to heat, flame, sparks, static
electricity, or other sources of ignition. They may explode and cause
injury or death. Empty drums should be completely drained, properly
bunged, and promptly returned to a drum reconditioner, or properly
disposed of.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
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ENGINEERING CONTROLS
If user operations generate airborne material, use process enclosures,
local exhaust ventilation, or other engineering controls to control
exposure.
PERSONAL PROTECTIVE EQUIPMENT
EYE/FACE PROTECTION:
No special eye protection is normally required. Where splashing is
possible, wear safety glasses with side shields as a good safety practice.
SKIN PROTECTION:
No special protective clothing is normally required. Where splashing is
possible, select protective clothing depending on operations conducted,
physical requirements and other substances. Suggested materials for
protective gloves include:
Alcohol (or PVA - Note: Avoid contact with water. PVA deteriorates in
water)>
RESPIRATORY PROTECTION:
No special respiratory protection is normally required. If user
operations generate airborne material, wear a NIOSH/MSHA approved
respirator. Use the following element(s) for air purifying respirators:
Organic Vapor. Use a positive pressure, air-supplying respirator if there
is potential for uncontrolled release, exposure levels are not known, or
other circumstances where air-purifying respirators may not provide
adequate protection.
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9. PHYSICAL AND CHEMICAL PROPERTIES
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PHYSICAL DESCRIPTION:
Pale yellow liquid with petroleum odor.
pH:
NA
VAPOR PRESSURE: 0.1 PSIA @ 100F
VAPOR DENSITY
(AIR=1): 5.7
BOILING POINT: 160 - 300C (320-572F)
FREEZING POINT: - 40C
SOLUBILITY: Soluble in hydrocarbon solvents;
insoluble in water.
SPECIFIC GRAVITY: 0.81 @ 15.6/15.6C
DENSITY: 6.75 lb/gal
EVAPORATION RATE: NDA
VISCOSITY: 1.6 cSt @ 40C
PERCENT VOLATILE
(VOL): 100%
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10. STABILITY AND REACTIVITY
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HAZARDOUS DECOMPOSITION PRODUCTS:
None known
CHEMICAL STABILITY:
Stable.
CONDITIONS TO AVOID:
See section 7.
INCOMPATIBILITY WITH OTHER MATERIALS:
May react with strong oxidizing agents, such as chlorates, nitrates,
peroxides, etc.
HAZARDOUS POLYMERIZATION:
Polymerization will not occur.
______________________________________________________________________
11. TOXICOLOGICAL INFORMATION
______________________________________________________________________
EYE EFFECTS:
Minimal effects clearing in less than 24 hours.
SKIN EFFECTS:
Moderate irritation at 72 hours. (Moderate erythema). The acute dermal
LD50 in rabbits is >5 ml/kg. This material did not cause sensitization
reactions in a Modified Buehler guinea pig test.
ACUTE ORAL EFFECTS:
The acute oral LD50 in rats is >5 ml/kg.
ACUTE INHALATION EFFECTS:
The 4-hour inhalation LC50 in rats is >5 ml/l.
The data above is obtained from studies sponsored by the American
Petroleum Institute.
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains kerosene. CONCAWE (product dossier 94/106) has
summarized current health, safety and environmental data available for a
number of kerosenes (typically straight-run kerosene, CAS 8008-20-6, or
hydrodesulfurized kerosene, CAS 64742-81-0). Following acute exposure to
kerosene, signs observed in rats and rabbits were of a low order of
toxicity: central nervous system depression occurred following oral
exposure, skin irritation (ranging from slight to severe irritation)
occurred with dermal exposure, and respiratory tract irritation occurred
with inhalation exposure. None of the kerosenes tested produced more than
slight eye irritation and none were skin sensitizers. However,
intratracheal administration or artificial aspiration of small volumes
(0.1 to 0.2 ml) of kerosene into the lungs of rats, chickens and primates
resulted in lung damage and/or death. Chronic (3 to 24 months) mouse
dermal toxicity studies of kerosenes and jet fuels produced mild to
moderate skin irritation, while long-term (2+ years) studies showed
moderate to severe skin damage as well as an increased incidence of tumors
after long latency periods (probably due to a secondary mechanism related
to skin irritancy). In a study in which rats, mice, rabbits and cats were
exposed to kerosene aerosol concentrations in the range 0.05 to 120 mg/l
for up to four weeks, reductions in respiratory rate, pulmonary
hyperaemia, leucocytosis, monocytosis and decreased erythrocyte
sedimentation rate were observed, and histological examination revealed
inflammatory changes in the respiratory tract (tracheitis, bronchitis and
pneumonia).
Hydrodesulfurized kerosene was tested by the Petroleum Product Stewardship
Council in a OECD Guideline 421 Reproductive/Developmental Toxicity Study.
The kerosene sample was diluted to 494 (60%), 330 (40%), and 165 (20%)
mg/kg/day in food grade mineral oil and applied daily during pre-mating
and mating to day 19 of gestation. There was no apparent maternal,
reproductive, or developmental toxicity at any dose. Males treated for
eight weeks had increased relative kidney weights in the high dose group
but no microscopic changes in testes or epididymides. No gross anomalies
were observed in the pups.
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12. ECOLOGICAL INFORMATION
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ECOTOXICITY:
The toxicity of this material to aquatic organisms has not been evaluated.
Consequently, this material should be kept out of sewage and drainage
systems and all bodies of water.
ENVIRONMENTAL FATE:
No data available.
______________________________________________________________________
13. DISPOSAL CONSIDERATIONS
______________________________________________________________________
Use material for its intended purpose or recycle if possible. This
material, if it must be discarded, may meet the criteria of a hazardous
waste as defined by USEPA under RCRA (40CFR261) or other State and local
regulations. Measurement of certain physical properties and analysis for
regulated components may be necessary to make a correct determination. If
this material is classified as a hazardous waste, federal law requires
disposal at a licensed hazardous waste disposal facility.
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14. TRANSPORT INFORMATION
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The description shown may not apply to all shipping situations.
Consult 49CFR, or appropriate Dangerous Goods Regulations, for
additional description requirements (e.g., technical name) and
mode-specific or quantity-specific shipping requirements.
DOT SHIPPING NAME: FUEL, AVIATION, TURBINE ENGINE
DOT HAZARD CLASS: 3 (FLAMMABLE LIQUID)
DOT IDENTIFICATION NUMBER: UN1863
DOT PACKING GROUP: III
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15. REGULATORY INFORMATION
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SARA 311 CATEGORIES: 1. Immediate (Acute) Health Effects:
YES
2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard:
YES
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard:
NO
REGULATORY LISTS SEARCHED:
01=SARA 313
11=NJ RTK
22=TSCA Sect 5(a)(2)
02=MASS RTK
12=CERCLA 302.4 23=TSCA Sect 6
03=NTP Carcinogen 13=MN RTK
24=TSCA Sect 12(b)
04=CA Prop 65-Carcin 14=ACGIH TWA
25=TSCA Sect 8(a)
05=CA Prop 65-Repro Tox 15=ACGIH STEL
26=TSCA Sect 8(d)
06=IARC Group 1 16=ACGIH Calc TLV
27=TSCA Sect 4(a)
07=IARC Group 2A 17=OSHA PEL
28=Canadian
WHMIS
08=IARC Group 2B 18=DOT Marine Pollutant
29=OSHA CEILING
09=SARA 302/304 19=Chevron TWA
30=Chevron STEL
10=PA RTK
20=EPA Carcinogen
The following components of this material are found on the regulatory
lists indicated.
KEROSINE
is found on lists: 02,10,11,
EEC RISK AND SAFETY STATEMENTS:
R65
R20
R10
R38
S62
S51
S36/37
WHMIS CLASSIFICATION:
Class B, Division 3: Combustible Liquids
Class D, Division 2, Subdivision B: Toxic Material
-Skin or Eye Irritation
______________________________________________________________________
16. OTHER INFORMATION
______________________________________________________________________
NFPA RATINGS: Health 0; Flammability 2; Reactivity 0;
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal
Protection Equipment Index recommendation, *- Chronic Effect
Indicator). These values are obtained using the guidelines or
published evaluations prepared by the National Fire Protection
Association (NFPA) or the National Paint and Coating Association
(for HMIS ratings).
REVISION STATEMENT:
Changes have been made throughout this Material Safety Data Sheet.
Please read the entire document.
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA - Time
Weighted Average
STEL - Short-term Exposure Limit TPQ - Threshold Planning Quantity
RQ - Reportable Quantity
PEL - Permissible Exposure Limit
C - Ceiling Limit
CAS - Chemical Abstract Service Number
A1-5 - Appendix A Categories () - Change
Has Been Proposed
NDA - No Data Available
NA - Not Applicable
______________________________________________________________________
Prepared according to the OSHA Hazard Communication Standard
(29 CFR 1910.1200) and the ANSI MSDS Standard (Z400.1) by the Toxicology
and Health Risk Assessment Unit, CRTC, P.O. Box 4054, Richmond, CA 94804
**********************************************************************
______________________________________________________________________
The above information is based on the data of which we are aware and is
believed to be correct as of the date hereof. Since this information may
be applied under conditions beyond our control and with which we may be
unfamiliar and since data made available subsequent to the date hereof may
suggest modification of the information, we do not assume any responsibil-
ity for the results of its use. This information is furnished upon
condition that the person receiving it shall make his own determination
of the suitability of the material for his particular purpose.
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THIS IS THE LAST PAGE OF THIS MSDS
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